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316results about How to "Improve anti-poisoning performance" patented technology

A kind of ferromanganese composite oxide catalyst for simultaneous denitrification and mercury removal and preparation method thereof

The invention discloses a ferromanganese composite oxide catalyst for simultaneous denitrification and mercury removal, the active components of which are MnO2 and Fe2O3, wherein the molar ratio of Mn / Fe is 0.5-5, the catalyst is compounded on the carrier TiO2, and its active components are The total mass fraction of the component is 5% to 40%, and CuO, CeO2, V2O5 and other oxide auxiliary components can also be added, and the addition amount is 0% to 10% of the total mass fraction. The invention also discloses a preparation method of the catalyst, which adopts an impregnation method or a co-precipitation method. The catalyst of the present invention has high activity and selectivity for the catalytic oxidation of nitrogen oxides and mercury, and its temperature adaptability window is wide, which can effectively improve the anti-poisoning performance of the catalyst, and has strong adaptability to harsh operating conditions, and can It is widely used in the catalytic oxidation of pollutants in the flue gas selective catalytic oxidation denitrification and demercuration process, and at the same time, the preparation method of the catalyst of the present invention is simple in process and low in cost.
Owner:ZHEJIANG UNIV

SCR (selective catalytic reduction) catalyst for denitrating low-temperature smoke of cement kiln and preparation method thereof

The invention provides an SCR (selective catalytic reduction) catalyst for denitrating low-temperature smoke of a cement kiln and a preparation method thereof. The SCR catalyst is characterized in that by adjusting the technological conditions such as proportions of active components, mass ratio of carriers and active components, calcining temperature and the like, a composite metal oxide which is formed by one or more metal elements out of manganese (Mn), ferrum (Fe), copper (Cu), cerium (Ce), lanthanum (La), bismuth (Bi), niobium (Nb), tantalum (Ta) and the like is loaded on a carrier by adopting an impregnation method, and tungsten and molybdate are used as active assistants. The active components in the SCR catalyst are uniformly distributed on the surface of the carrier in an unformed shape, the low-temperature activity of the catalyst is improved by utilizing the synergistic effect of multiple metals, the SCR catalyst is particularly suitable for the denitration of the smoke which is discharged from a dust collector on the tail of the cement kiln, the denitration rate can reach higher than 70 percent at the temperature of 80 DEG C, the denitration rate is higher than 90 percent in the temperature range of 125 DEG C to 200 DEG C, and the toxicity resistance is strong.
Owner:CHINA BUILDING MATERIALS ACAD

Denitration catalyst and preparation method thereof

The invention provides a denitration catalyst and a preparation method thereof. The denitration catalyst comprises: by weight, 40 to 45 parts of nano-titanium dioxide, 6 to 8 parts of nano-silica, 0.5 to 4 parts of ammonium metavanadate, 0.5 to 4 parts of ammonium paratungstate, 0.5 to 2 parts of Acesulfame K (A.K) sugar, and 3 to 5 parts of one or two moulding auxiliary agents. In the invention,trough the introduction of A.K sugar, the denitration catalyst has an excellent denitration performance and through the introduction of rare earth elements, an anti-poisoning performance of the denitration catalyst is improved greatly; the A.K sugar in the denitration catalyst has a binding effect and can improve effectively a mechanical property and a strength of the denitration catalyst thus ananti-crushing property of the denitration catalyst is improved and the problem that a denitration catalyst adopted by the prior art can be crushed frequently in use is solved.
Owner:上海瀚昱环保材料有限公司

Preparation method and application of nitrogen and phosphorus co-doped porous carbon materials

The invention provides a preparation method and application of nitrogen and phosphorus co-doped porous carbon materials which are used in the aspects of electric catalysis, catalyst carriers, super capacitors, water treatment and the like. The method comprises that a carbon source, a nitrogen source, a phosphorus source and a carbonization activating agent are mixed in different proportions, ground, then subjected to high temperature carbonization treatment in nitrogen gas, and then subjected to acid treatment to obtain the porous carbon materials with different nitrogen and phosphorus compositions. The prepared carbon materials are used as non-noble metal catalysts; compared with traditional noble metal catalysts, the materials have the advantages of simpler preparation process, high activity, strong anti-poisoning ability, and good stability, and are ideal oxygen reduction catalysts for fuel cells. The prepared carbon materials are used as catalyst carriers; compared with traditional carbon powder carriers, the catalysts loaded with nanoparticles have the catalytic activity, stability, anti-poisoning ability and the like improved significantly. The carbon materials have relatively idea effects when used in the fields of super capacitors and water treatment.
Owner:LANZHOU JIAOTONG UNIV

Cu-SSZ-13 catalyst, and preparation method and application thereof

The invention discloses a method for preparing a Cu-SSZ-13 catalyst through an in-situ synthesis method. A Cu-SSZ-13 molecular sieve sample is prepared by taking acid as an exchange reagent and treating through an in-situ synthesis method. Compared with the currently used ammonium nitrate ion exchange method, the after treatment method for the Cu-SSZ-13 molecular sieve prepared through an in-situ synthesis method is more environment-friendly and effective; the activity of the prepared catalyst is higher; and the hydrothermal stability is better. According to the method, the silica-alumina ratio of the molecular sieve structure is increased while the catalyst having high catalytic activity is obtained; and the obtained Cu-SSZ-13 catalyst has excellent hydrothermal stability, wide temperature window and excellent N2 selectivity, and is very applicable to purification of tail gas from diesel cars.
Owner:江西中科鸿虔新材料有限公司

Photoresist undercoat-forming material and patterning process

A material comprising a novolac resin having a C6-C30 aromatic hydrocarbon group substituted with a sulfo group or an amine salt thereof is useful in forming a photoresist undercoat. The undercoat-forming material has an extinction coefficient sufficient to provide an antireflective effect at a thickness of at least 200 nm, and a high etching resistance as demonstrated by slow etching rates with CF4 / CHF3 gas for substrate processing.
Owner:SHIN ETSU CHEM CO LTD

Nano porous gold-loaded ultrathin platinum metallic film catalyst and preparation method thereof

The invention discloses a nanoporous gold supported ultrathin platinum metal film catalyst; the catalyst is an alloy sheet which is 0.1 - 100 micrometer thick, 0.1 - 10cm wide, and 0.1 - 20cm long, and is uniformly covered with a platinum metal atom layer on the surface thereof; the invention takes the method of under-potential depositing copper, silver or lead on the nanoporous gold and then performing exchange with the platinum metal cations to deposit the platinum metal film on the surface of the porous gold, thus obtaining the nanoporous gold supported ultrathin platinum metal film catalyst. The catalyst material prepared by the method of the invention can be easily controlled with regards to the aperture size, pore wall thickness and the platinum metal film thickness; and the catalyst is characterized by high specific surface area, high utilization ratio of the platinum metal, good catalytic activity and high anti-poisoning property.
Owner:SHANDONG UNIV

Mercuric chloride low-mercury catalyst and preparation method thereof

The invention provides a mercuric chloride low-mercury catalyst and a preparation method thereof. The catalyst adopts active carbon as a carrier to adsorb mercuric chloride, and the formula of the catalyst comprises 8.0 to 10.0 percent of mercuric chloride, 8 to 13 percent of rare earth chloride assistant A, 5 to 25 percent of alkaline earth metal chloride assistant B, 10 to 20 percent of assistant C, and the balance of active carbon. The preparation method comprises the following steps: firstly, soaking the active carbon in hydrochloric acid solution at low temperature for standby; simultaneously dissolving the mercuric chloride, the assistant A, the assistant B and the assistant C together, and soaking the active carton in the solution; performing low-temperature pre-drying on an intermediate product; continuously drying the catalyst; and finally pumping a product at vacuum into a storage silo, packaging and leaving factory. The catalyst can reduce resource consumption and the pressure of treating mercury pollution; simultaneously the production cost is reduced, the poisoning resistance, reduction resistance and loss resistance are greatly improved, the catalytic performance of the catalyst is fully guaranteed, the using time can be prolonged and the using consumption can be reduced; and the catalyst is suitable for polyvinyl chloride manufacturers.
Owner:贵阳白云银星化工有限公司

Honeycomb type low-temperature flue gas denitrification catalyst and preparing method

The invention discloses a honeycomb type low-temperature flue gas denitrification catalystpowder and a preparing method thereof.The honeycomb type low-temperature flue gas denitrification catalyst powder is prepared from, by mass, 3.0-5.0 parts of vanadium oxide, 3.5-5.1 parts of molybdenum oxide, 0.1-1.0 part of tungsten oxide, 0.1-3.0 parts of manganese oxide, 0.01-0.1 part of phosphorus oxide, 0.01-0.05 part of boric oxide, 0.1-1.0 part of copper oxide and 84.75-92.68 parts of titanium dioxide.The preparing method comprises the steps that firstly, an active component solution is prepared; secondly, a catalyst is loaded with an impregnation method; thirdly, the consistent honeycomb type catalyst is prepared through extruding forming.According to the honeycomb type low-temperature flue gas denitrification catalyst powder and the preparing method thereof, the activity and catalytic capability of the low-temperature flue gas denitrification catalyst are effectively improved, the denitrification efficiency can reach 38% at 120 DEG C and reaches 95.1% at 210 DEG C, high industrial application value is achieved, and the honeycomb type low-temperature flue gas denitrification catalyst can be widely applied to NH3 selective catalytic reaction of nitric oxide in flue gas.
Owner:东营信拓汽车消声器有限公司

Low-mercury catalyst for hydrochlorination of acetylene

The invention discloses a low-mercury catalyst and particularly relates to the low-mercury catalyst which is suitable for synthesizing vinyl chloride by hydrochlorination reaction of acetylene. The catalyst comprises a main active component, namely mercury chloride, auxiliary active components, namely at least one of oxides of cobalt, manganese, silver and copper and a carrier, namely activated carbon, wherein the mercury chloride accounts for 2-4% of the weight of the carrier of the catalyst, and the auxiliary active components account for 5-30% of the weight of the carrier of the catalyst in total. According to the prepared low-mercury complex catalyst disclosed by the invention, the auxiliary components are added, so that the anti-poisoning performance of the low-mercury catalyst is enhanced, the reduction of the mercury chloride during the using process is reduced, the loss of mercury is retarded, the service life of the low-mercury catalyst is significantly prolonged, and the low-mercury catalyst is the novel low-mercury catalyst with good activity, strong stability and high selectivity. The low-mercury catalyst has the advantages of simple production process, short production period and low mercury consumption.
Owner:XINJIANG TIANYE GRP +1

Oxygen-enriched tail gas nitrogen oxide purifying catalyst

A catalyst of removing the NOx, residual organic substance and CO from the oxygen-enriched tail gas from engine contains the porous inorganic carrier, silver, noble metal chosen from Au, Pt, Pd, Ph, Ir and Ru, and other metal chosen from Fe, Cu, Ti, Zr, Ba, Sn, W, Zn, Mo, Ce, Cs, La and Ca.
Owner:RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI

Noble metal-rare-earth catalyst for purifying waste gas and its preparation

The catalyst includes alumina, RE metal oxide, composite Al-La oxide, and active metal Pt, Pd and Rh. It features that the mixed oxide grain with aluina, cerium oxide and Al-La oxide carries at least one of Pt and Pd as well as Rh. The mixed oxide grain is prepared through dissolving salt of Al, Ce and La in water, adding NH3OH to produce precipitate, and heating to decompose the precipitate. The catalyst preparing process includes carrying mixed oxide grains onto the carrier, carrying least one of Pt and Pd onto the mixed oxide grains, and carrying Rh finally. The catalyst is especially suitable for purifying automobile tail gas of gasoline engine near the theoretical air / fuel ratio, and has the features of lasting use, less noble metal consumption, high purifying efficiency and powerful sulfur poison resistance.
Owner:昆明贵研催化剂有限责任公司

Catalyst for removing traces of oxygen in catalytic cracking dry gas

The invention provides a catalyst for removing traces of oxygen in catalytic cracking dry gas, which is characterized in that the catalyst contains catalytic active components and a carrier, wherein the catalytic active components consist of main catalytic active components and auxiliary catalytic active components; the main catalytic active components are palladium; based on the weight of the catalyst, the palladium content is 0.01 to 0.5 percent; the auxiliary catalytic active components are one or more of Ag, Au, Co and Cr; the content of the auxiliary catalytic active components is 0.05 to 1.0 percent; the carrier is alumina, activated carbon, silica or zeolite; and the catalytic active components are distributed in an eggshell-like state on the surface of the carrier. The catalyst has the deoxidation depth up to 0.1 ppm at high space velocity, and has the characteristics of strong anti-poisoning capability, reaction bed insusceptible to temperature runaway, and the like.
Owner:CHINA PETROLEUM & CHEM CORP +1

Applicable load-type catalyst for purifying air at room temperature

The present invention relates to an applicable load-type catalyst for purifying air at room temperature using copper, manganese and cerium as active ingredients and nano-palygorskite or nano-sepiolite powder as carriers, wherein contents of the copper, manganese and cerium account for 15%-40% of the total mass with a molar ratio of 1: 1: 1-1: 2: 4; and preparation technology includes a ultrasonic dispersion step for 1 hour, a stirring step at 30-50 DEG C for 2-4 hours, drying and activating steps at 110-120 DEG C for 5-10 hours, a calcination step in a muffle furnace at 500-800 DEG C for 3-6 hours, and a grinding step until a fineness is equal to or less than 20 microns. The applicable load-type catalyst is super strong in adsorption capacity, can continuously and effectively remove benzene, toluene and xylene (BTX), formaldehyde, CO, NO, SO2 and other harmful gases in the air, is high in processing efficiency, low in cost and wide in economic applicability, does not produce secondary pollution, and is suitable for the removal of pollutants at home, offices, hotels, conference rooms, furniture shopping malls, building material markets and other space.
Owner:北京天恒健科技发展有限公司

Carried by CeO2 based composite oxides coated carrier Pd catalyst, its prepn. method

A catalyst for catalytic combustion features that a coated composite oxide layer based on CeO2 is carried by cellular ceramic carrier. It contains the cellular cordierite ceramic matrix, coated composite oxide layer based on CeO2, and Pd. Its preparing process is also disclosed.
Owner:ZHEJIANG NORMAL UNIVERSITY

Method for preparing anode catalyst of direct methanol fuel cell

A process for preparing the anode catalyst Pt / PANI / MWNT able to be directly used for methanol fuel battery includes such steps as adding sulfuric acid solution containing disperser into container, adding multi-wall carbon nanotubes, ultrasonic oscillating, adding phenylamine and ammonium persulfate solution, reacting, washing, baking to obtain polyphenylamine / multi-wall carbon nanotubes carrier, adding additive contained buffering solution of acetic acid, ultrasonic oscillating, adding chloroplatinic acid solution, continuous oscillating while heating and dropping sodium borohydride solution, reacting, filtering, washing and baking.
Owner:XIAMEN UNIV

Dendritic platinum-palladium alloy nanometer catalyst as well as preparation method and application thereof

The invention relates to a dendritic platinum-palladium alloy nanometer catalyst as well as a preparation method and application thereof. A structural formula of the dendritic platinum-palladium alloy nanometer catalyst is PtxPd100-x, and x is not less than 0 and not more than 100; the dendritic platinum-palladium alloy nanometer catalyst is prepared from platinum pentanedionate and palladium pentanedionate in an oleylamine solution under conditions of a temperature of 50-90 DEG C and the presence of H2. The dendritic platinum-palladium alloy nanometer catalyst is used for hydrogenation reduction of a methanol fuel cell anode catalyst and a nitrocompound. The dendritic platinum-palladium alloy nanometer catalyst shows a relatively strong poisoning resistance and relatively high electric catalysis stability in a process of an electric catalytic oxidation of a methane solution with a certain concentration, can realize the hydrogenation reduction of the nitrocompound at a low temperature and a normal pressure, has a dormant advantage especially for the hydrogenation reduction of polynitro compounds, and can be used for effectively reducing the energy consumption.
Owner:俞杏英

Preparation method and application of multifunctional desulfurizer for hydrolyzing, absorbing and deoxidizing organic sulfur

ActiveCN107497440AGood dispersionHigh and low temperature hydrolysis conversion and absorptionGas treatmentHeterogenous catalyst chemical elementsActivated carbonAluminium isopropoxide
The invention provides a preparation method of a multifunctional desulfurizer for hydrolyzing, absorbing and deoxidizing organic sulfur. The preparation method comprises the steps as follows: adding activated carbon to a mixed solution of Zn(NO3)2, Fe(NO3)3 and first active aid soluble salt, performing ultrasonic equivalent-volume impregnation and microwave roasting to obtain first semi-finished catalyst powder, adding an acetic acid aqueous solution to an isopropanol solution of aluminum isopropoxide and tetrabutyl titanate, and performing microwave roasting to obtain Al2O3-TiO2 composite carrier powder; adding an Al2O3-TiO2 composite carrier to a second aid soluble salt solution, performing ultrasonic equivalent-volume impregnation and microwave roasting to obtain second semi-finished catalyst powder, evenly mixing the first semi-finished catalyst powder, the second semi-finished catalyst powder, a binder, a the pore forming agent and water, and performing extrusion forming, drying and microwave roasting to obtain the multifunctional desulfurizer. The multifunctional desulfurizer has the advantages of efficiently hydrolyzing, converting, absorbing and deoxidizing the organic sulfur.
Owner:江苏天东新材料科技有限公司

Preparation method of non noble metal catalyst for cathodic oxygen reduction reaction of fuel cell

The invention provides a preparation method of a non noble metal catalyst for cathodic oxygen reduction reaction of a fuel cell and belongs to the technical field of electrode catalytic materials. The preparation method comprises the steps as follows: in a protonic solvent, mixing dipyridine with a carbon nanotube according to a mass ratio of (20 to 1) to (1 to 1), ultrasonically dispersing and stirring for 20 to 50 min respectively, adding metal salt which is 1 to 20 times the carbon nanotube in mass, strongly stirring for 1 to 5 h, evaporating to removal the solvent, drying, grinding, placing into a tubular furnace, adding nitrogen for heat treatment, grinding, then treating with an acid solution, carrying out suction filtration, washing and drying so as to obtain the non noble metal catalyst. The non noble metal catalyst prepared by the preparation method has the advantages of low cost, high activity, high poisoning resistance and good stability in comparison with the traditional noble metal catalyst, and is an ideal catalyst for the cathodic oxygen reduction reaction of the fuel cell.
Owner:NORTHWEST NORMAL UNIVERSITY

Method for preparing nanometer platinum nickel/titanium dioxide nanotube electrode by cyclic voltammeter electrodeposition

The invention discloses a method for preparing a nanometer platinum nickel / titanium dioxide nanotube electrode by cyclic voltammeter electrodeposition, and belongs to the technical field of photoelectrocatalysis. A titanium dioxide nanotube array, tidily arranged and vertically oriented, is prepared on a titanium chip by adopting an anodic oxidation method; and then, nanometer metal particles are deposited in nanotubes and on the surfaces of the nanotubes by adopting a cyclic voltammeter electrodeposition method to prepare a nanometer platinum / nickel modified titanium dioxide nanotube electrode. An electrocatalyst preparation method needs no surface active agent, stabilizing agent or functional component in deposition, is simple in process, and is uniform in nanoparticle dispersion; and the prepared electrode can obviously reduce the toxicity of catalyst and improve the electro-catalytic property of the electrode, and is wide in application prospect.
Owner:BEIJING UNIV OF TECH

Bimetallic catalyst for catalytic oxidation of VOCs and preparation method and application of bimetallic catalyst

The invention provides a bimetallic catalyst for catalytic oxidation of VOCs and a preparation method and application of the bimetallic catalyst. According to the catalyst, titanium dioxide is adopted as a carrier, an active agent is an elementary substance of any one of ruthenium, palladium and platinum and / or an oxide of the elementary substance, and a promoter is any one of cobaltosic oxide, manganese oxide, copper oxide and nickel oxide. Nano particles with the active agent and the promoter evenly compounded are synthesized through a nano regulation means and a Salen ligand, a high concerted catalysis function is achieved between the active agent and the promoter, and the catalytic oxidation efficiency of VOCs can be improved. The catalyst is high activity and high in universality, the complete oxidizing temperature on multiple kinds of VOCs ranges from 160 DEG C to 230 DEG C, the overall performance is superior to that of a commercial palladium-platinum catalyst, the selectivity of final reaction products CO2 is high, and good application prospects are achieved.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Vanadium oxide nanotube denitration catalyst with anti-poisoning performance and preparation method of catalyst

The invention discloses a vanadium oxide nanotube denitration catalyst with anti-poisoning performance and a preparation method of the catalyst. The catalyst is prepared from a carrier as well as an active substance and a catalysis aid which are supported on the carrier, wherein the carrier is a vanadium oxide nanotube, the active substance is at least one of oxides of cerium, niobium, iron, copper, chromium, cobalt and manganese, and the catalysis aid is oxide of molybdenum or tungsten. The catalyst has a good inhibition function on poisoning effects of phosphate, heavy metals, alkali metals and alkaline-earth metals.
Owner:ZHEJIANG UNIV

Palladium/nitrogen-doped graphene composite electrode catalyst and preparation method thereof

The invention discloses a palladium / nitrogen-doped graphene composite electrode catalyst and a preparation method thereof. The preparation method comprises the following steps: carrying out ultrasonic dispersion on oxidized graphene in water, adding tripolycyanamide, heating and stirring the mixture, freezing and drying the mixed system and carrying out high-temperature heat treatment, so as to obtain nitrogen-doped graphene; carrying out ultrasonic dispersion again on the nitrogen-doped graphene in an ethylene glycol solution, adding a palladium nitrate solution to the ethylene glycol solution and mixing the mixture evenly; reducing palladium nitrate by virtue of a mild reduction method, and depositing palladium nanoparticles in-situ on the surface of the nitrogen-doped graphene; and after reaction is ended, carrying out centrifugal separation to obtain a solid product, and washing and drying the product to obtain the catalyst. By virtue of the mild reduction method, the palladium nanoparticles are deposited in-situ on the surface of the nitrogen-doped graphene; and high temperature or high pressure is not needed, so that the preparation method is simple and controllable, and the repeatability is relatively good. The prepared palladium / nitrogen-doped graphene composite electrode catalyst has excellent electrochemical properties as a direct methanol / formic acid fuel cell cathode material.
Owner:NANJING UNIV OF SCI & TECH +1

La1-xAgxMnO3 perovskite type catalyst for auto tail gas purification

The invention relates to a La1-X AgXMnO3 perovskite catalyst used to purify the vehicle tail gas, wherein the A of ABO3 structure of perovskite is formed by lanthanum and silver; the B is formed by manganese; 0.05<=X<=0.4; the total mol of lanthanum and silver, the mol of manganese and oxygen mol are rated as 1:1:3; via analyzing crystal phase, the perovskite structure is 95% of catalyst. The invention can adjust the ratio of lanthanum and silver to improve the application in different vehicle discharge systems. And the invention can effectively resist to the toxicity of lead and sulfur. And it has high thermal stability, with simple structure and low cost.
Owner:TIANJIN UNIV

Single-zone plate type high-temperature electrostatic dust collector

The invention discloses a single-zone plate type high-temperature electrostatic dust collector and belongs to the technical field of environmental-protection dust collecting equipment. The equipment mainly comprises positive plates, a negative plate, emitter electrodes, a high-temperature power supply, wherein two stainless steel plates are grounded and parallelly arranged to serve as positive plates; a stainless steel plate which has the same shape and size as the positive plates is connected with the negative pole of a high-temperature power supply to serve as the negative plate; the negative plate is suspended in the middle of the two positive plates and parallel to the positive plates; and all disc-like emitter electrodes are embedded on the two sides of the negative plate. In the invention, a single-zone plate type structure is adopted, so the structure of the equipment is compact and the electrical field is uniform, and the stability and reliability of the high temperature operation of the equipment are improved; and the emitter electrode is made of cerium oxide-doped barium-tungsten hot electron emitting material, which contributes to improving dust collection efficiency and prolonging the service life of the equipment.
Owner:苏州南师大智慧创意产业有限公司

Catalyst for catalyzing methyl alcohol, preparation method and chemically modified electrode of catalyst

The invention discloses a catalyst for catalyzing methyl alcohol. The catalyst disclosed by the invention comprises graphene, a polyacrylic acid-ferrocene compound and metal nanoparticles, wherein the mass ratio of the grapheme to the polyacrylic acid-ferrocene compound and the metal nanoparticles is (20-50):(150-250):(1-15). The graphene is taken as a substrate material of the catalyst for catalyzing methyl alcohol disclosed by the invention; the polyacrylic acid-ferrocene compound can enter a layer structure of the graphene to inhibit the aggregation of the graphene; homogeneous nucleation of the metal nanoparticles is promoted by the polyacrylic acid, so that the loaded metal nanoparticles has a higher catalytic activity; due to a net structure of the polyacrylic acid, the graphene-polyacrylic acid-ferrocene has a multi-channel stereoscopic structure, the movement of the particles is buffered and the homogeneous growth of the metal nanoparticles is further promoted. Therefore, the catalyst for catalyzing methyl alcohol disclosed by the invention has the advantages of higher catalytic activity for methanol and higher capability of resisting the poisoning of an intermediate.
Owner:QINGDAO UNIV

A preparing method of a catalyst for low-temperature denitrification

The invention relates to a preparing method of a catalyst for low-temperature denitrification, and belongs to the field of flue gas denitrification. The denitrification efficiency of the catalyst for flue gas at 150-420 DEG C is 95% or above. Raw materials for preparing the catalyst comprise 55-91 parts of superfine titanium dioxide, 1-10 parts of lanthanum nitrate, 1-5 parts of polyoxyethylene, 1-10 parts of cerous nitrate, 1-10 parts of zirconium nitrate, 0.05-10 parts of ammonium metavanadate, 0.05-15 parts of ammonium heptamolybdate, 0.05-10 parts of ammonium paratungstate, 1-5 parts of carboxymethylcellulose, 10-30 parts of deionized water, 1-15 parts of monoetanolamine and 1-5 parts of oxalic acid. The catalyst is characterized by high selectivity, high activity and strong poison resistance.
Owner:ANHUI YUANCHEN ENVIRONMENTAL PROTECTION SCI & TECH

Tungsten carbide/platinum composite material with core-shell structure as well as preparation and application thereof

The invention discloses a tungsten carbide / platinum composite material with a core-shell structure as well as preparation and application thereof. The granule of the tungsten carbide / platinum composite material with the core-shell structure takes tungsten carbide as a core, and the platinum is coated and grown on the surface of the tungsten carbide; the granule diameter of the tungsten carbide / platinum composite material with the core-shell structure is 50-1500 nanometers. The preparation method comprises the following steps of firstly preparing a tungsten carbide / copper composite material with the core-shell structure through spray drying-reduction carbonization; then reducing to obtain Cu in a carbonization process through Pt displacement so as to obtain the tungsten carbide / platinum composite material with the core-shell structure. The preparation method disclosed by the invention has the advantages of simple integral preparation step and low cost. The invention provides application of the tungsten carbide / platinum composite material with the core-shell structure as an electrocatalyst in a methanol fuel cell. A result indicates that the tungsten carbide / platinum composite material with the core-shell structure can obviously increase the catalytic conversion efficiency and prolong the service life of a catalyst.
Owner:ZHEJIANG UNIV OF TECH

High-anti-poisoning one-component pouring sealant for LED driving power supply and preparation method of high-anti-poisoning one-component pouring sealant

The invention discloses a high-anti-poisoning one-component pouring sealant for an LED driving power supply and a preparation method of the high-anti-poisoning one-component pouring sealant. The pouring sealant is prepared from 100 parts of vinyl polydimethyl siloxane, 100-300 parts of heat conducting fillers, 5-50 parts of a hydrogenous silicon oil crosslinking agent, 0.01-0.5 part of a curing inhibitor and 0.1-5 parts of a platinum complex catalyst. The preparation method comprises the following steps: sequentially adding the raw materials into a stirrer for uniformly mixing, and vacuum-removing air bubbles. The prepared pouring sealant is good in anti-poisoning property, is good in flowing property and operability during use, can fully fill superfine gaps in the LED driving power supply, is high in heat-conducting property and dielectric property after being cured, effectively improves the heat rejection efficiency of heating components of the LED driving power supply, and has good electromagnetic compatibility with the LED driving power supply. The reliability of the LED driving power supply can be improved, and the service life of the LED driving power supply is prolonged.
Owner:GUANGZHOU BAIYUN CHEM IND

Method for preparing denitration catalyst from vanadium titano-magnetite

The invention provides a method for preparing a denitration catalyst from vanadium titano-magnetite raw ore, tailings, vanadium slag, blast furnace slag and desulfurization slag. The method comprisesthe steps of grinding, component blending, forming and roasting. The method comprises the following steps: crushing the vanadium titano-magnetite until the average particle size is less than or equalto 0.5 mm; performing component blending such that the content of V2O5 is 0.1-5 wt%, the content of TiO2 is 1-50 wt%, the content of WO3 or MoO3 is 0.5-10 wt%, and the balance being 35-98.4 wt%; and finally molding and roasting to obtain the denitration catalyst. According to the method for preparing the denitration catalyst from the vanadium titano-magnetite, high-valued utilization of the vanadium titano-magnetite raw ore, tailings and vanadium slag is achieved, the production cost of the denitration catalyst is reduced, and the method has important environmental benefits and economic value.
Owner:UNIV OF SCI & TECH BEIJING
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