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A surface nano-fluorinated scandium lithium layer modified and near-surface co-doped anode material of nickel-cobalt-manganese ternary and a preparation method thereof

The application relates to a kind of surface nano fluorinated scandium lithium layer modification and near surface anion and cation co-doped nickel cobalt manganese ternary positive electrode material and its preparation method, belong to chemical energy storage battery technical field.According to the molar ratio of Li, Sc and F element 3:1:6, lithium salt, scandium salt and fluorine salt are weighed respectively, then ultrasonic is added in ethanol aqueous solution and is fully stirred to obtain mixed salt solution;Nickel cobalt manganese ternary positive electrode material is added to the mixed salt solution, heated and stirred until the suspension is dry, and then dried to obtain a powder;The powder is calcined in oxygen atmosphere to obtain a kind of surface nano fluorinated scandium lithium layer modification and near surface anion and cation co-doped modified nickel cobalt manganese ternary positive electrode material.The synergistic effect of Li3ScF6 surface coating and near surface lattice Sc, F co-doping improves the electrochemical performance and thermal stability of nickel cobalt manganese ternary positive electrode material.
Owner:BEIJING INST OF TECH