Geopolymer composite material for 3D printing and its preparation method and use
A geopolymer and 3D printing technology, applied in the field of 3D printing materials, can solve the problems of no vertical accumulation performance, long setting time of concrete materials, and the inability to use existing materials, etc., and achieve the effect of low cost
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Embodiment 1
[0056] Blast furnace quenched slag powder 25%; steel slag powder 10%; fly ash 5%; tailings machine-made sand 33%; sodium metasilicate 3.5%; sodium hydroxide 1.5%; polymer 3%; starch ether 0.2% 1% polyvinyl alcohol fiber; shrinkage reducing agent 1.8%; hydroxypropyl methylcellulose ether 0.3%; organic bentonite 1.7%; defoamer 0.1%; mixing water 13.9%.
[0057] The preparation method of the above-mentioned geopolymer composite material for 3D printing is as follows: the above powdery raw materials are pre-mixed, and after adding water and fully stirring, they can be used for pumping by the construction 3D printer, and the amount of stirring each time can be controlled according to the printing speed. Specific steps are as follows:
[0058] Step 1, preparing a composite activator: Weighing sodium metasilicate and sodium hydroxide in proportion and mixing them uniformly to prepare an activator for use;
[0059] Step 2, preparing a volume stabilizer: weighing starch ether, polyvin...
Embodiment 2
[0067] Blast furnace quenched slag powder 20%; steel slag powder 15%; fly ash 0%; tailings machine-made sand 45%; sodium metasilicate 2.2%; sodium hydroxide 0.8%; polymer 2.5%; starch ether 0.05% ; Polyvinyl alcohol fiber 0.5%; Shrinkage reducing agent 0.45%; Hydroxypropyl methyl cellulose ether 0.1; Machine bentonite 0.9%;
[0068] The specific implementation steps are the same as in Embodiment 1, and the amount of stirring each time can be controlled according to the printing speed.
[0069] The performance of the geopolymer composite material used for 3D printing in this embodiment is detected, and the results are as follows:
[0070] The initial setting time is 35 minutes, and the final time is 68 minutes;
[0071] Compressive strength R 1d =12.3MPa, R 7d =38.5MPa,R 28d =46.7MPa.
Embodiment 3
[0073] Blast furnace quenched slag powder 23%; steel slag powder 12%; fly ash 3%; tailings machine-made sand 39%; sodium metasilicate 3%; sodium hydroxide 1%; polymer 3%; starch ether 0.05% ; polyvinyl alcohol fiber 0.5%; shrinkage reducing agent 0.45%; hydroxypropyl methylcellulose ether 0.1%; machine bentonite 1.3%; defoamer 0.1%; mixing water 13.5%.
[0074] The specific implementation steps are the same as in Embodiment 1, and the amount of stirring each time can be controlled according to the printing speed.
[0075] The performance of the geopolymer composite material used for 3D printing in this embodiment is detected, and the results are as follows:
[0076] The initial setting time is 25 minutes, and the final time is 48 minutes;
[0077] Compressive strength R 1d =20.0MPa, R 7d =47.6MPa,R 28d =55.8MPa.
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