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Ozone generating system and operation method thereof

a technology of ozone generating system and generating system, which is applied in the direction of oxygen/ozone/oxide/hydroxide, electrical discharge ozone preparation, and separation processes, etc., can solve the problems of short circuit between electrodes and reduced ozone generation efficiency, and achieve high-reliability ozone generating system, prevent hno3 from entering the ozone generating apparatus, and suppress corrosion caused by hno3

Active Publication Date: 2019-03-05
MITSUBISHI ELECTRIC CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0020]According to this invention, in an ozone generating operation standby period of an intermittent operation, gas which is sealed in an ozone generating apparatus is circulated to the outside of an ozone generating apparatus, and at least HNO3 is removed from gas which is circulated to the outside, therefore, in an ozone generating operation standby period, diffusion of HNO3 in an ozone generating apparatus can be prevented. Further, in order to leak gas which is sealed in an ozone generating apparatus to the outside of an ozone generating apparatus, a gentle gas flow for one direction at a gas exit side is formed in an ozone generating apparatus, therefore, NOx and HNO3 which is diffused in an ozone generating apparatus does not exit at a gas entrance side of an ozone generating apparatus. Consequently, with respect to a discharge electrode, corrosion caused by HNO3 can be suppressed, as a result, a highly reliable ozone generating system can be obtained.

Problems solved by technology

Especially, when electrode parts are corroded, at the time of restarting, ozone generation efficiency is reduced, and further, in some cases, a short circuit between electrodes may be caused.

Method used

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  • Ozone generating system and operation method thereof
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  • Ozone generating system and operation method thereof

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embodiment 1

[0037]FIGS. 1 to 3 are figures for describing an ozone generating system and its operation method according to Embodiment 1, FIG. 1 is a block diagram showing the configuration of an ozone generating system and its flow line, FIG. 2A and FIG. 2B are cross-sectional views showing the configuration of a discharge electrode part in an ozone generating apparatus, FIG. 2A is a cross-sectional view of a cut section of a discharge electrode part which is parallel to a direction of a gas flow, and FIG. 2B is a cross-sectional view of a discharge electrode part which is perpendicular to a direction of gas flow, taken along the line of A-A in FIG. 2A. FIG. 3 is a time chart for describing an operation of equipment when an ozone generating apparatus is intermittently operated, and FIG. 4 is a flow chart showing an operation of an ozone generating apparatus.

[0038]The configuration of an ozone generating system according to Embodiment 1 will be described. As shown in FIG. 1, an ozone generating ...

embodiment 2

[0063]An ozone generating system according to Embodiment 2 of this invention will be described. A basic configuration and operation of an ozone generating system according to Embodiment 2 is same as that of an ozone generating system according to Embodiment 1, however, there is a different point such that an intermittent operation is performed by operation control of a plurality of ozone generating apparatuses. FIG. 5 is a block diagram for describing an ozone generating system and its operation method according to Embodiment 2, and showing the configuration of an ozone generating system and a gas flow line. Here, a case in which two ozone generating apparatuses are used will be described as an example. In FIGs, a part which is same as or corresponding to the configuration of an ozone generating system according to Embodiment 1 will be given same reference character, and description will be omitted unless it is particularly required. Further, in FIG., a cooing device, a power supply...

embodiment 3

[0069]An ozone generating system according to Embodiment 3 of this invention will be described. A basic configuration and operation of an ozone generating system according to Embodiment 3 is same as that of an ozone generating system according to Embodiment 1 and Embodiment 2, however, there is a different point such that in an ozone generating apparatus according to Embodiment 1 and Embodiment 2, a high voltage electrode tube of the ozone generating apparatus 2 is one ground electrode tube, on the other hand, in Embodiment 3, two high voltage electrode tubes are provided in serial so as for closed end parts of the high voltage electrode tubes to face each other. FIG. 6 is a cross-sectional view showing the configuration of a discharge electrode part in the ozone generating apparatus 2 according to Embodiment 3 of this invention, and is a section view in a cut section which is parallel to gas flow direction in a discharge electrode part. In FIG., a part which is same as or correspon...

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Abstract

In an ozone generating system which performs intermittent operation, that is, an operation in an ozone generating operation period in which ozone is generated by discharging gas including oxygen at a discharge electrode part and an operation in an ozone generating operation standby period in which ozone is not generated by stopping discharge are alternately repeated, a gas circulating device which circulates gas in the ozone generating apparatus and removes at least nitric acid from the gas which is circulated is connected to the ozone generating apparatus.

Description

TECHNICAL FIELD[0001]This invention relates to an ozone generating system using an ozone generating apparatus for generating ozone by using discharge and its operation method.BACKGROUND ART[0002]In an ozone generating apparatus in which ozone (O3) is generated using gas including oxygen as a material gas by using discharge, it is generally known such that nitrogen oxide (NOx) is by-produced when ozone is generated. Further, nitrogen oxides (NOx) which is by-produced is under the coexistence of ozone, most of nitrogen oxides (NOx) is present as the structure of dinitrogen pentoxide (N2O5). Dinitrogen pentoxide (N2O5) is a subliming material which becomes a solid at room temperatures lower than 30 degrees, therefore dinitrogen pentoxide (N2O5) easily changes its phase between a solid and gas. However, under ordinary operation conditions, it is very probable such that dinitrogen pentoxide (N2O5) is attached to almost whole area of discharge space as a discharge product.[0003]On the oth...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): C01B13/11B01D53/56
CPCC01B13/115B01D53/56C01B13/11C01B2201/90C01B2201/22C01B2201/64C01B2201/76C01B2201/10C01B2201/12
Inventor WADA, NOBORUINANAGA, YASUTAKA
Owner MITSUBISHI ELECTRIC CORP