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A surface nano-fluorinated scandium lithium layer modified and near-surface co-doped anode material of nickel-cobalt-manganese ternary and a preparation method thereof
Active
CN116470026B
Improve electrochemical performance
improve security
The application relates to a kind of surface nano fluorinated
scandium
lithium
layer modification and near surface anion and cation co-doped
nickel
cobalt
manganese
ternary positive
electrode
material and its preparation method, belong to
chemical energy
storage battery technical field.According to the
molar
ratio of Li, Sc and F element 3:1:6,
lithium
salt,
scandium
salt and
fluorine
salt are weighed respectively, then ultrasonic is added in
ethanol
aqueous solution
and is fully stirred to obtain mixed
salt solution
;
Nickel
cobalt
manganese
ternary positive
electrode
material is added to the mixed
salt solution
, heated and stirred until the suspension is dry, and then dried to obtain a
powder
;The
powder
is calcined in
oxygen
atmosphere
to obtain a kind of surface nano fluorinated
scandium
lithium
layer modification and near surface anion and cation co-doped modified
nickel
cobalt
manganese
ternary positive
electrode
material.The synergistic effect of Li3ScF6
surface coating
and near surface lattice Sc, F co-
doping
improves the electrochemical performance and
thermal stability
of
nickel
cobalt manganese ternary positive
electrode material
.
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Owner:
BEIJING INST OF TECH
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