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Novel linear amino and polyester modified organosilicon compound for textiles

An organosilicon compound, textile technology, applied in textiles and papermaking, plant fibers, fiber processing and other directions, can solve the problems of excess hand feel, sticking rollers and bleaching oil, etc. Effect

Inactive Publication Date: 2014-09-10
上海德周化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the above-mentioned deficiencies in the prior art, provide a kind of stability that reaches the level of polyether amino silicone oil, solve the problem of amino silicone oil softener sticking roller floating oil, and feel more than traditional amino silicone oil softener at the same time

Method used

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  • Novel linear amino and polyester modified organosilicon compound for textiles
  • Novel linear amino and polyester modified organosilicon compound for textiles
  • Novel linear amino and polyester modified organosilicon compound for textiles

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0033] Step 1, D4 reacts with hydrogen-containing silicone oil, using sulfuric acid as a catalyst, sequentially add 900g of D4 and 2-10g of concentrated sulfuric acid, stir, heat up to 40°C, add hydrogen-containing silicone oil with a mass percentage of 1.8-1.92% 20 ~40g, reacted at 20~80°C for 2~10 hours, added 2~10g of soda ash, stirred for 2 hours, and stood still for 12 hours to obtain intermediate 1

[0034] Step 2: Add 1000g of intermediate to 20-40g of allyl glycidyl ether for reaction, stir and heat to 60-80°C, then add 20-40g of chloroplatinic acid and isopropanol solution (1:1) dropwise to react 2~ After 10 hours, the intermediate product 2 was obtained by this method, and the small molecular products were removed by vacuuming.

[0035] Step 3, add intermediate 1000g (2)

[0036] 5~10g of NH 2 (CH 2 CH 2 O) a wxya 2 and

[0037] 5~10gNH 2 R2(CH 2 (CH 3 ) CHO) c (CH2CHO) d R 3 NH 2 Stir the reaction for 3 to 5 hours, the viscosity increases, add 200 to 4...

Embodiment 2

[0054] Step 1, D4 reacts with hydrogen-containing silicone oil, using sulfuric acid as a catalyst, sequentially add 900g of D4 and 2g of concentrated sulfuric acid, stir, heat up to 40°C, add 20g of high hydrogen-containing silicone oil with a mass percentage of hydrogen of 1.92%, at 20~ React at 80°C for 2 to 10 hours, add soda ash and stir for 2 hours, then stand still for 12 hours to obtain intermediate 1

[0055] Step 2: add 1000g of intermediate to 30g of allyl glycidyl ether for reaction, stir and heat to 60-80°C, then add chloroplatinic acid and isopropanol solution dropwise to react for 2-10 hours, this method obtains intermediate product 2 , to remove small molecule products (i.e., impurities) by vacuuming.

[0056] Step 3, add intermediate 1000g (2)

[0057] 10 g NH 2 (CH 2 CH 2 O) a wxya 2 and

[0058] 10 g NH 2 R2(CH 2 (CH 3 ) CHO) c (CH2CHO) d R 3 NH 2 Stir the reaction for 3 to 5 hours, control the appropriate viscosity, the viscosity increases, add...

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Abstract

The invention relates to the technical field of organosilicon softeners in textile softeners, in particular relates to an organosilicon compound for textile softeners and a preparation method thereof. The organosilicon compound is finally obtained by adding octamethylcyclotetrasiloxane and hydrogen-containing silicone oil to react, carrying out a further reaction after vacuumizing and adding alkali for neutralization and then adding glycidyl ether, NH2(CH2CH2O)aR1NH2, NH2R2(CH2(CH3)CHO)c-(CH2CHO)dR3NH2 and the like, wherein R1, R4R1, R2, R3 and R4 are 2-8 alkyl amine of a carbon chain; a is equal to 3-10; b is equal to 2000-10000; c and d are equal to 3-15; and e is equal to 2000-10000. The organosilicon has excellent film-forming property, stability and handfeel on the textiles by adopting a new structure and has better stability and handfeel compared with that of the conventional amino / polyester silicone oil.

Description

[technical field] [0001] The invention relates to the technical field of silicone softeners in textile softeners, in particular to a novel linear amino and polyether modified organosilicon compound used in textile softeners [Background technique] [0002] Softening is an important auxiliary agent for the treatment of natural fibers and synthetic fiber fabrics. The softeners used in the early days include amino-modified polydimethylsiloxane, etc., which have solved the problem of industrialization and scale. The cost has its own special advantages, but because it needs to solve the problem of oil in water, its poor stability (commonly known as sticking rollers and oil floating problems in the market) limits its use. [0003] In order to solve the problem of insufficient stability of amino silicon in the market, there is also a softener based on polyether silicone oil in the market. For example, the domestic application CN101418518A discloses a durable hydrophilic polyether mo...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G81/00D06M15/647D06M101/06
Inventor 蒋冶欣
Owner 上海德周化工有限公司
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