Isothiocyanato-diphenylacetylene
A group, alkyl technology, applied in the field of devices comprising the component
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[0901] The following examples illustrate the invention without limiting it in any way.
[0902] It is clear to those skilled in the art what properties are achievable by physical properties and to what extent they can be modified. In particular, combinations of properties which can preferably be achieved are therefore well defined for the person skilled in the art.
[0903] Synthetic example
[0904] Synthetic Example 1: 1,3-Difluoro-2-isothiocyanato-5-[2-methyl-4-[4-(trifluoromethoxy)phenyl]phenylethynyl]benzene
[0905] step 1 :1-Bromo-2-methyl-4-[4-(trifluoromethoxy)phenyl]benzene
[0906]
[0907] Tetrakis-(triphenylphosphine)-palladium-(0) (2.0 g; 1.7 mmol) was added to 1-bromo-4-iodo-2-methyl-benzene (50.5 g, 170 mmol) and carbonic acid at 80 °C Sodium (43.2g, 408mmol) in a mixture of toluene (250mL) and water (150mL), then dropwise added [4-(trifluoromethoxy)phenyl]boronic acid (35.0g, 170mmol) in ethanol (40mL ) in the solution. The reaction mixture was h...
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