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78results about How to "Increase active point" patented technology

Transitional metal oxide/nitrogen-doped ordered mesoporous carbon composite material and preparation method thereof

The invention discloses a transitional metal oxide/nitrogen-doped ordered mesoporous carbon composite material and a preparation method thereof. The preparation method comprises the following steps: carrying out inert gas calcining and removing a template to obtain nitrogen-doped ordered mesoporous carbon first by taking a mesoporous molecular sieve SBA-15 as the template, a saccharide carbohydrate as a carbon source and urea and hexamethylenetetramine as a nitrogen source; and then adding a transitional metal salt solution and introducing inert gas to calcine to obtain the transitional metaloxide/nitrogen-doped ordered mesoporous carbon composite material. The preparation method disclosed by the invention is low in cost and easy to operate. The nitrogen-doped ordered mesoporous carbon prepared by the method is clear in pore, proper in pore diameter and large in specific surface area, and nanoparticles of the transitional metal oxide are uniformly distributed and high in capacity. Thetransitional metal oxide/nitrogen-doped ordered mesoporous carbon composite material is excellent in electrochemical property and has a wide market prospect in the fields such as catalysts, electricity and heat conduction and energy-storage materials.
Owner:SHANDONG JIANZHU UNIV

Preparation technology of nitrogen-doped mesoporous carbon composite metal oxide electrode material for supercapacitor

The invention discloses a preparation technology of a nitrogen-doped mesoporous carbon composite metal oxide electrode material for a supercapacitor, wherein the preparation method comprises the following steps of firstly, taking a mesoporous molecular sieve SBA-15 as a template agent, taking carbohydrate as a carbon source, and taking urea and hexamethylenetetramine as a nitrogen sources, performing calcining by inert gas, and removing the template agent to obtain nitrogen-doped mesoporous carbon; then, adding a metal salt solution, introducing inert gas for calcining to obtain a nitrogen-doped mesoporous carbon composite metal oxide composite material; and then mixing the material with polytetrafluoroethylene (PTFE) ) and the carbon black and then performing coating, pressing and dryingto obtain the nitrogen-doped mesoporous carbon composite metal oxide electrode material for the supercapacitor. The preparation method disclosed by the invention is low in cost and simple and convenient to operate. The nitrogen-doped mesoporous carbon prepared by the method disclosed by the invention is clear in pore passage and appropriate in pore size, the specific surface area is large, the distribution of the transition metal oxide nano particles is uniform, and the loading capacity is large. The electrochemical performance of the nitrogen-doped mesoporous carbon composite metal oxide electrode material is excellent, so that the electrode material has a wide market prospect in the field of energy storage materials such as supercapacitors and the like.
Owner:SHANDONG JIANZHU UNIV

Preparation method of nitrogen and sulfur co-doped graphene oxide grafted polyaniline/MoS2 electrode

The invention provides a preparation method of a nitrogen and sulfur co-doped graphene oxide grafted polyaniline/MoS2 electrode material. According to the method, graphene oxide is used as a carrier, pyrrole is used as a nitrogen source, thiophene is used as a sulfur source, and nitrogen and sulfur co-doped graphene oxide is obtained through a series of polymerization, activation, pre-oxidation and carbonization; the nitrogen and sulfur co-doped graphene oxide is subjected to acid activation, thionyl chloride modification, p-phenylenediamine modification and aniline polymerization to obtain nitrogen and sulfur co-doped graphene oxide grafted polyaniline; and MoS2 is loaded onto the nitrogen and sulfur co-doped graphene oxide grafted polyaniline through a hot water reaction to obtain the nitrogen and sulfur co-doped graphene oxide grafted polyaniline/MoS2. According to the nitrogen and sulfur co-doped graphene oxide grafted polyaniline/MoS2 electrode, the specific capacitance is larger than 400 F/g under the condition that the current density is 1A/g, and the capacitance is 80% or above of the initial value after the nitrogen and sulfur co-doped graphene oxide grafted polyaniline/MoS2 electrode is recycled 800 times.
Owner:武夷学院 +1

Visible-light catalyst of C60 implanted into mesoporous CdS/TiO2 duct and preparation method of catalyst

The invention discloses a visible-light catalyst of C60 implanted into a mesoporous CdS/TiO2 duct and a preparation method of the catalyst. The method concretely comprises the following steps: firstly, implanting a C60 quantum dot into a CdS/TiO2 duct of an ordered mesoporous structure by adopting an evaporation induced self-assembly method, and then synthetizing the C60 quantum dot-modified CdS/TiO2 light catalyst with the ordered mesoporous structure by using an ion exchange method, wherein the C60 is embedded into a hole wall skeleton of the mesoporous TiO2. The visible-light catalyst has the significant characteristics that 1) the visible-light catalyst has an excellent electron conduction role of C60, photogenerated electrons and cavities are prevented from being compounded again, and the photocatalytic process is facilitated; 2) the C60 is introduced to a semiconductor surface and expected to replace precious metal catalysts such as Pt, so that photocatalytic active points are increased; 3) the preparation method of the composite material is simple. The catalyst has the characteristics of visible-light response and the like, so that the visible-light catalyst has certain application value in the aspects such as photocatalytic water hydrogen production, a solar cell and degradation of environmental pollutants.
Owner:SHANGHAI NORMAL UNIVERSITY

Method for preparing polyfunctional group containing compatilizer with controllable polarity

The invention discloses a method for preparing polyfunctional group containing compatilizer with controllable polarity. The method comprises the following steps that 1, after a glycidyl alkyl salt compound is added into an aqueous solution containing nano particles to react for 1 h to 3 h, an intermediate 1 is obtained; 2, epoxy chloropropane is dropwise added into polyethylene polyamine, reacting is carried out for 6 h to 12 h at the temperature of 90 DEG C to 100 DEG C, rotary evaporation is carried out, and an intermediate 2 is obtained; 3, non-polar polymer graft and the intermediate 2 are mixed in a solvent, a phase transfer catalyst is added, reacting is carried out for 5-12 hours at the temperature of 100 DEG C to 160 DEG C, and an intermediate 3 is obtained; 4, the intermediate 1 and the intermediate 3 are mixed in a solvent, a phase transfer catalyst is added, reacting is carried out for 4-12 hours at the temperature of 80 DEG C to 130 DEG C, and the product is obtained. The obtained compatilizer contains a polar part with high activity, the grafting rate of the compatilizer is high, the characteristic that a large number of reaction activity points are provided for two incompatible phases in the blending process is guaranteed through rich polar functional groups on the solvent, and the interface bonding force is improved.
Owner:HEBEI UNIV OF TECH

Jeans garment shaping liquid as well as preparation method and application thereof in ultraviolet light photocatalytic shaping and finishing method

The invention provides a jeans garment shaping liquid as well as a preparation method and an application thereof in an ultraviolet light photocatalytic shaping and finishing method and relates to a jeans garment shaping liquid. The jeans garment shaping liquid comprises the following components in percentage by weight: 5.0-15.0 percent of polycarboxylic acid, 3.0-9.0 percent of sodium hypophosphite, 0.1-2.0 percent of Fe<3+>doped nanometer titanium dioxide, 1.0-5.0 percent of penetrating agents, 2.0-5.0 percent of formaldehyde-free environmentally-friendly stiffening agents, 3.0-5.0 percent of smooth brighteners and 59.0-85.9 percent of water. The invention also relates to the jeans garment ultraviolet light photocatalytic shaping and finishing method by adopting the shaping liquid, which comprises the following steps of: carrying out plasma radiation treatment on a part of a jeans garment required to be shaped, spraying the shaping liquid onto the treated part of the jeans garment, pre-drying on a drying tunnel-type drying oven and crinkling the treated part of the jeans garment; then carrying out photocatalytic shaping on the treated parts; and finally washing and drying. The method is high in catalytic efficiency, is environmental-friendly and energy-saving and is high in production efficiency. The finished jeans garment is durable, is good in shaping effect and good in handfeel and gloss, is environmental-friendly and generates no formaldehyde emission.
Owner:GUANGDONG JUNAN JEANS RES INST +1

Metal loaded activated carbon modified silk protein porous membrane and preparation and application methods thereof

The invention provides a metal loaded activated carbon modified silk protein porous membrane and preparation and application methods thereof. The metal loaded activated carbon modified silk protein porous membrane is composed of silk protein and loofah sponge sheet-like activated carbon materials loaded with gold, platinum, palladium, titanium, iron, manganese or cerium. The preparation process ofthe metal loaded activated carbon modified silk protein porous membrane comprises processing the peripheral fiber of loofah sponge into sheets, performing pretreatment through dilute alkali, and thoroughly immersing the raw materials into sugar alcohol solution containing metal salt; inletting nitrogen into the solution to form tiny bubble clusters, performing immersion treatment, extracting andthen squeezing the materials to remove superfluous sugar alcohol solution, and performing drying, curing and high-temperature carbonization treatment to obtain loofah sponge sheet-like activated carbon materials; mixing the loofah sponge sheet-like activated carbon materials with the silk protein solution; performing electrophoresis treatment to obtain hydrogel, freeze-drying the hydrogel in vacuum to obtain the metal loaded activated carbon modified silk protein porous membrane. The prepared metal loaded activated carbon modified silk protein porous membrane achieves absorption, oxidation catalysis and protein immobilization, and is significant in processing effects and free from the potential risk of secondary pollution.
Owner:DONGGUAN LIANZHOU INTPROP OPERATION MANAGEMENT CO LTD

Separation system and method for coking flat coal slime

The invention relates to a whole-component separation system and method for coking flat coal slime, and belongs to the technical field of coal slime separation. The defect of a technology for recycling low ash fine coal from middling coal in the prior art is overcome, and the problem of waste of clay mineral resources such as kaolin in the prior art is solved. The whole-component separation systemfor the coking flat coal slime comprises a middling coal separation operation device which comprises rod mills, a second-section grading cyclone, flotation columns and a first slurry mixing machine.According to the separation method for the coking flat coal slime, middling coal separation operation comprises the following steps that bottom flow coarse particles of a first-section grading cycloneare screened, first-section rod milling, second-section rod milling, slurry mixing, coarse separation and fine separation are conducted to obtain a light product and heavy product flotation waste coal, and the light product serves as a middling coal product to be discharged to complete coking flat coal slime middling coal recovery. According to the whole-component separation system and method forthe coking flat coal slime, whole-component separation of the coking flat coal slime can be achieved.
Owner:湖南兴辉洗选药剂科技开发有限公司 +1

Benzene hydrorefining catalyst, and preparation method and application thereof

The invention specifically relates to a benzene hydrorefining catalyst, and a preparation method and application thereof, belonging to the technical field of benzene hydrorefining catalysts. The preparation method comprises the following steps: S1. Uniformly mixing raw materials for a carrier of the benzene hydrorefining catalyst, carrying out extrusion granulation, and then carrying out sinteringmolding at 680 to 700 DEG C to obtain the carrier; S2, adding phosphoric acid into water with a temperature of 46-50 DEG C, carrying out uniform mixing, then carrying out heating to 88-92 DEG C, adding cobalt carbonate for a reaction, then adding molybdenum trioxide after gas release of the reaction is completed, and then carrying out mixing and dissolving to obtain an activation solution; S3, placing the carrier in an enclosed reactor, and carrying out multi-stage high-temperature activation; and S4, carrying out cooling to room temperature to obtain the benzene hydrorefining catalyst. According to the invention, phosphoric acid and rare earth metals are added into the benzene hydrorefining catalyst, so dispersion of the active component molybdenum is facilitated, the specific surface area of the catalyst is larger and more uniform, and active sites are increased; moreover, the preparation method is simple and employs a multi-stage high-temperature activation manner for activation, so the water content of the catalyst is reduced, the water resistance of the catalyst is improved, and the service life of the catalyst is prolonged.
Owner:NORTH CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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