The invention relates to a
sulfur-containing
ether polyamine as well as a preparation method and application thereof, a
chlorine-resistant anti-oxidation
sulfur-containing
ether separation membrane and a preparation method thereof, and belongs to the field of
macromolecule materials. The invention provides a preparation method of
sulfur-containing
ether polyamine. The preparation method comprisesthe following steps: preparing a semi-aromatic poly-halogenated
amide monomer; purifying a crude product of the semi-aromatic poly-halogenated
amide monomer; preparing a sulfur-containing ether
polyamine monomer; purifying a sulfur-containing ether polyamine solution.
Polyamine with a reducing group of a high content, namely a sulfur ether (-S-), is synthesized for a first time, the reducing sulfur ether structure of the high content is capable of reacting with active
chlorine, and most oxidative
chlorine in a separation membrane oxidation treatment process can be consumed; meanwhile, by virtue of multiple amino groups and
acyl chloride in a molecular chain, a multi-crosslinking structure can be formed, and the strength of an interface separation layer can be further improved, so that theseparation efficiency and properties of the separation membrane can be maintained, the service life of the separation membrane can be greatly prolonged, and the use cost of the separation membrane canbe reduced.