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Fusible polyacrylonitrile resin in low melting point

A technology of polyacrylonitrile resin and low melting point is applied in the field of fusible polyacrylonitrile resin to avoid decomposition, increase melt index and improve flow performance.

Inactive Publication Date: 2007-11-14
SINOPEC SHANGHAI PETROCHEMICAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention provides a meltable polyacrylonitrile resin with a low melting point. The technical problem to be solved is to require the meltable polyacrylonitrile resin to have a processing melting point lower than 200°C. The resin will not have adverse effects on the performance of the product

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Take the meltable polyacrylonitrile resin and additives and add them into a 2L open container equipped with a stirring device according to the required weight ratio, and stir for about 15 minutes until the additives and the resin are mixed evenly. If the additives are lumpy, first crush the additives into powder or fine particles, and the particle size is required to be no more than 200 mesh.

[0019] Fusible polyacrylonitrile resin is a copolymer of acrylonitrile and methyl methacrylate, based on the total amount of all polymerized units, the content of methyl methacrylate in the copolymer is 1.5% by weight, and the viscosity-average molecular weight of the resin is It is 4000, the melting point of the resin is 240°C, and the melt index measured at 240°C is 11g / 10 minutes.

Embodiment 2～8

[0021] Fusible polyacrylonitrile resin is the copolymer of acrylonitrile and acrylonitrile, based on the total amount of all polymerized units, the content of acrylonitrile in the copolymer is 14% by weight, and the viscosity-average molecular weight of polyacrylonitrile resin is 3500 . All the other are the same as embodiment 1

[0022] The specific additives used in each embodiment, the weight ratio of additives and polyacrylonitrile resin mixed, and the melting point and melt index of the mixture are listed in Table 1.

[0023] Further with the low-melting-point fusible polyacrylonitrile resin that embodiment 2~8 obtains as raw material, adopt the technique of melt spinning to carry out spinning, make the acrylic fiber of 1.46 dtex, test the breaking strength and breaking elongation of fiber, its result sees Table 2.

[0024] Table 1.

[0025] Additives

Additives / Resins

(weight ratio)

melting point

(℃)

Melt Index

(g / 10min)

...

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Abstract

A fusible polyacrylonitrile resin with low fusion point (lower than 200 deg.C) is proportionally prepared from a solid additive and a fusible polyacrylonitrile resin through mechanical mixing. Said additive is chosen from sweet alcohol, hydroquinone and their mixture. Said fusible polyacrylonitrile resin is the copolymer of acrylonitrile and the second unit chosen from perspex, methylacrylonitrile and butenenitrile.

Description

technical field [0001] The invention relates to a meltable polyacrylonitrile resin, in particular to a low melting point meltable polyacrylonitrile resin obtained by adding solid additives. Background technique [0002] Polyacrylonitrile resin is a high polymer with a wide range of uses, especially the performance of fibers made of polypropylene resin is similar to that of wool, and it occupies a large proportion in the total production of synthetic fibers. However, a defect of polyacrylonitrile resin is that the melting point (theoretical value is 319°C) is higher than the decomposition temperature (generally 250°C), so it cannot be processed by melting, and polyacrylonitrile fibers can usually only be processed by solution spinning. This spinning method uses a large amount of toxic, harmful or corrosive solvents. During the production process, the solvent must be recovered and purified, and the fibers must be washed and dried. Therefore, the process is complicated and the ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L33/20C08K5/13
Inventor 李荣安季春晓杜欣庄王雁周涛
Owner SINOPEC SHANGHAI PETROCHEMICAL CO LTD