Method for preparing SiO2 nanoparticle shearing and thickening fluid on basis of surface modification and etching

A nanoparticle and surface modification technology, applied in chemical instruments and methods, fibrous fillers, dyed organosilicon compound treatment, etc., can solve the problem of decreased damping performance and thickening characteristics of shear thickening fluid, and no nanoparticle Due to problems such as performance and large particle size distribution of particle agglomeration, it can achieve the effect of high critical shear rate, high viscosity and yield stress, and stable product performance

Inactive Publication Date: 2018-07-20
中国化工集团曙光橡胶工业研究设计院有限公司
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  • Claims
  • Application Information

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Problems solved by technology

But this method has obvious disadvantages: the synthesized SiO 2 The particle agglomeration is serious and the particle size distribution is large. According to the fluid lubrication theory, after agglomeration, SiO 2 The specific surface area of ​​nanoparticles is greatly reduced, the damping performance and thickening characteristics of the shear thickening fluid are greatly reduced, and the proper performance of nanoparticles is not shown. Therefore, the synthesis and modification of non-agglomerated SiO 2 Nanoparticles still await further study

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  • Method for preparing SiO2 nanoparticle shearing and thickening fluid on basis of surface modification and etching
  • Method for preparing SiO2 nanoparticle shearing and thickening fluid on basis of surface modification and etching

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Embodiment

[0028] A SiO based on surface modification and etching 2 A method for preparing a nanoparticle shear thickening fluid, comprising the steps of:

[0029] 1) Preparation of etched SiO with a particle size of 20nm-500nm on the surface 2 Nanoparticles: By controlling the concentration of deionized water and ammonia in the reaction solution in different reaction stages, SiO 2 The regulation of particle size and distribution of nanoparticles, and then through the silane coupling agent on SiO 2 The nanoparticles were surface modified, and finally the SiO 2 Etching the surface of the nanoparticles;

[0030] 2) SiO obtained in step 1) 2 Nanoparticles are added to the mixed liquid, and dispersed evenly by mechanical stirring, grinding and ultrasonic equipment to obtain a suspension;

[0031] 3) Dry the volatile components in the suspension obtained in step 2), and the resulting fluid is SiO 2 shear thickening fluid.

[0032] Step 1) is:

[0033] (1) Preparation of SiO with a par...

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Abstract

The invention discloses a method for preparing a SiO2 nanoparticle shearing and thickening fluid on the basis of surface modification and etching. The method comprises the following steps: 1) preparing SiO2 nanoparticles of which the particle size is 20-500nm and the surface is etched; 2) putting the SiO2 nanoparticles obtained in the step 1) into a mixed liquid, uniformly dispersing the SiO2 nanoparticles through mechanical stirring, grinding and ultrasonic equipment so as to obtain a suspension; 3) drying volatile components in the suspension obtained in the step 2), so as to obtain a fluid,namely a SiO2 shearing and thickening fluid. The method is simple in process, good in operability, stable in product property, small in waste emission and applicable to industrial production, the SiO2 nanoparticles synthesized by using the method are good in dispersibility, uniform in particle size distribution and free of aggregation, the shearing and thickening fluid prepared from the SiO2 nanoparticles synthesized by using the method has the characteristics of being large in critical shearing velocity, large in viscosity and yield stress after thickening, large in damping coefficient, andthe like, and is applicable to application requirements of fields such as individual protection, armor protection and damping and noise reduction.

Description

technical field [0001] The present invention relates to SiO 2 Synthesis, surface modification and etching of nanoparticles, SiO 2 The field of nanoparticle application technology mainly involves a monodisperse non-agglomerated SiO 2 Synthesis, surface modification and etching of nanoparticles and based on this SiO 2 Preparation method of shear thickening fluid, specifically a SiO2 based on surface modification and etching 2 Preparation method of nanoparticle shear thickening fluid. Background technique [0002] A shear thickening fluid is one in which the viscosity of the fluid increases as the shear rate increases. This characteristic makes the shear thickening fluid have a wide range of applications, such as personal protection, armor protection, damping and shock absorption, sound insulation and noise reduction, and building shock resistance. With the deepening of the study on the fluid shear thickening effect, a series of shear thickening fluids have been prepared, ...

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): D06M11/79C08K9/06C08K9/02C08K3/36C09C1/28C09C3/12C09C3/06
CPCC08K3/36C08K9/02C08K9/06C08K2201/011C09C1/28C09C3/006C09C3/06C09C3/12D06M11/79
Inventor李霜兵
Owner中国化工集团曙光橡胶工业研究设计院有限公司