Method for preparing small crystal grain molecular sieve

A technology of molecular sieves and small crystals, applied in the direction of crystalline aluminosilicate zeolite, etc., can solve the problems of high production cost, difficult product separation, long production cycle, etc., and achieve the effect of strong activity

Active Publication Date: 2012-03-14
CHINA PETROLEUM & CHEM CORP +1
View PDF7 Cites 9 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The technical problem to be solved by the present invention is that hydrothermal synthesis is required in the preparation process of small-grain molecular sieves, the prepared products are difficult to separate, the preparation cycle is long, the use of templates in the preparation pollutes the environment, and the preparation cost is high. A n

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for preparing small crystal grain molecular sieve

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Take 500 grams of SiO with a grain size of 10um 2 / Al 2 O 3 ZSM-5 molecular sieve of 40 is placed in the feeder of the supersonic jet mill, the feed rate of the feeder is adjusted to 1 kg / h, and the air inlet air pressure of the jet mill is set to 2Mpa. After crushing, the cyclone separation is large. The granular crystals were newly put into the feeder for airflow crushing, and after repeated two times, a small crystal ZSM-5 molecular sieve with an average particle size of 1um was obtained.

Embodiment 2

[0018] Take 500 grams of mordenite with a grain size of 5um and put it into the feeder of the supersonic jet mill, adjust the feed rate of the feeder to 0.5 kg / h, and set the supersonic jet mill inlet air pressure to 3Mpa for crushing Afterwards, the large-particle crystals separated by the cyclone were newly put into the feeder for airflow crushing, and after repeated twice, small-crystal mordenite with an average particle size of 0.5um was obtained.

Embodiment 3

[0020] Take 200 grams of mordenite with a grain size of 5um and put it into the feeder of the supersonic jet mill. Adjust the feed rate of the feeder to 0.2 kg / h. Set the air inlet air pressure of the jet mill to 5Mpa. After crushing, The large-particle crystals separated by the cyclone are newly put into the feeder for airflow crushing. After repeating 3 times, all the obtained small-crystal molecular sieves are put into the feeder. After repeating the above process twice, the average particle size is 0.1um. Of small grains of mordenite.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
The average particle sizeaaaaaaaaaa
The average particle sizeaaaaaaaaaa
Particle sizeaaaaaaaaaa
Login to view more

Abstract

The invention relates to a method for preparing a small crystal grain molecular sieve, and mainly solves the problems that: by the conventional method for preparing the small crystal grain molecular sieve, the hydrothermal synthesis is required, the period is longer, the small crystal grain molecular sieve cannot be continuously produced, the separation is difficult after synthesis and the synthetic cost is high. The problems are better solved by adopting the technical scheme that the method for preparing the small crystal grain molecular sieve comprises the following steps of: feeding synthesized large crystal grain molecular sieve raw materials into crushing equipment and performing physical crushing, and classifying products to obtain the small crystal grain molecular sieve; and the method can be used for the production of small crystal grain molecular sieves.

Description

Technical field [0001] The invention relates to a preparation method of small crystal particle molecular sieve. Background technique [0002] Molecular sieves have good shape-selective catalytic performance and adsorption performance due to their uniform and regular pore structure, larger specific surface area and higher thermal stability, and are widely used in petrochemical and other fields. However, with the development of fine chemicals, large-grained zeolite materials have narrow pores and large diffusion resistance, and cannot achieve the expected catalytic effect in reactions involving large molecules or liquid phases. The small-crystalline zeolite molecular sieve has a larger external specific surface area and a higher intracrystalline diffusion rate, which can provide more active sites, the reactant molecules can easily reach the catalytic active sites, and the products generated can quickly pass from the pores. Diffusion out has superior performance in improving the ut...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C01B39/02
Inventor 马广伟陈希强
Owner CHINA PETROLEUM & CHEM CORP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products