A kind of anti-atomic oxygen modified prepreg, composite material and preparation method thereof
A technology resistant to atomic oxygen and composite materials, which is applied in epoxy resin coatings, chemical instruments and methods, polyether coatings, etc., can solve the problems of affecting the mechanical properties of materials, material weight gain, insufficient atomic oxygen barrier ability, etc., and achieve improved The effect of interlayer mechanical properties
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[0033] see figure 1 , the embodiment of the present application shows a method for preparing a composite material prepared from an atomic oxygen-resistant modified prepreg, characterized in that the method includes:
[0034] S101 Lay up the atomic oxygen-resistant prepregs in sequence to obtain a prefabricated body;
[0035] S102 The attached thin layer faces one direction so that each layer has a thin layer of atomic oxygen resistance, and the two outer surfaces are not paved or a layer of atomic oxygen resistant thin layer is laid, and then the prepreg molding and curing process conditions are followed. solidified.
[0036] The core of the technical solution of the present invention is to obtain a composite material that is resistant to the barrier effect of atomic oxygen layer by layer. Damage, fatigue or impact delamination damage, pore defects, etc. continue to play a role in blocking atomic oxygen erosion, compatible with existing material systems, and can further impr...
Embodiment 1
[0042] The implementation process of the technical solution of the present invention is as follows:
[0043] (1-1) Dissolve 20g or 35g of polyphenylsulfone diphenylphosphonate (PSPPP) with a number average molecular weight of 25,000 and 25g of phenolphthalein-modified polyaryletherketone (PEK-C) in N,N-bis Methylformamide (DMF), keep the environment dry, cast the solution into a film, control the final film thickness at 16 μm or 25 μm by the amount of solution, blow dry at 80°C for 1 hour, and then vacuum dry at 100°C for 6 hours Or 12 hours, after taking off the film, a thin layer with excellent resistance to atomic oxygen was obtained.
[0044] (1-2) Take the thin layer with excellent atomic oxygen resistance obtained above, and take epoxy resin carbon fiber prepreg, wherein the carbon fiber is T300, 3K or T800, 12K, and the grade of epoxy resin is 5228 (China Aviation Composites Co., Ltd. company product), lay the film on one side of the prepreg, and use a hot iron to make...
Embodiment 2
[0049] The implementation process of the technical solution of the present invention is as follows:
[0050] (2-1) 40g of polyphenylsulfone diphenylphosphonate (PSPPP) with a number average molecular weight of 35,000 or 28g of boron-modified novolac resin with a number average molecular weight of 15,000 or more, and 25g of benzoxazine (BOZ) resin were dissolved together In 120mL of N,N-dimethylformamide, add 1.2g of boron nitride nanosheets or nano-layered silicate clay, add 1g of silane coupling agent, ultrasonically disperse evenly, and set aside. Coating film and controlling the final film thickness, one is 100 μm or 150 μm, the other is 15 μm or 28 μm, after fully drying in the oven, stick the film with a thickness of 15 μm or 28 μm on the benzoxazine (BOZ) resin carbon fiber prepreg The surface of the impregnated material is heated up to 60°C to soften and the two are attached together to obtain a benzoxazine (BOZ) resin carbon fiber prepreg resistant to atomic oxygen.
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