Electric-conductive super-hydrophobic paint and preparation method thereof

Abstract

The invention relates to electric-conductive super-hydrophobic paint. The electric-conductive super-hydrophobic paint is obtained by mixing a component A and a component B according to a weight ratioof 10:(1-5), wherein the component A comprises the following preparation raw materials: epoxy resin E44, polyurethane emulsion, polytetrafluoroethylene emulsion, sulfonated graphene oxide, cyclodextrin modified polyester coated nano yttrium oxide, a cyclodextrin modified polyester coated carbon nano tube and a solvent C; and the component B comprises the following preparation raw materials: polyether amine grafted with hyaluronic acid, 1-methyl-4-aminoimidazole, hexamethylenediamine and a solvent D. The invention further relates to a preparation method for the electric-conductive super-hydrophobic paint. The electric-conductive super-hydrophobic paint is good in cleaning property, anti-pollution and good in conductivity, and has good market prospect.

Description

technical field

[0001] The invention relates to the technical field of coatings, in particular to a conductive superhydrophobic coating and a preparation method thereof. Background technique

[0002] With the development of the defense industry, daily necessities, and medical equipment, the demand for super-hydrophobic conductive coatings is increasing. Currently, there have been reports on superhydrophobic conductive coatings. For example, patent CN101108947A uses inorganic conductive filler as the coating of conductive filler, but the compatibility of inorganic filler and resin becomes poor, so that the mechanical properties of the paint film decline; patent CN102070960A uses conductive polymer as the coating of conductive filler, but the cost is higher. Patent CN1704191A adopts metal powder as the conductive filler of coating, but its corrosion resistance is not good.

[0003] For this reason, process development is required to improve formulations and obtain new coatin...

Examples

Embodiment 1

[0038] In parts by weight, 15 parts of epoxy resin E44, 6 parts of polyurethane emulsion, 7 parts of polytetrafluoroethylene emulsion, 13 parts of sulfonated graphene oxide, 7 parts of cyclodextrin modified polyester coated nanometer yttrium oxide, cyclodextrin Add 6 parts of dextrin-modified polyester-coated carbon nanotubes and 120 parts of solvent C (a mixture of dimethyl sulfoxide and N, N-dimethylformamide in a weight ratio of 1:2) to a mixer, and mix thoroughly Get component A;

[0039] In parts by weight, 15 parts of polyetheramine grafted with hyaluronic acid, 5 parts of 1-methyl-4-aminoimidazole, 3 parts of hexamethylenediamine and solvent D (propylene glycol methyl ether and N, N-dimethyl 38 parts of the mixture of acetamide in a weight ratio of 1:1 were added to the mixer, and component B was obtained after thorough mixing;

[0040] Mix component A and component B in a weight ratio of 5:1 to obtain a conductive superhydrophobic coating;

[0041] Wherein, the prepa...

Embodiment 2

[0052] In parts by weight, 15 parts of epoxy resin E44, 6 parts of polyurethane emulsion, 7 parts of polytetrafluoroethylene emulsion, 13 parts of sulfonated graphene oxide, 7 parts of nanometer yttrium oxide (average particle diameter 300 nanometers), 7 parts of carbon nanotube (Average particle size 800 nanometers) 6 parts and solvent C (a mixture of dimethyl sulfoxide and N, N-dimethylformamide in a weight ratio of 1:2) 120 parts were added to the mixer, and component A was obtained after thorough mixing ;

[0053] In parts by weight, 15 parts of polyetheramine grafted with hyaluronic acid, 5 parts of 1-methyl-4-aminoimidazole, 3 parts of hexamethylenediamine and solvent D (propylene glycol methyl ether and N, N-dimethyl 38 parts of the mixture of acetamide in a weight ratio of 1:1 were added to the mixer, and component B was obtained after thorough mixing;

[0054] Mix component A and component B in a weight ratio of 5:1 to obtain a conductive superhydrophobic coating;

...

Embodiment 3

[0060] In parts by weight, 15 parts of epoxy resin E44, 6 parts of polyurethane emulsion, 7 parts of polytetrafluoroethylene emulsion, 13 parts of sulfonated graphene oxide, 7 parts of cyclodextrin modified polyester coated nanometer yttrium oxide, cyclodextrin Add 6 parts of dextrin-modified polyester-coated carbon nanotubes and 120 parts of solvent C (a mixture of dimethyl sulfoxide and N, N-dimethylformamide in a weight ratio of 1:2) to the mixer, and mix thoroughly Get component A;

[0061] In parts by weight, 15 parts of polyetheramine, 5 parts of 1-methyl-4-aminoimidazole, 3 parts of hexamethylenediamine and solvent D (a mixture of propylene glycol methyl ether and N, N-dimethylacetamide by weight 1:1 ratio) Add 38 parts into the blender, mix thoroughly to get component B;

[0062] Mix component A and component B in a weight ratio of 5:1 to obtain a conductive superhydrophobic coating;

[0063] Wherein, the preparation method of described sulfonated graphene oxide is: ...

technical field

[0001] The invention relates to the technical field of coatings, in particular to a conductive superhydrophobic coating and a preparation method thereof. Background technique

[0002] With the development of the defense industry, daily necessities, and medical equipment, the demand for super-hydrophobic conductive coatings is increasing. Currently, there have been reports on superhydrophobic conductive coatings. For example, patent CN101108947A uses inorganic conductive filler as the coating of conductive filler, but the compatibility of inorganic filler and resin becomes poor, so that the mechanical properties of the paint film decline; patent CN102070960A uses conductive polymer as the coating of conductive filler, but the cost is higher. Patent CN1704191A adopts metal powder as the conductive filler of coating, but its corrosion resistance is not good.

[0003] For this reason, process development is required to improve formulations and obtain new coatin...

Examples

Embodiment 1

[0038] In parts by weight, 15 parts of epoxy resin E44, 6 parts of polyurethane emulsion, 7 parts of polytetrafluoroethylene emulsion, 13 parts of sulfonated graphene oxide, 7 parts of cyclodextrin modified polyester coated nanometer yttrium oxide, cyclodextrin Add 6 parts of dextrin-modified polyester-coated carbon nanotubes and 120 parts of solvent C (a mixture of dimethyl sulfoxide and N, N-dimethylformamide in a weight ratio of 1:2) to a mixer, and mix thoroughly Get component A;

[0039] In parts by weight, 15 parts of polyetheramine grafted with hyaluronic acid, 5 parts of 1-methyl-4-aminoimidazole, 3 parts of hexamethylenediamine and solvent D (propylene glycol methyl ether and N, N-dimethyl 38 parts of the mixture of acetamide in a weight ratio of 1:1 were added to the mixer, and component B was obtained after thorough mixing;

[0040] Mix component A and component B in a weight ratio of 5:1 to obtain a conductive superhydrophobic coating;

[0041] Wherein, the prepa...

Embodiment 2

[0052] In parts by weight, 15 parts of epoxy resin E44, 6 parts of polyurethane emulsion, 7 parts of polytetrafluoroethylene emulsion, 13 parts of sulfonated graphene oxide, 7 parts of nanometer yttrium oxide (average particle diameter 300 nanometers), 7 parts of carbon nanotube (Average particle size 800 nanometers) 6 parts and solvent C (a mixture of dimethyl sulfoxide and N, N-dimethylformamide in a weight ratio of 1:2) 120 parts were added to the mixer, and component A was obtained after thorough mixing ;

[0053] In parts by weight, 15 parts of polyetheramine grafted with hyaluronic acid, 5 parts of 1-methyl-4-aminoimidazole, 3 parts of hexamethylenediamine and solvent D (propylene glycol methyl ether and N, N-dimethyl 38 parts of the mixture of acetamide in a weight ratio of 1:1 were added to the mixer, and component B was obtained after thorough mixing;

[0054] Mix component A and component B in a weight ratio of 5:1 to obtain a conductive superhydrophobic coating;

...

Embodiment 3

[0060] In parts by weight, 15 parts of epoxy resin E44, 6 parts of polyurethane emulsion, 7 parts of polytetrafluoroethylene emulsion, 13 parts of sulfonated graphene oxide, 7 parts of cyclodextrin modified polyester coated nanometer yttrium oxide, cyclodextrin Add 6 parts of dextrin-modified polyester-coated carbon nanotubes and 120 parts of solvent C (a mixture of dimethyl sulfoxide and N, N-dimethylformamide in a weight ratio of 1:2) to the mixer, and mix thoroughly Get component A;

[0061] In parts by weight, 15 parts of polyetheramine, 5 parts of 1-methyl-4-aminoimidazole, 3 parts of hexamethylenediamine and solvent D (a mixture of propylene glycol methyl ether and N, N-dimethylacetamide by weight 1:1 ratio) Add 38 parts into the blender, mix thoroughly to get component B;

[0062] Mix component A and component B in a weight ratio of 5:1 to obtain a conductive superhydrophobic coating;

[0063] Wherein, the preparation method of described sulfonated graphene oxide is: ...