Thermotropic fluorescent color-variable coordination polymer containing [Cu414]n clusters as well as synthesis method and application thereof

A coordination polymer and thermoluminescence technology, which is applied in the direction of 1/11 group organic compounds without C-metal bonds, copper organic compounds, color-changing fluorescent materials, etc., can solve the problems of short fluorescence life, high raw material cost, and luminous color Single and other problems, to achieve the effect of good monochromaticity, small distance and pure color

Active Publication Date: 2015-07-29
HARBIN INST OF TECH
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The present invention aims to solve the technical problems of single luminescent color, short fluorescent life and high cost of raw materials of current thermofluorochromic materials, thereby providing a kind of [Cu 4 I 4 ] n Cluster thermoluminescent color-changing coordination polymer and its synthesis method and application

Method used

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  • Thermotropic fluorescent color-variable coordination polymer containing [Cu414]n clusters as well as synthesis method and application thereof
  • Thermotropic fluorescent color-variable coordination polymer containing [Cu414]n clusters as well as synthesis method and application thereof
  • Thermotropic fluorescent color-variable coordination polymer containing [Cu414]n clusters as well as synthesis method and application thereof

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specific Embodiment approach 1

[0034] Specific embodiment one: this embodiment is a kind of containing [Cu 4 I 4 ] n The thermofluorochromic coordination polymer of the cluster, the molecular formula is [Cu 4 I 4 (C 14 h 14 N 4 ) 2 ] n , the structural formula is:

[0035]

[0036] , where n is a positive integer.

specific Embodiment approach 2

[0037] Specific embodiment two: the difference between this embodiment and specific embodiment one is: the described containing [Cu 4 I 4 ] n The structural unit of the clustered thermofluorochromic coordination polymer consists of 4 central Cu + ions, 4 I - ion and two 1,4-bisimidazolylmethylbenzene ligands; each center Cu + The ion has 4 coordination bonds, respectively with 3 I - The ion coordinates with a nitrogen atom in a 1,4-bis-imidazolylmethylbenzene to form a bond. Others are the same as the first embodiment.

specific Embodiment approach 3

[0038] Specific embodiment three: the difference between this embodiment and specific embodiment one or two is: the described containing [Cu 4 I 4 ] n Four Centers Cu in the Structural Unit of a Clustered Thermofluorochromic Coordination Polymer + ions and 4 I - ions form a [Cu 4 I 4 ] clusters, each [Cu 4 I 4 ] clusters present a twisted cubane configuration, forming a tetranuclear secondary structural unit; each [Cu 4 I 4 ] clusters form a one-dimensional right-helical chain structure through two nitrogen atoms in the 1,4-bis-imidazolylmethylbenzene ligand, and a 1,4-bis-imidazolyl chain is passed between adjacent one-dimensional right-helical chains The coordinated nitrogen atoms of the methylbenzene ligands are connected to form a two-layer structure, and the adjacent four [Cu 4 I 4 ] A channel is constructed between the clusters by four 1,4-bis-imidazolylmethylbenzene ligands, and the size of the channel is Others are the same as those in Embodiment 1 or 2. ...

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Abstract

The invention provides a thermotropic fluorescent color-variable coordination polymer containing [Cu414]n clusters as well as a synthesis method and application thereof and relates to a thermotropic fluorescent color-variable coordination polymer as well as a synthesis method and application thereof. The thermotropic fluorescent color-variable coordination polymer containing [Cu414(C14H14N4)2]n clusters is used for solving the technical problems of single emitted light color, short fluorescent life and high raw material cost of an existing thermotropic fluorescent color-variable material. The thermotropic fluorescent color-variable coordination polymer containing [Cu414(C14H14N4)2]n clusters has a molecular formula of [CU414(C14H14N4)2]n, and has a structural formula as shown in the specification. A preparation method comprises the following steps of mixing raw materials; heating with water; cooling; filtering; drying. The method has the beneficial effect that the yield is about 60%. The polymer presents yellow fluorescence at room temperature, and is good in single color property; a thermotropic fluorescent color-variable material capable of changing yellow fluorescence into red fluorescence is obtained by virtue of regulating different temperatures. The polymer is doped into polymethyl acrylate, so that the strength is improved, raw materials are easily available, the preparation method is simple, and the polymer can serve as a raw material for a fluorescent material film.

Description

technical field [0001] The invention relates to a thermoluminescent color-changing coordination polymer, a synthesis method and application thereof. Background technique [0002] Thermofluorochromic materials refer to functional materials whose visible absorption spectrum changes when some compounds or mixtures are heated or cooled. It has the characteristic that the color changes with temperature. The temperature at which the color changes occurs is called the color change temperature. A good thermochromic material can see the color change with the naked eye, but so far, thermochromic materials that can see the color change by heating or cooling are still rare. At present, most of these materials have a single luminescent color, short fluorescence lifetime, and high raw material cost. Contents of the invention [0003] The present invention aims to solve the technical problems of single luminescent color, short fluorescent life and high cost of raw materials of current t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F1/08C09K9/02C08L33/12C08K5/00
CPCC07F1/005C08K5/00C09K9/02C09K2211/1007C09K2211/1044C08L33/12
Inventor 范瑞清宋阳杨玉林高嵩杜玺
Owner HARBIN INST OF TECH
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