51results about How to "High melt tension" patented technology

The present invention provides a fluoropolymer that is melt-processible and thermoplastic and that has a melting point between 100° C. and 320° C. The fluoropolymer is derived from (a) one or more gaseous fluorinated monomers, (b) one or more modifiers selected from (i) olefins having a bromine or iodine atom bonded to a carbon of the double bond of the olefin, (ii) olefins corresponding to formula (I):Xa2C═CXa—Rf—Br  (I)wherein each Xa independently represents hydrogen, fluorine, bromine, chlorine or iodine, Rf is a perfluoroalkylene group, typically having 1 to 8 carbon atoms, a perfluorooxyalkylene group or a perfluoropolyether group and (iii) mixtures thereof; and (c) optionally one or more comonomers selected from non-gaseous fluorinated monomers and non-fluorinated monomers. The resulting fluoropolymer has long chain branches. The invention further provides a method for making these polymers.

The present invention relates to a hollow molded foam article in which a plurality of polypropylene resins are used as the base resin, and to a process for the production of this hollow molded foam article. More particularly, the present invention relates to a polypropylene resin hollow molded foam article having a foam layer, in which the base resin comprises (a) a polypropylene resin with a melt tension of at least 98 mN and a melt flow rate of 0.5 to 15 g / 10 minutes, (b) a polypropylene resin with a melt tension of less than 30 mN (excluding O) and a melt flow rate of 2 to 30 g / 10 minutes, and (c) a polypropylene resin with a melt tension of at least 30 mN and less than 98 mN and a melt flow rate of 2 to 15 g / 10 minutes, formed by positioning in a mold a softened cylindrical foam having a foam layer obtained by extruding from the die of an extruder a foamable molten resin composition containing a foaming agent, wherein the melt tension at 230° C. of the polypropylene resin that forms the foam layer is at least 10 mN and less than 49 mN, and the apparent density of the foam layer is no more than 0.3 g / cm3.

The purpose of the present invention is to provide: a semiaromatic polyamide which has excellent heat resistance, chemical resistance and mechanical characteristics, while exhibiting moldability that is suitable for various component materials for automobiles and the like; and a molded article of this semiaromatic polyamide. A semiaromatic polyamide (I) of the present invention contains 35-50% by mole of a structural unit derived from terephthalic acid [A], 25-40% by mole of a structural unit derived from isophthalic acid [B], 15-35% by mole of a structural unit derived from an aliphatic dicarboxylic acid [C] (provided that the total of [A], [B] and [C] is 100% by mole), and a structural unit derived from an aliphatic diamine [D] having 4-12 carbon atoms. The molar ratio ([A] / [B]) is from 65 / 35 to 50 / 50, and the molar ratio ([C] / [B]) is from 30 / 70 to 50 / 50. The melting enthalpy (∆H) of the semiaromatic polyamide (I) as determined by differential scanning calorimetry (DSC) is 20-40 mJ / mg, and the limiting viscosity [η] of the semiaromatic polyamide (I) is 0.7-1.6 dl / g.

The process for producing an olefin polymer according to the present invention is characterized in that it comprises polymerizing an olefin having 3 or more carbon atoms in the presence of a catalyst for olefin polymerization containing a solid titanium catalyst component (I) which contains titanium, magnesium, halogen, and a cyclic ester compound (a) specified by the following formula (1):wherein n is an integer of 5 to 10,R2 and R3 are each independently COOR1 or a hydrogen atom, and at least one of R2 and R3 is COOR1; and R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms, anda single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is a hydrogen atom) in the cyclic backbone may be replaced with a double bond, andan organometallic compound catalyst component (II),at an internal pressure of the polymerization vessel which is 0.25 times or more as high as the saturation vapor pressure of the olefin at a polymerization temperature.According to this process, an olefin polymer having a broad molecular weight distribution can be prepared.

A propylene-based polymer which is suitably applicable to foam molding, sheet molding, blow molding or the like, because of having good flow characteristics, high melt tension, high swell ratio and thus good molding workability.It is attained by a propylene-based polymer or the like characterized by satisfying the following requirements (i) to (vi).Requirement (i): MFR is 0.1 g / 10 minutes to 100 g / 10 minutes.Requirement (ii): Q value by GPC is 3.5 to 10.5.Requirement (iii): ratio of components with a molecular weight of equal to or higher than 2,000,000, in a molecular weight distribution curve obtained by GPC, is equal to or larger than 0.4% by weight and less than 10% by weight.Requirement (iv): components, which elute at a temperature of equal to or lower than 40° C., are equal to or less than 3.0% by weight, in temperature rising elution fractionation by ODCB.Requirement (v): isotactic triad fraction (mm) measured with 13C-NMR is equal to or higher than 95%.Requirement (vi): strain hardening degree (λmax), in measurement of extensional viscosity, is equal to or higher than 6.0.

A water-soluble polyvinyl alcohol resin fiber obtained by melt-spinning a material containing as the main component a water-soluble polyvinyl alcohol resin having 1,2-diol structural units represented by the general formula (1); and nonwoven fabrics made by using the fiber. The resin is excellent in the solubility in water at low temperature and is depressed in the bubbling as observed in being dissolved in water. Additionally, the invention permits the use of completely saponified PVA in melt forming, which brings about a depression in the production of acetic acid smell and an improve in the working atmosphere: [Chemical formula 1] (1) wherein R<1>, R<2>, R<3>, R<4>, R<5> and R<6> are each hydrogen or a monovalent organic group and may be the same or different from each other; and X is a single bond or a connecting chain].

Colored aromatic polycarbonate resin compositions are prepared by dispersing a colorant (b) selected from phthalocyanine-based compounds, anthraquinone-based compounds and ultramarine blue in a polyalkyleneglycol compound (c) having a number-average molecular weight of 62 to 4000 of formula (2):HO—[—CHR1—CHR2—]m—OH  (2)where R1, R2, R3 and R4 are independently hydrogen atoms or alkyl groups, and m is not less than 1. The dispersion is added to an aromatic polycarbonate resin (a) kept in a molten state which has a viscosity-average molecular weight of not less than 16000 and contains a branched constitutional unit of formula (1):in an amount of 0.3 to 0.95 mol % where X is a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, or a divalent connecting group —O—, —S—, —CO—, —SO— and —SO2—.

The purpose of the invention is to provide an ethylene-α-olefin copolymer, which has a high melt tension but a small neck-in, and a molded object produced by extrusion molding of the copolymer. An ethylene-α-olefin copolymer having a monomer unit based on ethylene and a monomer unit based on an α-olefin having 3 to 20 carbon atoms, which has a melt flow rate (MFR) of 0.1 to 100 g / 10 min, a density (d) of 850 to 940 kg / m3, a ratio (Mw / Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) of 2 to 12, and a value g* defined by the following formula (I) of 0.50 to 0.75:g*=[η] / ([η]GPC×gSCB*)  (I).

Disclosed herein are a polypropylene resin composition having excellent melt tension and a method for preparing the same. More particularly, a high melt tension polypropylene resin composition prepared by stepwise reaction of existing polypropylene resin with at least two organic peroxides having different half-life distributions, as well as a method for preparation thereof are described.