68 results about "Extensional viscosity" patented technology

The invention is directed to essentially saturated hydrocarbon polymer composition comprising essentially saturated hydrocarbon polymers having A) a backbone chain, B) a plurality of essentially hydrocarbyl sidechains connected to A), said sidechains each having a number-average molecular weight of from 2500 Daltons to 125,000 Daltons and a MWD by SEC of 1.0-3.5; and having A) a Newtonian limiting viscosity (eta0) at 190° C. at least 50% greater than that of a linear olefinic polymer of the same chemical composition and weight average molecular weight, preferably at least twice as great as that of said linear polymer, B) a ratio of the rubbery plateau modulus at 190° C. to that of a linear polymer of the same chemical composition less than 0.5, preferably <0.3, C) a ratio of the Newtonian limiting viscosity (eta0) to the absolute value of the complex viscosity in oscillatory shear (eta*)at 100 rad / sec at 190° C. of at least 5, and D) a ratio of the extensional viscosity measured at a strain rate of 1 sec-1, 190° C., and time=3 sec (i.e., a strain of 3) to that predicted by linear viscoelasticity at the same temperature and time of 2 or greater. Ethylene-butene prepared by anionic polymerization and hydrogenation illustrate and ethylene-hexene copolymers prepared by coordination polymerization illustrate the invention. The invention polymers exhibit improved processing characteristics in that the shear thinning behavior closely approaches that of ideal polymers and exhibit improved strain thickening.

Non-thermoplastic starch fibers having no melting point and having apparent peak wet tensile stress greater than about 0.2 MegaPascals (MPa). The fibers can be manufactured from a composition comprising a modified starch and a cross-linking agent. The composition can have a shear viscosity from about 1 Pascal·Seconds to about 80 Pascal·Seconds and an apparent extensional viscosity in the range of from about 150 Pascal·Seconds to about 13,000 Pascal·Seconds. The composition can comprise from about 50% to about 75% by weight of a modified starch; from about 0.1% to about 10% by weight of an aldehyde cross-linking agent; and from about 25% to about 50% by weight of water. Prior to cross-linking, the modified starch can have a weight average molecular weight greater than about 100,000 g / mol.

A propylene-based polymer comprising the following component (A) insoluble in p-xylene at 25° C. and component (B) soluble in p-xylene at 25° C., wherein (i) the weight average molecular weight (Mw) measured with GPC is 100,000 to 1,000,000, (ii) the content of the component insoluble in hot p-xylene is 0.3% by weight or lower, and (iii) the degree of strain hardening (λ max) in measurement of elongational viscosity is 2.0 or higher; and a method for producing the same, along with a resin composition comprising a propylene-ethylene copolymer (Z) in an amount of 50.0 to 99.9% by weight and a propylene-based polymer (M) in an amount of 0.1 to 50.0% by weight.Component (A): a component (CXIS) insoluble in p-xylene at 25° C., having requirements specified by (A1) to (A5). Component (B): a component (CXS) is soluble in p-xylene at 25° C., having requirements specified by (B1) to (B4).

A polypropylene-based resin composition is provided that can provide a foam molding that exhibits an excellent closed cell characteristic and excellent extrusion characteristics, that is light weight and has a rigid feel, and that has an excellent recyclability.This polypropylene-based resin composition contains 100 weight % or is less than 100 weight % but at least 70 weight % of component (A) below and contains 0 weight % or is greater than 0 weight % but not more than 30 weight % of component (B) below,component (A):a propylene-based resin composition that comprises at least the following two components: a propylene-α-olefin copolymer (A1) satisfying conditions (A-1) to (A-3) and a propylene homopolymer (A2), (A1) and (A2) being obtained by polymerization by a multistage polymerization method, and this propylene-based resin composition having a content of (A1) of 1 to 20 weight % and a content of (A2) of 99 to 80 weight %, having a melt flow rate in the range from 5 to 20 g / 10 minutes and exhibiting strain hardening in a measurement of extensional viscosity at a temperature of 180° C. and a strain rate of 10 s−1,(A-1) an α-olefin content of 15 to 85 weight %,(A-2) an intrinsic viscosity η of 5 to 20 dL / g,(A-3) a Mw / Mn of 5 to 15;component (B):a propylene-based resin composition comprising at least the following two components: a propylene homopolymer or a propylene-α-olefin copolymer having a content of non-propylene α-olefin of less than 1 weight % (B1), which has an MFR of 10 to 1000 g / 10 minutes, and a propylene-α-olefin copolymer (B2) that has a weight-average molecular weight of 500,000 to 10,000,000 and a content of non-propylene α-olefin of 1 to 15 weight %, (B1) and (B2) being obtained by polymerization by a multistage polymerization method, and this propylene-based resin composition having a content of (B1) of 50 to 90 weight % and a content of (B2) of 50 to 10 weight %, and satisfying prescribed conditions (B-1) to (B-3).

A propylene-based polymer which is suitably applicable to foam molding, sheet molding, blow molding or the like, because of having good flow characteristics, high melt tension, high swell ratio and thus good molding workability.It is attained by a propylene-based polymer or the like characterized by satisfying the following requirements (i) to (vi).Requirement (i): MFR is 0.1 g / 10 minutes to 100 g / 10 minutes.Requirement (ii): Q value by GPC is 3.5 to 10.5.Requirement (iii): ratio of components with a molecular weight of equal to or higher than 2,000,000, in a molecular weight distribution curve obtained by GPC, is equal to or larger than 0.4% by weight and less than 10% by weight.Requirement (iv): components, which elute at a temperature of equal to or lower than 40° C., are equal to or less than 3.0% by weight, in temperature rising elution fractionation by ODCB.Requirement (v): isotactic triad fraction (mm) measured with 13C-NMR is equal to or higher than 95%.Requirement (vi): strain hardening degree (λmax), in measurement of extensional viscosity, is equal to or higher than 6.0.

A chewing gum, when chewed, produces a cud having improved removability from environmental surfaces by virtue of its extensional viscosity strain hardening parameter. Specifically, the cud has a extensional strain hardening parameter of less than zero or greater than 2.0.