Iron oxide red pigment production wastewater disposal method

A technology for iron oxide red and waste water production, applied in biological water/sewage treatment, waste paint treatment, multi-stage water treatment, etc., can solve the problems of water pollution, waste, high chroma, etc., achieve zero pollution discharge, and improve resources Utilization rate, the effect of improving economic efficiency

Inactive Publication Date: 2019-02-15
湖南冠一颜料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the production methods of iron oxide red mainly include dry method and wet method. In the production process of preparing iron oxide red by wet method, acidic wastewater containing a large amount of ferrous ions and ammonium roots and a small amount of iron ions will be produced. This wastewater It has the characteristics of high chroma, strong acidity, high concentration of ammonia nitrogen, and high content of ferrous ions. If it is discharged directly, it will cause serious pollution to water bodies and cause waste

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The iron oxide red pigment production wastewater treatment method of the present embodiment may further comprise the steps:

[0019] (1) Collect the wastewater from the production of iron oxide red pigment, and carry out aeration and oxidation treatment with the help of ultrasonic intensified zero-valent iron, and the aeration time is 4 hours;

[0020] (2) Adjust the pH value of the wastewater treated in step (1) to 5.5, flocculate and settle the wastewater, and then press filter to obtain a primary filtrate and a primary filter residue, wherein the filter residue is mainly iron sludge;

[0021] (3) Add crushed egg shells to the primary filtrate treated in step (2). The amount of egg shells added is 2% of the total weight of the primary filtrate. While stirring, the temperature is raised to 55°C, kept for 55 minutes, and then filtered to obtain Secondary filtrate and secondary filter residue;

[0022] (4) Send the secondary filtrate in step (3) into a high-pressure rev...

Embodiment 2

[0025] The iron oxide red pigment production wastewater treatment method of the present embodiment may further comprise the steps:

[0026] (1) Collect the wastewater from the production of iron oxide red pigment, and carry out aeration and oxidation treatment with the help of ultrasonic intensified zero-valent iron, and the aeration time is 3 hours;

[0027] (2), adjusting the pH value of the wastewater treated in step (1) to 6, performing flocculation and sedimentation on the wastewater, and then pressing to obtain a primary filtrate and a primary filter residue, wherein the filter residue is mainly iron sludge;

[0028] (3) Add crushed egg shells to the primary filtrate treated in step (2), the amount of egg shells added is 1% of the total weight of the primary filtrate, heat up to 50°C while stirring, keep warm for 50 minutes, and then filter to obtain Secondary filtrate and secondary filter residue;

[0029] (4) The secondary filtrate in step (3) is sent to a high-pressu...

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Abstract

The invention discloses an iron oxide red pigment production wastewater disposal method which comprises the following steps: collecting wastewater during iron oxide red pigment production for aeratingoxidizing treatment under assisted action of ultrasonic-enhanced zero-valent iron, carrying out flocculating settling on the wastewater, and then carrying out filter pressing to obtain primary filtrate and primary filter residue, wherein the filter residue is primarily iron mud; then adding crushed egg shells into the primary filtrate, and then filtering to obtain secondary filtrate and secondaryfilter residue; and carrying out high pressure reverse osmosis treatment on the secondary filtrate to obtain fresh water and concentrated water, adding a carbon source into the concentrated water, and inoculating nitrifying bacteria, standing still the mixture, settling and filtering. The method achieves cyclic utilization of the wastewater, so that zero pollution emission is achieved, and the economical benefit is improved.

Description

technical field [0001] The invention relates to a method for treating iron oxide red pigment production wastewater, and belongs to the technical field of iron oxide red pigment production. Background technique [0002] Iron oxide red, that is, iron oxide red has good color covering power, tinting power, heat resistance, solvent resistance, acid resistance, non-toxicity, anti-rust and other properties. It is a high-quality pigment variety and can be widely used in paints, inks, plastics, etc. , rubber, textiles, ceramics, art cement, cosmetics, etc. [0003] At present, the production methods of iron oxide red mainly include dry method and wet method. In the production process of preparing iron oxide red by wet method, acidic wastewater containing a large amount of ferrous ions and ammonium roots and a small amount of iron ions will be produced. This wastewater It has the characteristics of high chroma, strong acidity, high concentration of ammonia nitrogen, and high content...

Claims

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): C02F9/14C02F103/14
CPCC02F1/001C02F1/281C02F1/36C02F1/441C02F1/5245C02F3/02C02F3/34C02F9/00C02F2103/14C02F2301/08
Inventor张清敏肖剑张柏梁赵俊海陈启波
Owner湖南冠一颜料有限公司