Polyphenylene oxide resin composite material as well as preparation method and application thereof

A technology of polyphenylene ether resin and composite material, applied in the field of polyphenylene ether resin composite material and its preparation, can solve the problems of poor toughness and stress cracking of polyphenylene ether resin, and achieve stable performance, easily controllable conditions and low cost. Effect

Active Publication Date: 2019-01-18
SHENZHEN WOTE ADVANCED MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The purpose of the present invention is to provide a polyphenylene ether resin composite material and its preparation method and application, aiming to solve t

Method used

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  • Polyphenylene oxide resin composite material as well as preparation method and application thereof
  • Polyphenylene oxide resin composite material as well as preparation method and application thereof
  • Polyphenylene oxide resin composite material as well as preparation method and application thereof

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preparation example Construction

[0054] Correspondingly, an embodiment of the present invention provides a method for preparing a polyphenylene ether resin composite material, and the polyphenylene ether resin composite material includes the following components by weight:

[0055]

[0056] Wherein, the total weight of the functional master batch is 100%, and the functional master batch includes the following components in the following weight percentages:

[0057] Resin base 60-79%;

[0058] Fumed nano silica with branched structure 20-39%;

[0059] Coupling agent 1-3%;

[0060] And the coupling agent is coated on the surface of the fumed nano-silica having a branched structure;

[0061] The preparation method of described polyphenylene ether resin composite material, comprises the following steps:

[0062] S01. Weigh each component according to the formula of the polyphenylene ether resin composite material;

[0063] S02. Mixing the polyphenylene ether resin and the elastomer to obtain a first mixed ...

Embodiment 1

[0088] A polyphenylene ether resin composite material, the composition of which is shown in Table 1, specifically: 70 parts of polyphenylene ether resin (PPO), 5 parts of elastomer, 8 parts of flame retardant, 1 part of polyolefin, 15.7 parts of functional masterbatch , 0.2 parts of primary antioxidant and 0.1 part of auxiliary antioxidant; wherein, based on the total weight of the functional master batch as 100%, the functional master batch includes the following components in the following weight percentages: polyphenylene 70% of ether resin base material, 28% of fumed silica with branched structure, and 2% of coupling agent.

[0089] The preparation method of the polyphenylene ether resin composite material includes: 70 parts of polyphenylene ether resin (PPO) and 5 parts of elastomer are added from the first weight loss feeder port, 8 parts of flame retardant, 1 part of polyolefin, 15.7 parts Functional masterbatch, 0.2 parts of primary antioxidant and 0.1 part of secondar...

Embodiment 2

[0091] A polyphenylene ether resin composite material, the composition of which is shown in Table 1, specifically: 70 parts of polyphenylene ether resin (PPO), 10 parts of elastomer, 8 parts of flame retardant, 1 part of polyolefin, 10.7 parts of functional masterbatch , 0.2 parts of primary antioxidant and 0.1 part of auxiliary antioxidant; wherein, based on the total weight of the functional master batch as 100%, the functional master batch includes the following components in the following weight percentages: polyphenylene 68% of ether resin base material, 30% of fumed silica with branched structure, and 2% of coupling agent.

[0092] The preparation method of the polyphenylene ether resin composite material includes: 70 parts of polyphenylene ether resin (PPO) and 10 parts of elastomer are added from the first weight loss feeder port, 8 parts of flame retardant, 1 part of polyolefin, 10.7 parts Functional masterbatch, 0.2 parts of primary antioxidant and 0.1 part of second...

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Abstract

The invention provides a polyphenylene oxide resin composite material which comprises the following ingredients in parts by weight: polyphenylene oxide resin, an elastomer, a fire retardant, polyolefin, functional master batches, a primary antioxidant and an auxiliary antioxidant, wherein the 10% total weight of the functional master batches comprise the following ingredients by weight percentage:60-79% of resin binders, 20-39% of gas phase nano-silica with a branch structure and 1-3% of a coupling agent; the coupling agent is coated on the surface of the gas phase nano-silica with the branchstructure. On the basis that the excellent property of the polyphenylene oxide resin can be effectively maintained, the polyphenylene oxide resin composite material provided by the invention also hasexcellent high temperature and high pressure resistance and has obviously improved toughness and stress cracking resistance.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a polyphenylene ether resin composite material and a preparation method thereof. Background technique [0002] Polyphenylene ether resin alloys have many excellent properties, such as high modulus, high temperature resistance, creep resistance, self-flammability, etc., and are widely used in electronic appliances, auto parts, communication photovoltaics and other fields. The polyphenylene ether resin with the above properties is also suitable for making cold and hot water supply pipe valves. However, due to the low impact strength, poor toughness and poor stress cracking resistance of polyphenylene ether materials, stress cracking is prone to occur when used in water pipe valves, thus limiting the application of polyphenylene ether materials in the field of water pipe valves. Contents of the invention [0003] The purpose of the present invention is to pr...

Claims

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Application Information

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IPC IPC(8): C08L71/12C08L9/06C08L15/00C08L53/02C08L23/02C08K9/10C08K3/36C08J3/22
CPCC08J3/226C08J2371/12C08J2409/06C08J2415/00C08J2423/02C08J2453/02C08K3/36C08K9/10C08K2201/011
Inventor 杨瑞权吴宪何征徐春生谭目志
Owner SHENZHEN WOTE ADVANCED MATERIALS
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