A kind of amorphous manganese dioxide and its preparation method and application
A manganese dioxide and amorphous technology, applied in the field of materials, can solve the problems of increasing cost of lithium-ion batteries, restricting the application of lithium-ion batteries, and increasing lithium prices, etc., achieving good cycle stability, low requirements for reaction environment, and high specific capacity Effect
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[0028] At room temperature, add 1.58g KMnO 4 And 3.68g Mn(CH 3 COO) 2 ·4H 2 O was prepared into 50mL solution with deionized water, and KMnO 4 The solution is magnetically stirred, and then the Mn(CH 3 COO) 2 ·4H 2 O solution is added dropwise to KMnO 4 In the solution, stir for 5 minutes to form a homogeneous solution. Prepare 10mL of KOH solution with a concentration of 0.16g / L, add it to the above homogeneous solution, keep magnetic stirring at room temperature for 4h to obtain a dark brown precipitate, wash it several times with deionized water and absolute ethanol, and put the precipitate in an oven Dry at 85°C for 12 hours, grind uniformly with a mortar, and calcinate at 400°C for 3 hours in an air atmosphere to obtain sample manganese dioxide.
[0029] The synthesized MnO 2 The material and the conductive agent (graphite: carbon black = 4:6) are mixed and added to the ball milling tank at a mass ratio of 7:2, dry milled in a planetary ball mill for two hours, and then wet m...
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