White light apparatus with enhanced color contrast
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[0106] Various LED based light devices based on violet chip with emission maximum near 405 nm and using phosphor blends according to the above embodiments were investigated and compared to identical light sources also including a Nd glass filter of average thickness 1 mm and containing 7.5% Nd2O3 by weight. A summary of photometric characteristics (luminous flux Iv, 1931 CIE coordinates x and y, CCT and CRI values) of these devices is shown in Table 1. The yellow phosphor used in LED samples 1 through 10 was an alkali earth silicate doped with Eu(II) and corresponding to the formula Sr1.66Ca0.30Eu0.04Si0.96O3.92. The blue and green phosphors (Ca,Sr,Ba)5(PO4)3Cl:Eu2+, (Ba0.65Sr0.20Ca0.10Eu0.05)2SiO4 and Sr4Al14O25:Eu2+also used, as needed to achieve the requisite CCTs ranging from 2500 to 7500K prior to filtration. In addition, sample #7 contained a deep red line emitting phosphor (3.5 MgO*0.5 MgF2*GeO2:Mn4+) whereas samples #4-#6 and #8-#10 contained a deep red broadband phosphor (C...
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