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An organic deoxidation compound inhibitor for preventing coal spontaneous combustion and preparation method thereof

A chemical inhibitor and coal spontaneous combustion technology, applied in chemical instruments and methods, compositions for inhibiting chemical changes, dust prevention, etc., can solve the problems of unable to reduce the ambient oxygen concentration, and can not better inhibit coal spontaneous combustion, etc., to achieve application Wide range, easy operation, and the effect of reducing oxygen concentration

Active Publication Date: 2020-08-04
LIAONING TECHNICAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the inhibitor can only reduce the chance of coal contacting with oxygen, but cannot reduce the surrounding oxygen concentration, and cannot better inhibit coal spontaneous combustion

Method used

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  • An organic deoxidation compound inhibitor for preventing coal spontaneous combustion and preparation method thereof
  • An organic deoxidation compound inhibitor for preventing coal spontaneous combustion and preparation method thereof
  • An organic deoxidation compound inhibitor for preventing coal spontaneous combustion and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] An organic deoxidation type composite inhibitor for preventing coal spontaneous combustion, its composition includes a mixed solution of glucose and sodium hydroxide and magnesium chloride, the addition of each component in the composite inhibitor is by mass ratio, glucose: hydrogen oxide Sodium:magnesium chloride=10:1:0.1.

[0040] The preparation method of the organic deoxidation type composite inhibitor for preventing spontaneous combustion of coal comprises the following steps:

[0041] Step 1, preparation of deoxidizer solution:

[0042] According to the ratio, weigh 17g of glucose and put it in a beaker, add 55ml of water to configure a glucose solution with a mass fraction of 23.6%, weigh 1.7g of sodium hydroxide and put it in a beaker, add 5.1ml of water to configure a mass fraction of 25% % sodium hydroxide solution, mix the configured glucose solution with sodium hydroxide solution to obtain a deoxidizer solution;

[0043] (2) Preparation of composite inhibi...

Embodiment 2

[0047] An organic deoxidation type composite inhibitor for preventing spontaneous combustion of coal, its composition includes a mixed solution of glucose and sodium hydroxide and sodium chloride, the addition of each component in the composite inhibitor is by mass ratio, glucose: Sodium hydroxide: sodium chloride = 10:1:0.2.

[0048] The preparation method of the organic deoxidation type composite inhibitor for preventing spontaneous combustion of coal comprises the following steps:

[0049] Step 1, preparation of deoxidizer solution:

[0050] According to the ratio, weigh 17g of glucose and put it in a beaker, add 55ml of water to configure a glucose solution with a mass fraction of 23.6%, weigh 1.7g of sodium hydroxide and put it in a beaker, add 5.1ml of water to configure a mass fraction of 25% % sodium hydroxide solution, mix the configured glucose solution with sodium hydroxide solution to obtain a deoxidizer solution;

[0051] (2) Preparation of composite inhibitor: ...

Embodiment 3

[0055] An organic deoxidation type composite inhibitor for preventing coal spontaneous combustion, its composition includes a mixed solution of glucose and sodium hydroxide and calcium chloride, the addition of each component in the composite inhibitor is by mass ratio, glucose: Sodium hydroxide: calcium chloride=10:1:0.1.

[0056] The preparation method of the organic deoxidation type composite inhibitor for preventing spontaneous combustion of coal comprises the following steps:

[0057] Step 1, preparation of deoxidizer solution:

[0058] According to the ratio, weigh 17g of glucose and put it in a beaker, add 55ml of water to configure a glucose solution with a mass fraction of 23.6%, weigh 1.7g of sodium hydroxide and put it in a beaker, add 5.1ml of water to configure a mass fraction of 25% % sodium hydroxide solution, mix the configured glucose solution with sodium hydroxide solution to obtain a deoxidizer solution;

[0059] (2) Preparation of composite inhibitor:

...

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Abstract

The invention relates to an organic deoxygenated composite retardant for preventing spontaneous combustion of coal and a preparation method of the organic deoxygenated composite retardant. The composite retardant is prepared from a mixed solution of glucose and sodium hydroxide and a retardant, wherein the weight ratio of glucose to sodium hydroxide to the retardant is (8 to 10): 1: (0.1 to 0.3).The preparation method comprises the following steps: collecting glucose and sodium hydroxide according to the ratio, preparing a glucose solution and a sodium hydroxide solution of a corresponding mass fraction, and mixing to obtain a deoxidant solution; and adding the retardant into the deoxidant solution, and uniformly stirring to obtain the organic deoxygenated composite retardant for preventing the spontaneous combustion of coal. The preparation method is simple, and a product for preventing the spontaneous combustion of the coal can play a role in preventing the oxidation of active groups of the coal and preventing the coal from absorbing oxygen surrounding the residual coal; and the product has the characteristic similar to the traditional retardant that can be prepared into a solution, so that the organic deoxygenated composite retardant can be applied to the places of underground opening and closed gobs and coal walls with two-lane two-line crack development and the like in the aspect of preventing the spontaneous combustion of underground coal in coal mines and is wide in application range.

Description

Technical field: [0001] The invention belongs to the technical field of fire prevention and extinguishing materials for coal mines, and in particular relates to an organic deoxidation type composite inhibitor for preventing coal spontaneous combustion and a preparation method thereof. Background technique: [0002] Coal spontaneous combustion disasters cause serious safety accidents and environmental pollution. In order to promote the continuous development of coal spontaneous combustion prevention and control technology, adapt to the complexity of coal mine production conditions and the diversity of coal spontaneous combustion in my country, further curb the occurrence of disasters, reduce economic losses and casualties , Inhibitor (generally use inorganic salt MgCl 2 , NaCl, CaCl 2 etc.) Fire prevention is an important technical means. However, the inhibitor can only reduce the chance of coal contacting with oxygen, but cannot reduce the surrounding oxygen concentration, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K15/06C09K15/08E21F5/06
CPCC09K15/06C09K15/08E21F5/06
Inventor 郝朝瑜陈艳玲王浩宇王继仁邓存宝司蕊
Owner LIAONING TECHNICAL UNIVERSITY
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