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Ionomer resin, resin compositions containing same and uses of both

A technology of ionomer resin and resin composition, which is applied in the field of ionomer resin and resin composition containing the ionomer resin, can solve the problem of damage to the balance of mechanical properties, the decline of impact resistance, mechanical properties, and mechanical properties. Reduced strength and other problems, to improve the effect of extensional viscosity

Active Publication Date: 2011-07-20
MITSUI CHEM INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, due to the low compatibility between polypropylene and ethylene-based ionomer resins, phase separation occurs in molded products, and there is a problem that the balance of mechanical properties such as rigidity, ductility, and impact resistance is significantly lowered.
[0006] In addition, in the method (2), although strain curability can be imparted, there is a problem that the balance of mechanical properties is impaired due to the low compatibility between polypropylene and ultra-high molecular weight polyethylene.
[0007] In the method (3), when a peroxide is used, the main chain of polypropylene is decomposed at the same time as the branched structure is introduced. Food hygiene problems caused by odor of peroxides, undecomposed peroxide residues, etc.
In addition, when irradiation with electron beams is used, there are problems in that a large-scale device is required; mechanical strength is lowered along with a decrease in crystallinity due to the introduction of a branched structure; and it is difficult to recycle
However, in order to impart sufficient strain curability to polypropylene, the effect is poor when added in a small amount. Conversely, if the ionomer resin is added in a large amount to the extent that strain curability is exhibited, there is a problem that the mechanical strength decreases.

Method used

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  • Ionomer resin, resin compositions containing same and uses of both
  • Ionomer resin, resin compositions containing same and uses of both
  • Ionomer resin, resin compositions containing same and uses of both

Examples

Experimental program
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Effect test

Embodiment

[0151] The present invention will be described more specifically below using examples, but the present invention is not limited to these examples. In the present invention, various physical properties were measured by the following methods.

[0152] (1) Melt flow rate (MFR)

[0153] The melt flow rate (MFR) of various resin compositions is measured in accordance with ASTM D1238 when using a propylene-based polymer at a temperature of 230°C and a load of 2.16kg. When using 4-methyl-1-pentane In the case of an ethylenic polymer, the measurement was performed under conditions of a temperature of 260°C and a load of 5.0 kg.

[0154] (2) Tensile properties (tensile modulus, elongation at break)

[0155] The tensile modulus and elongation at break were obtained by performing a tensile test at 23° C. and a tensile speed of 30 mm / min by a method based on JIS K7113.

[0156] (3) Bending characteristics (bending modulus)

[0157] The flexural modulus was determined by performing a f...

Embodiment 1

[0198] Except having used the metal salt of the compounding quantity shown in Table 1 as metal salt (B), it carried out similarly to the comparative example 1, and obtained the pellet (a2) and the test piece. Using the pellets and the test piece, various physical properties were evaluated. The results are shown in Table 1.

Embodiment 2

[0200] Except having used the metal salt of the compounding quantity shown in Table 1 as metal salt (B), it carried out similarly to the comparative example 1, and obtained the pellet (a3) ​​and the test piece. Using the pellets and the test piece, various physical properties were evaluated. The results are shown in Table 1.

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Abstract

Provided are an ionomer resin which is well-balanced between processability in molding and mechanical properties and which can form olefin molded articles; resin compositions containing the same; and molded articles of the ionomer resin or the resin compositions. An ionomer resin (X1) formed from (A) 100 parts by weight of an olefin polymer which comprises constituent units derived from an a-olefin having 2 to 20 carbon atoms and has a functional group (alpha) and (B) 0.01 to 100 parts by weight of a metal salt having two or more functional groups (b).

Description

technical field [0001] The present invention relates to an ionomer resin and a resin composition containing the ionomer resin, more specifically, to an ionomer resin with improved extensional viscosity and a resin composition containing the ionomer resin . The ionomer resin of the present invention and the resin composition containing the ionomer resin are suitably used as, for example, blow molding products, foam molding products, or resin modified materials. Background technique [0002] Polypropylene generally has a lower melt viscosity than polyethylene, and is known as a material that does not exhibit "strain curability" in which viscosity increases with strain when uniaxial tensile deformation is imparted. On the other hand, in specific molding methods such as blow molding, foam molding, and vacuum molding, materials showing strain hardening properties are suitable from the viewpoint of molding processability. In this sense, polypropylene is considered to be unsuitab...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/26B29C45/00B29C49/00C08J5/18C08J9/00C08K3/00C08K5/00C08L23/00B29K23/00B29K96/02B29K105/04
CPCC08K5/098C08L2203/16C08L23/0876C08L2666/06B29C49/06B29C49/04B29C49/0005C08F8/44C08L23/02C08L2205/02C08K5/175Y10T428/269B29C2949/0715C08L51/06C08F255/02C08L23/26C08L23/00C08J5/18C08J9/00
Inventor 田中宏和小野木隆行大地广泰池永成伸
Owner MITSUI CHEM INC
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