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Improved amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof

A technology for the polymerization of aromatic vinyl and monomers, which is applied in the direction of compositions, hydrocarbons, and organic chemical methods that inhibit chemical changes, and can solve problems such as unsolved polymerization problems.

Active Publication Date: 2014-08-20
DORF KETAL CHEM (I) PTE LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the inventors found (with reference to the examples and corresponding data) that the main problem with this known combination of quinone methide (QM) and 4HT is that even with higher amounts of this composition, the problem of polymerization remains unsolved to an acceptable level

Method used

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  • Improved amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof
  • Improved amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof
  • Improved amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof

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Embodiment Construction

[0024] In order to overcome the above-mentioned problems of the prior art and achieve the above-mentioned object of the present invention, the inventors have found that when one or more tertiary amines are added to a compound containing one or more aromatic compounds and one or more nitroxide When used in the composition of aromatic compounds and nitroxide compounds, the polymerization control and inhibition efficiency of compositions comprising aromatic compounds and nitroxides is not only substantially improved, but surprisingly and unexpectedly, by including one or more tertiary amines Substantially reduced and minimal amounts of aromatic compounds and nitroxides in compositions with one or more aromatic compounds and one or more nitroxides, including aromatic vinyl of styrene Polymerization of the monomers is also controlled and inhibited to acceptable levels, making the present compositions both economical and environmentally friendly.

[0025] In order to overcome the ab...

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Abstract

The present invention relates to an improved amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers including styrene comprising one or more of the quinone methide or derivatives thereof, one or more of nitroxide compounds and further comprising one or more of aliphatic tertiary amines. In one embodiment, the present invention also relates to method of use of presently provided composition. In another embodiment, the present invention also relates to method of controlling and inhibiting polymerization of aromatic vinyl monomers, particularly of styrene by employing presently provided composition.; In still another embodiment, the present invention also relates to method of preparation of presently provided composition.

Description

technical field [0001] The present invention relates to an improved amine-based additive composition for controlling and inhibiting the polymerization of aromatic vinyl monomers including styrene, wherein the modification comprises one or more tertiary amines and A composition of a mixture of one or more aromatic compounds and one or more nitroxide (or, nitroxyl) compounds. [0002] In one embodiment, the present invention relates to the use of the improved amine-based additive composition of the present invention to control and inhibit the polymerization of aromatic vinyl monomers including styrene, wherein the improvement comprises the use of a compound comprising one or more tertiary amines And compositions of mixtures of one or more aromatic compounds and one or more nitroxide (ie, nitroxyl) compounds. [0003] In another embodiment, the present invention is directed to a process for preparing the improved additive composition of the present invention for controlling and ...

Claims

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Application Information

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IPC IPC(8): C07C7/20C07B63/04C09K15/18C09K15/24
CPCC07B63/04C07C7/20C09K15/30C07C15/46C07C49/587C08F2/42C09K15/18C09K15/24
Inventor 马赫什·苏布拉马尼亚姆
Owner DORF KETAL CHEM (I) PTE LTD
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