This invention belongs to the field of inorganic luminescent materials technology, and discloses a
germanate-based long
afterglow luminescent material, its preparation method, and its uses. This
luminescent material uses MReGeO4 (M = Li or Na, Re = Y, Lu or Gd) as a matrix, and introduces Bi
dopant ions. 3+ and Ln 3+ Obtained; and the
chemical formula of the
luminescent material is M 1‑x Re 1‑y GeO4:xBi 3+ ,yLn 3+ Where x is the
dopant ion Bi 3+ The proportion of
alkali metal ions Li in the matrix + Or Na + The
molar doping concentration is given by , and 0 < x ≤ 0.010; y is the
molar doping concentration of Ln. 3+ The proportion of ions (Ln = one of Eu, Tb, Pr or Yb) in the Re content of the matrix 3+ The
molar doping concentration is such that 0 ≤ y ≤ 0.001. Based on trap
engineering and bandgap
engineering, this invention achieves the modulation of multimode
fluorescence properties such as
photoluminescence,
afterglow, and photo / thermal excited
fluorescence. In particular, it realizes dynamic
information storage and
encryption of multicolor multimode fluorescent printing, providing a material basis and physical prototype for next-generation fluorescent printing
information storage and anti-counterfeiting technology.