A method of treating sludge
A sludge and oxidant technology, which is applied in the oxidation treatment of sludge, dewatering/drying/concentrating sludge treatment, etc., can solve problems such as degradation of organic matter in unfavorable sludge, catalyst deactivation, and catalytic ability decline.
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[0041] The present invention has no special limitation on the preparation method of the oxidation-directed catalyst, and the technical scheme for preparing the composition well-known to those skilled in the art can be used. In the present invention, the above-mentioned components are preferably mixed uniformly to obtain the oxidation-directed catalyst.
[0042] After the oxidation-guiding catalyst is obtained, the present invention preferentially adds the oxidation-guiding catalyst to the sludge to be treated, and the amount of the oxidation-guiding catalyst varies according to the type of sludge to be treated. In the present invention, the The sludge to be treated is preferably excess sludge or sludge. When the sludge to be treated is excess sludge, the mass ratio of the oxidation-guiding catalyst to the dry basis in the excess sludge is (3%~8%):1, preferably (4%~7%) ): 1; when the sludge to be treated is sludge, the mass ratio of the oxidation-directing catalyst to the dry b...
Embodiment 1
[0057] Carbon powder and FeCl with a mass ratio of 80:20 3 Mixing and mixing evenly to obtain an oxidation-guiding catalyst;
[0058] Add 50 g of the oxidation-directed catalyst obtained in this embodiment to the remaining sludge containing 1.0 kg dry basis, and after stirring, pass 0.5 g of ozone into it to carry out the oxidation-reduction reaction; add 0.5 g of ozone to the obtained oxidation-reduction reaction product Contains 45wt% FeCl 3 , 45wt% of the PAC and 10wt% of the CPAM flocculant, fully mixed and flocculated, obtained solid matter and filtrate through pressure filtration.
[0059] The present invention detects that the pH value of the filtrate is 6; the present invention detects that the specific resistance of the sludge obtained through flocculation is 0.080×10 12 m / kg~1.0×10 12 m / kg.
Embodiment 2
[0061] Mix activated carbon powder, fly ash, iron formate and aluminum formate with a mass ratio of 30:35:10:15, and mix uniformly to obtain an oxidation-guiding catalyst;
[0062] Add 0.35kg of the oxidation-directed catalyst prepared in this embodiment to the remaining sludge containing 10kg dry basis, after stirring, pass 3.5g of ozone into it to carry out redox reaction; add 10g containing 50wt% FeCl 3 , 45wt% of the PAC and 5wt% of the CPAM flocculant, fully mixed for flocculation, solid matter and filtrate obtained by pressure filtration.
[0063] The present invention detects that the pH value of the filtrate is 6.2, and the present invention detects that the specific resistance of the sludge obtained through flocculation is 0.090×10 12 m / kg~1.2×10 12 m / kg.
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