Wear-proof elastic fiber and preparation method thereof

An elastic fiber and thermoplastic elastomer technology, applied in the field of elastic fibers, can solve the problems of destroying the regularity of fibers, large structural differences, and decreasing fiber strength, so as to ensure comprehensive performance, overcome poor compatibility, and improve wear resistance. Effect

Active Publication Date: 2019-07-30
SHANGHAI YITAN NEW MATERIAL CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the large structural difference between branched nylon and conventional nylon, it will destroy the regularity of the fiber, which is not conducive to the improvement of fiber performance, resulting in a decrease in the strength of the fiber.

Method used

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  • Wear-proof elastic fiber and preparation method thereof
  • Wear-proof elastic fiber and preparation method thereof
  • Wear-proof elastic fiber and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] The preparation method of wear-resistant elastic fiber is to extrude the mixture melt composed of TPEE (1) and TPEE (2) at a temperature of 220°C from the spinneret hole with an aspect ratio of 1.5, and then perform slow cooling and then strong cooling Then wear-resistant elastic fiber is obtained by multi-stage stretching. The temperature of slow cooling is 215°C, the temperature of strong cooling is 18°C, the length of slow cooling zone is 10cm, the spinning temperature is 220°C, and the strong cooling adopts ring blowing The way of cooling, the total stretching ratio is 10 times, and the stretching series is 5.

[0049] The mass content of TPEE (1) in the mixture melt is 10wt%, and TPEE (1) and TPEE (2) all are the hard segment of formula (I) and the soft segment of formula (II) by basic structural unit Arranged as follows:

[0050]

[0051] In the formula, R 1 for n is 2, R 2 for R 3 for m is 2;

[0052] The average molecular weight of the soft segment...

Embodiment 2

[0063] The preparation method of wear-resistant elastic fiber is to extrude the mixture melt composed of TPEE(1) and TPEE(2) at a temperature of 150°C from the spinneret hole with an aspect ratio of 1.5, and then perform slow cooling and then strong cooling Then wear-resistant elastic fiber is obtained by multi-stage stretching. The slow cooling temperature is 145°C, the strong cooling temperature is 25°C, the length of the slow cooling zone is 15cm, the spinning temperature is 150°C, and the strong cooling adopts ring blowing The way of cooling, the total stretching ratio is 3 times, and the stretching series is 4.

[0064] The mass content of TPEE (1) in the mixture melt is 40wt%, and TPEE (1) and TPEE (2) all are the hard segment of formula (I) and the soft segment of formula (II) by basic structural unit Arranged, the structural formulas of formula (I) and formula (II) are basically the same as embodiment 1, the difference is that in the formula, R 1 for R 2 for R 3...

Embodiment 3

[0068] The preparation method of wear-resistant elastic fiber is to extrude the mixture melt composed of TPEE (1) and TPEE (2) at a temperature of 180°C from a spinneret hole with an aspect ratio of 2, and then perform slow cooling and then strong cooling Then wear-resistant elastic fiber is obtained by multi-stage stretching. The slow cooling temperature is 180°C, the strong cooling temperature is 15°C, the length of the slow cooling zone is 10cm, the spinning temperature is 180°C, and the strong cooling adopts ring blowing The way of cooling, the total stretching ratio is 6 times, and the stretching series is 4.

[0069] The mass content of TPEE (1) in the mixture melt is 50wt%, and TPEE (1) and TPEE (2) all are the hard segment of formula (I) and the soft segment of formula (II) by basic structural unit Arranged, the structural formulas of formula (I) and formula (II) are basically the same as embodiment 1, the difference is that in the formula, R 1 for n is 8, R 2 for ...

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Abstract

The invention relates to a wear-proof elastic fiber and a preparation method of the wear-proof elastic fiber. The preparation method comprises the steps of extruding mixture melt from a spinneret orifice, and performing slow cooling and forced cooling to form the wear-proof elastic fiber. The mixture melt comprises more than two components; all of the components are thermoplastic elastomers, havethe same molecular weight and are formed by alternating arrangement of soft sections and hard sections; fundamental structural units of the soft sections and fundamental structural units of the hard sections are identical; all of the components have different contents of the soft sections; a maximum mass content of the soft sections is 50-88.9wt%; a minimum mass content of the soft sections is 7.7-46.2wt%; a temperature of the slow cooling is T + / - 5 DEG C; a temperature of the forced cooling is 15-25 DEG C; and the components in the prepared wear-proof elastic fiber are arrayed from an innerlayer to an outer layer of the wear-proof elastic fiber in an ascending order of the mass contents of the soft sections. The method is simple; the components of the prepared fiber are high in compatibility; the wear resistance is improved; at the same time, high mechanical properties are ensured; and the fiber has very good application prospects.

Description

technical field [0001] The invention belongs to the technical field of elastic fibers, in particular to a wear-resistant elastic fiber and a preparation method thereof. Background technique [0002] Because thermoplastic elastic fiber is prepared by melt spinning, there is no problem of solvent use and recycling, soft hand feeling, excellent chlorine resistance and heat resistance, it is deeply loved by consumers, and its proportion in the elastic fiber market is increasing year by year. [0003] It is well known that woven / knitted fabrics containing elastic fibers or products prepared in other forms have good elasticity and shape retention. However, during long-term use with large deformations, there are often severe wear and deformation of some parts, such as Knee joints, elbow joints, underarms and thighs, etc., causing problems such as protrusions, aliasing, fluffing and even damage on the surface of the clothing, especially when used in sportswear, shoe materials, outdo...

Claims

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Application Information

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IPC IPC(8): D01F8/16
CPCD01F8/16
Inventor于金超刘森林南建举张玉梅姬洪张阳甘宇
OwnerSHANGHAI YITAN NEW MATERIAL CO LTD