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Method and device for detecting moisture content of negative electrode sheet

A detection method and detection device technology, applied in the field of lithium-ion batteries, can solve problems such as high freshness requirements, great harm to the human body, and reduced sensitivity, so as to reduce use costs and maintenance costs, reduce production and detection costs, and reduce body weight. Harmful effect

Active Publication Date: 2022-05-03
SVOLT ENERGY TECHNOLOGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the detection method to negative plate moisture that is often adopted is to utilize the Karl-Fisher moisture analyzer to detect. At present, the following disadvantages are mainly contained in this detection method: 1) Karl-Fischer reagent is mainly composed of iodine, sulfur dioxide, pyridine The solution composed of sulfur dioxide and methanol, in which sulfur dioxide and pyridine are extremely volatile, is very harmful to the human body, especially when changing reagents, some operators have insufficient knowledge of the hazards of the reagents, and without any protective measures, There is a great safety hazard in pouring reagents in and out at will; 2) Karl Fischer actually has high requirements for freshness, and it must be stored in the dark to extend the storage period; 3) Calibration of the titer of Karl Fischer reagents Whether it is accurate or not is directly related to the accuracy of sample determination, so titer calibration should be carried out before sample testing every day, and the operation complexity is high; 4) The electrode is a key component of the Karl Fischer moisture analyzer. The pollution on the surface directly leads to the decrease of sensitivity, so sometimes although the pollution on the electrode cannot be seen, it can be observed that the reaction is slow, which directly affects the measurement accuracy

Method used

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  • Method and device for detecting moisture content of negative electrode sheet
  • Method and device for detecting moisture content of negative electrode sheet
  • Method and device for detecting moisture content of negative electrode sheet

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Experimental program
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Embodiment 1

[0082] 1. Establishment of peel strength-moisture content characteristic model

[0083] After the production of the negative electrode sheet is completed, a total of 250 negative electrode sheets are dried and 20 negative electrode sheets are selected as negative electrode sheet samples. The moisture content of the negative electrode sheet samples is measured using a Karl Fischer moisture analyzer, and the friction peeling test is used Machine for 180° peel strength measurement.

[0084] The moisture content and peel strength of 20 negative electrode sheet samples are shown in Table 1.

[0085] Table 1

[0086] Electrode serial number Peel strength (KN / m) Moisture content (ppm) 1 0.0425 300 2 0.057 350 3 0.049 323.1 4 0.049 380 5 0.0575 406 6 0.066 379.4 7 0.061 415.5 8 0.051 319 9 0.042 344.3 10 0.06 411.3 11 0.058 365.6 12 0.06 409 13 0.052 403 14 0.055 380 15 0.045 300 ...

Embodiment 2

[0097] 1. Establishment of peel strength-moisture content characteristic model

[0098] After the production of the negative electrode sheet is completed, a total of 250 negative electrode sheets are dried and 20 negative electrode sheets are selected as negative electrode sheet samples. The moisture content of the negative electrode sheet samples is measured using a Karl Fischer moisture analyzer, and the friction peeling test is used Machine for 180° peel strength measurement.

[0099] The moisture content and peel strength of 20 negative electrode sheet samples are shown in Table 3.

[0100] table 3

[0101]

[0102]

[0103] Carry out curve fitting with the data in above-mentioned table 3, obtain as follows Figure 6 The fitted straight line is shown. Figure 6 It is the fitting straight line diagram in the specific embodiment 2 of the present invention. Among them, the fitting straight line equation is y=2288.3x+254.22, and the fitting degree is 0.40.

[0104] ...

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Abstract

The invention provides a method and a detection device for detecting the moisture content of a negative electrode sheet. The method includes: obtaining a peel strength-moisture content characteristic model; obtaining the peel strength of the negative electrode sheet to be detected; according to the peel strength and the peel strength-moisture content characteristic model, The moisture content of the negative electrode sheet to be tested is obtained. The method for detecting the moisture content of the negative electrode sheet of the present invention is based on the relationship between the moisture content of the negative electrode sheet and the peel strength of the negative electrode sheet, and the moisture content of the negative electrode sheet can be obtained by detecting the peel strength of the negative electrode sheet, thereby reducing the physical harm to the operator and the detection cost. .

Description

technical field [0001] The invention relates to a method and a detection device for detecting the moisture content of a negative electrode sheet, belonging to the technical field of lithium ion batteries. Background technique [0002] In the production process of lithium-ion batteries, the moisture in the production environment must be strictly controlled, otherwise the moisture will react with the electrolyte, resulting in poor capacity, short life, or even direct scrapping of the product. Therefore, accurate detection of moisture in the negative electrode sheet is extremely important. [0003] At present, the detection method to negative plate moisture that is often adopted is to utilize the Karl-Fisher moisture analyzer to detect. At present, the following disadvantages are mainly contained in this detection method: 1) Karl-Fischer reagent is mainly composed of iodine, sulfur dioxide, pyridine The solution composed of sulfur dioxide and methanol, in which sulfur dioxide ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G16C20/20G16C20/70
CPCG06F30/20
Inventor 高旭朴明权苏夏谷传辉李恩光许舟峰
Owner SVOLT ENERGY TECHNOLOGY CO LTD
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