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Novel steel pipe rust remover and preparation method thereof

A technology of rust remover and steel pipe, which is applied in the field of preparation of new steel pipe rust remover and the steel pipe rust remover, can solve the problems of acid waste, slow rust removal speed, over-corrosion, etc., and reduce acid waste, acid Effect of reducing fog and reducing production cost

Active Publication Date: 2017-08-11
HUNAN JINHUA SCI & TECH GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the high labor intensity, low efficiency and serious dust pollution of the mechanical method, except for a few cases, the general steel pipe manufacturers use chemical methods for rust removal.
[0003] The simplest method for chemical rust removal of steel pipes is to use hydrochloric acid or sulfuric acid to treat the rust on the surface of steel pipes. In terms of rust removal effect, hydrochloric acid is higher than sulfuric acid, but it has one of the most fatal shortcomings: in the production process, hydrochloric acid It is volatile and produces a large amount of acid mist, which not only deteriorates the operating environment, but also causes certain corrosion to the surrounding steel structures and related equipment
Whether it is hydrochloric acid rust removal or sulfuric acid rust removal, there are the following two problems: First, in the early stage of use of the rust remover, due to the high acid concentration and low ferrous ions, the rust removal speed is fast. Well, it is easy to cause over-corrosion of steel pipes; second, in the later stage of use of the above-mentioned acid solution rust remover, with the decrease of acid concentration and the increase of ferrous concentration, the rust removal speed will become very slow. The acid is strong and the effect is not great. Under this situation, if you want to completely remove the rust, you have to completely replace the acid solution in the acid tank. The over-corrosion problem often occurs in the process, and the production cost of the enterprise is relatively high

Method used

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Examples

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Comparison scheme
Effect test

Embodiment approach

[0014] As an embodiment of the present invention, a new type of rust remover for steel pipes, the weight ratio of its components is: hydrochloric acid 18-23%, oxalic acid 8%-13%, corrosion inhibitor 1.8%-2.3%, EDTA 1.8% ~2.3%, citric acid 1.8~2.3%, penetrant JFC 0.25~0.35%, and the balance is water. The corrosion inhibitor consists of urotropine, rosin imidazoline ammonium salt and industrial alcohol according to the ratio of 3:0.8:5 The weight ratio is compounded.

[0015] As a preferred embodiment, the weight percentage distribution ratio of the components of the new steel pipe rust remover is: 20% hydrochloric acid, 10% oxalic acid, 2% corrosion inhibitor, 2% EDTA, 2% citric acid, penetrating agent JFC 0.3%, and the balance is water. The corrosion inhibitor is compounded by urotropine, rosin imidazolinium ammonium salt and industrial alcohol according to the weight ratio of 3:0.8:5.

[0016] As another aspect of the present invention, the method for preparing above-mention...

Embodiment 1

[0024] Under normal pressure, according to 18% hydrochloric acid, 8% oxalic acid, and 1.8% corrosion inhibitor (the corrosion inhibitor is composed of urotropine, rosin imidazolinium ammonium salt and industrial alcohol in a weight ratio of 3:0.8:5) ), EDTA 2.3%, citric acid 2.3%, penetrant JFC 0.35%, and the balance is the weight ratio of water. Prepare each component and put it in the corresponding container, and then take it from the container filled with water Add a part of water into the reactor, and then add oxalic acid, citric acid, and EDTA to the reactor according to the above-mentioned weight ratio while stirring; then heat the solution obtained after the above steps to 50~60°C to make Fully dissolve oxalic acid, citric acid and EDTA, and stop heating after the above components are completely dissolved; then add corrosion inhibitor and penetrant JFC into the reactor in sequence according to the weight ratio mentioned above, and then continuously stir the reactor Afte...

Embodiment 2

[0029] Embodiment 2 is compared with embodiment 1, only the weight proportion of each component changes to some extent, and other content is exactly the same as embodiment 1, does not go into details here, the weight proportion of each component among the present embodiment 2 is : 23% hydrochloric acid, 13% oxalic acid, 2.3% corrosion inhibitor (the corrosion inhibitor is compounded by urotropine, rosin imidazolinium ammonium salt and industrial alcohol according to the weight ratio of 3:0.8:5), EDTA1.8 %, citric acid 1.8%, penetrant JFC 0.25%, and the balance is water.

[0030] The novel steel pipe derusting agent that this embodiment 2 provides has carried out the test of derusting production in a domestic large-scale seamless steel pipe production enterprise since the beginning of 2014, and the test time ends at the end of October, 2014, and draws the following conclusions: use the present embodiment 2 to provide When the new type of rust remover for steel pipes is mixed wi...

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PUM

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Abstract

The invention provides a novel steel pipe rust remover and a preparation method thereof, and relates to the technical field of metal surface conditioning agents. The rust remover comprises 18-23wt% of hydrochloric acid, 8-13wt% of oxalic acid, 1.8-2.3wt% of a corrosion inhibitor, 1.8-2.3wt% of EDTA, 1.8-2.3wt% of citric acid, 0.25-0.35wt% of an osmotic agent JFC, and the balance of water. The corrosion inhibitor is prepared by compounding urotropine, rosinyl imidazoline ammonium salt and industrial alcohol according to a weight ratio of 3:0.8:5. The novel steel pipe rust remover provided by the invention generates obviously less acid mist than simple acid solutions for rust removal in the prior art in the use process, and the replacement frequency of the rust remover is only 1 / 3 of that of the acid solutions under a same use frequency, so the acid waste is greatly reduced; and almost no steel pipe over-etching conditions appear in the production process, so the production cost of steel pipe enterprises is greatly reduced.

Description

technical field [0001] The invention relates to a metal surface treatment agent and a preparation method thereof, in particular to a novel steel pipe rust remover and a preparation method of the steel pipe rust remover. Background technique [0002] Before phosphating and cold drawing, steel pipes are usually derusted. At present, there are two types of rust removal methods in the industry: mechanical methods and chemical methods. Due to the high labor intensity, low efficiency and serious dust pollution of the mechanical method, except for a few cases, the general steel pipe manufacturers use chemical methods for rust removal. [0003] The simplest method for chemical rust removal of steel pipes is to use hydrochloric acid or sulfuric acid to treat the rust on the surface of steel pipes. In terms of rust removal effect, hydrochloric acid is higher than sulfuric acid, but it has one of the most fatal shortcomings: in the production process, hydrochloric acid It is volatile...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23G1/04
CPCC23G1/06C23G1/088
Inventor 许峻豪
Owner HUNAN JINHUA SCI & TECH GRP
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