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50 results about "Dithizone" patented technology

Dithizone is a sulfur-containing organic compound. It is a good ligand, and forms complexes with many metals such as lead and mercury. Dithizone may be prepared by reacting phenylhydrazine with carbon disulfide, followed by reaction with potassium hydroxide.

Method for visual detection of pesticide residues in quantum dot fluorescence turn-off/turn-on mode

The invention discloses a method for the visual detection of pesticide residues in a quantum dot fluorescence turn-off / turn-on mode. The method comprises the steps of preparation of cadmium quantum dots and turn-off and turn-on of the fluorescence, wherein the step of the turn-off of the fluorescence comprises the specific steps of adding the solution of cadmium quantum dots into the alkali liquor at the concentration of 0.01 to 1M and then adding dithizone to turn off the bright green fluorescence; the step of turn-on of the fluorescence comprises the specific step of adding the solution of a sample to be detected into the solution of the quantum dots with turned-off fluorescence to turn on the bright green fluorescence; quantitative detection is realized according to the linear relationship between the sample concentration and the fluorescence turn-on intensity; and the cadmium quantum dots are the quantum dots emitting green fluorescence of any one of CdTe, CdTe / CdS, CdSe, CdSe / CdS or CdS. The method has the advantages of avoiding a large-scale instrument to a certain extent and effectively avoiding the interference from other impurities in the sample, along with simple operation, convenience and fastness.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI

Preparation method and use of loofah sponge surface lead ion imprinted absorbing material

The invention discloses a preparation method of a loofah sponge surface lead ion imprinted absorbing material and the use of the loofah sponge surface lead ion imprinted absorbing material in metal ion absorption and belongs to natural high polymer material modification. In the method, the loofah sponge natural high polymer material is used as a support, and the surface of the material is modified with a lead ion imprinted polymer. The main technical characteristics of the method include: adding acylated loofah sponge, lead-dithizone complex, 4-vinylpyridine, ethylene dimethacrylate and azodiisobutyronitrile into a chloroform medium, removing oxygen by argon in a certain proportion; introducing argon to expel oxygen; reacting in a water bath at a constant temperature of 50 to 70 DEG C, filtering and washing; and performing Soxhlet extraction by using 0.10mol / L solution of HNO3 for 12 hours, removing template lead ions, washing, drying and obtaining the material. The material has specific lead ion identification capacity, high selectivity, high absorption speed and high desorption capacity, is widely available and biodegradable, can be prepared by a simple process and has regeneration capacity and the advantages of environmental friendliness and the like.
Owner:UNIV OF JINAN

Sulfuric acid-boric acid-additive ternary anodizing fluid

The invention discloses a sulfuric acid-boric acid-additive ternary anodizing fluid, which is prepared by adding 1.6-7.6ml of sulfuric acid, 0.1-1.1g of boric acid and 5-100mg of additive into 100ml of deionized water. The additive is benzotriazole, 2-mercaptobenzothiazole, dithizone or 8-oxyquinoline. The anodizing fluid of the invention is the improvement of aluminium and aluminium alloy sulfuric acid-boric acid binary anodizing fluid, and cupreous efficient cathodic corrosion inhibitor is added to enable that preferential adsorption of the corrosion inhibitor is carried out on the copper-containing particle position of an aviation aluminum alloy surface, thus forming a compact reticulatepattern complexing product, providing targeted protection on copper-containing aluminum alloy phase particles, decreasing the current concentration tendency, and inhibiting excessive growth of oxidation film cavern defect at the position of the copper-containing aluminum alloy phase particles.
Owner:BEIHANG UNIV

Ultra-trace lead-cadmium ion detection method and detection test strip

The invention discloses an ultra-trace lead-cadmium ion detection method and a detection test strip. The detection method comprises the following steps: (1) acidifying a sample; (2) removing Hg2+ and Zn2+ in the sample; (3) diluting the sample by utilizing a buffer solution to obtain a neutral sample; (4) enabling the neutral sample obtained in the step (3) to be contacted with dithizone to generate a lead-cadmium ion-dithizone complex; (5) adding sulfide solution so as to enable the lead-cadmium ion-dithizone complex to be completely reacted to generate PbS and / or CdS; (6) carrying out silver staining reaction on the mixture containing PbS and / or CdS obtained in the step (5), and determining the concentration of lead and cadmium ions in the to-be-detected sample according to the grey scale of a reaction product. The test strip comprises a substrate film and a dithizone layer, wherein the dithizone layer is compounded onto the substrate film, and the test strip is packaged in a vacuum manner. The detection method and the detection test strip are sensitive inn detection, simple in judgment, capable of reaching the standard of naked eye detection, strong in applicability and stable inn performance.
Owner:HUAZHONG UNIV OF SCI & TECH

Linking dithizone resin and preparation method thereof

The invention discloses chelating resin bonded with dithizone and a method for preparing the same. A functional group of the resin is a dithizone group the construction unit of which is as shown in the graph. The preparation method comprises the following steps: styrene is taken as a monomer, diethylene is taken as a cross linking agent, fluid wax and other substances are taken as a pore-forming agent, magnesium carbonate and other substance are taken as a dispersing agent, and benzoperoxide is taken as an initiator, nitrating agents with different composition proportions are added for nitration and reduction so as to obtain macroporous amino resin, and stannous chloride dihydrate, hydrochloric acid and ethanol are added for diazotization, and acetone solution of the dithizone and glacial acetic acid are added to introduce the functional group so as to obtain the chelating resin bonded with the dithizone. Compared with the loaded resin, the stability of the functional group of the resin is obviously improved, so that the resin has wide application prospect in fields such as the metal separation and pre-enriching in the trace analysis, the heavy metal pollution treatment and recovery in the environment.
Owner:NANJING UNIV

Method and device for sequentially injecting lead in online detection of water quality

The invention relates to a method for sequentially injecting lead in online detection of water quality, wherein each step for detecting lead in stripping voltammetry and quantitative dose delivery of required solvent or solution are finished in sequence with sequential injection method; the method comprises the following steps: plating mercury on the surface of a working electrode by using mercury plating liquid HgSO4 solution or Hg(NO3)2 solution; absorbing lead ions in a raw water sample by using polystyrene-dithizone nanofiber; then eluting and condensing into sample water for detection; respectively injecting the sample water and carrier liquid in a electrolytic bath at fixed quantities, wherein the deposition potential is -1.0 to -1.2V, the deposition time is 140-160s, the cleaning potential is -0.3V, and the time is 15s; carrying out anode stripping voltammetry detection on the sample water so as to obtain a sample water stripping voltammetry curve, wherein the stripping peak area is combined with the stripping peak area of a guide sample; and calculating to obtain the lead concentration of sample water. The invention provides a special detection device, which is accurate in fixed quantity and high in sensitivity and can realize online and quick detection of lead content in various water sources.
Owner:DELIN ENVIRONMENTAL PROTECTION TECH

Anodic oxidation treating fluid containing corrosion inhibition additive

The invention discloses anodic oxidation treating fluid containing corrosion inhibition additive; the treating fluid is formed by adding 1.6-7.6ml of sulfuric acid, 5-30g of modifier and 10-100mg of corrosion inhibition additive in 100ml of deionized water; the modifier is adipic acid or adipate; the corrosion inhibition additive is benzotriazole, 2-mercaptobenzothiazole, dithizone or 8-oxyquinoline; the anodic oxidation treating fluid reduces the concentration of the sulfuric acid, reduces dissolving of bath solution to aerometal basal body and a generated oxidation film, and the corrosion inhibition additive is added for inhibiting excessive expansion of an oxidation film hole defect at the position of copper-bearing alloy phase particles. In the invention, the adipic acid or adipate which is environmental-protection and has low price replaces the using amount of the sulfuric acid, the film forming rate, the film layer compactness and uniformity of the anodic oxidation film are improved.
Owner:BEIHANG UNIV

Nitrogen and sulfur co-doped ordered mesoporous carbon material as well as preparation method and application thereof

The invention discloses a nitrogen and sulfur co-doped ordered mesoporous carbon material as well as a preparation method and application thereof. According to the ordered mesoporous carbon material,SBA-15 is mainly used as a mesoporous molecular sieve template, dithizone is used as a single carbon source, a sulfur source and a nitrogen source and carbon tetrachloride is used as a solvent, and polymerization is carried out to form a nitrogen and sulfur co-doped ordered mesoporous carbon polymer; after the obtained polymer is subjected to high-temperature pyrolysis, a mesoporous molecular sieve SBA-15 is removed by etching, and then the nitrogen and sulfur co-doped ordered mesoporous carbon material is obtained. The preparation method comprises synthesis of the molecular sieve, preparationof the polymer and pyrolysis, and template removal. The nitrogen and sulfur co-doped ordered mesoporous carbon material disclosed by the invention has the advantages of high mechanical strength, uniform pore diameter, strong stability, good biocompatibility and excellent electrochemical detection performance and is an environment-friendly ordered mesoporous carbon material which can be widely applied; the preparation method has the advantages of simple technological flow, moderate reaction conditions, environment protection and the like and can be used for large-scale preparation.
Owner:CENTRAL SOUTH UNIVERSITY OF FORESTRY AND TECHNOLOGY

Solubilization thinner

The invention discloses a solubilized viscosity-reducing agent composed of constituents with weight percent as: 7-15% dithizone solution, 9-13% carbon tetrachloride, 7-11% hydrogen peroxide, 13-15% xylene, 7-11% treated hydrochloride, and water. It has high permeability and speed to come to crude thick oil zone, combine minim water by inorganic solution, disperse gum bitumen and wax in crude oil, and also increase dissolution speed by 2-5 times. This invention is high efficient and fit to low temperature, and saves energy and cost.
Owner:大连百川通水务有限公司

Heavy metal detection method

The invention provides a heavy metal detection method. The method in the invention comprises the steps of: first, preparing a heavy metal dithizone solution and using a digital camera to collect colors in three different shooting conditions; then, using photoshop software to collect data on pictures of different colors; and finally, making a spectral analysis.
Owner:SHANGHAI QIBAO HIGH SCHOOL

Method for detecting trace lead in particulate matters

The invention discloses a method for detecting trace lead in particulate matters. The method comprises following steps: the particulate matters are collected on a filter membrane by an impact type dry sampler; the filter membrane is cut into pieces and placed in a beaker, a concentrated nitric acid and perchloric acid mixed solution is added, the mixture is heated by a heating plate until the particulate matters are totally dissolved, and a transparent digestion solution is obtained; the digestion solution is added to a colorimetric tube, ammonium citrate and hydroxylamine hydrochloride are added respectively, the PH value of the digestion solution is regulated with ammonium hydroxide, potassium tartrate, a dithizone-ethanol solution and a CTAB (cetyltrimethyl ammonium bromide)-ethanol solution are added to the digestion solution after PH value regulation, and nitric acid is adopted for constant volume finally; the solution absorbance is measured by an ultraviolet-visible spectrophotometer at 470 nm and is compared with a standard curve, and the content of lead in the particulate matters is obtained. Non-poisonous drugs are adopted in a detection process, higher safety is realized, lead ions are enriched and calcium ions, sodium ions and the like influencing lead ion detection are covered during detection, and the detection is efficient and accurate.
Owner:NANJING UNIV OF SCI & TECH

Dithizone grafted chelating gel, preparation method thereof and method for treating mercury-containing wastewater

The invention discloses dithizone grafted chelating gel which is prepared from the following raw materials in parts by weight: 1.0-2.0 parts of polyacrylamide gel, 2.0-3.5 parts of formaldehyde, 0.1-0.2 part of dithizone solution and 94.5-96.8 parts of distilled water. The method for preparing the dithizone grafted chelating gel comprises the following steps: adding the polyacrylamide gel in a formula amount into the distilled water with a formula amount, so that the polyacrylamide gel is dissolved to obtain a solution, and regulating the pH of the solution to be 9-11; adding the formaldehyde with a formula amount into the solution, dripping the dithizone solution with a formula amount into a bottle in a drip-by-drip mode, reacting at the temperature of 24-36 DEG C for 120-180 minutes, separating a product, and drying, so as to obtain the dithizone grafted chelating gel. The method is simple and feasible, and the prepared dithizone grafted chelating gel has the high adsorption property on heavy metal pollution ions and has a rapid high-efficiency mercury removal effect on the heavy metal wastewater.
Owner:CHANGAN UNIV

Preparation and application methods for detection agent for detecting zinc content in water

The invention relates to preparation and application methods for a detection agent for detecting zinc content in water. Concentrated sulfuric acid, anhydrous sodium sulfate, potassium pyrophosphate, sodium hyposulfite and thiourea in a weight ratio of 10:35:14:14:105 are weighed and mixed uniformly, and powder I is obtained. Then dithizone, polyethylene glycol 6000, thiourea, sodium acetate and cetyl trimethyl ammonium bromide in a weight ratio of 1:10:1000:500:500 are weighed and mixed uniformly, and powder II is obtained. When in use, the powder I and the powder II are directly added into 5ml of a water sample in order, mixed and dissolved fully. After 10min, the solution is measured by utilization of a spectrophotometer. The preparation method for the detection agent is simple. The detection agent is easy to carry, and easy to safekeep. Detection results are accurate and reliable. The detection agent is suitable for on-site quantitative detection of zinc in water such as underground water, surface water, drinking water, industrial wastewater and the like.
Owner:TONGJI UNIV

Polymer-based detection agent for fast detection of heavy metal lead and its preparation method and use

The invention discloses a polymer-based detection agent for fast detection of a heavy metal lead and its preparation method and use, and belongs to the technical field of analysis. The polymer-based detection agent is characterized in that a layer of N-vinylpyrrolidone and hydroxylated 3-(methylacryloxy)propyltrimethoxysilane nano-particles are coated on the surface of a PET polymer as a base material film by surface photografting; a mixture of dodecyltrimethylammonium bromide, polyving akohol and citric acid is loaded on the nano-particles; and dithizone and glutaraldehyde color-developing agents are loaded on the mixture. The preparation method comprises the following step of coating a layer of unhydroxylated nano-particles on the surface of a base material film, and carrying out hydrolysis, pre-treatment and color-developing agent loading. In use, a standard solution and the polymer-based detection agent undergo a reaction so that standard color gradation is obtained; a solution needing to be detected and the polymer-based detection agent undergo a reaction; and a color of the solution needing to be detected is compared with the standard color gradation. The polymer-based detection agent has the advantages of high detection precision, good repeatability, simple operation and low cost.
Owner:BEIJING UNIV OF CHEM TECH

Mouse islet separation and purification method

The invention discloses a mouse islet separation and purification method. A self-made puncture needle is adopted to reversely puncture a common bile duct and inject collagenase V to digest a pancreatic gland, and inslets are separated and purified by using the combination of density gradient medium centrifugation and manual sorting. Inset density is identified by dithizone staining, and inset activity is identified by AO / PI staining. Inset functionality is detected by a glucose stimulated insulin release experiment. By using the method to extract islets on a large scale, time can be greatly saved, the puncture success rate can be increased, and Ficoll400 formulation time and price can be reduced. In addition, all the yield, purity, activity and function of islets obtained by purification are relatively good, and the method is simple, fast, cheap and efficient.
Owner:SOUTHEAST UNIV

Water sample trace lead fast test kit

The invention discloses a water sample trace lead fast test kit. The test kit comprises a trace lead test reagent, trace lead standard color cards and several consumables. All the components are individually packed, and placed together in an outer box. The trace lead test reagent comprises a hydrochloric acid eluent A, a sodium hydrate neutralization solution B, a dithizone chloroform solution C and a mixture D of hydroxylamine hydrochloride and ammonium citrate. The consumables comprise water samplers, pippet tips, reaction tubes, sulfhydryl filter paper, adsorption funnel, a rack and waste liquid cups. The water sample trace lead fast test kit has the advantages of (1) being capable of being used for screening samples at site under a non-laboratory condition, (2) having no need of the coordination of expensive equipment and high-tech personnel, (3) being capable of completing a test in 2 hours to achieve the fast test of the trace lead, (4) having a test sensitivity, stability and reliability satisfying the requirement of hygiene assessment standard, and (5) having the individually packed test paper, consumables and reagent. The water sample trace lead fast test kit is convenient to carry.
Owner:BEIJING AFD PHARMA TECH DEVCO

Ciprofluoroquinolone C3/C7 dithizone Schiff base, preparation method and application thereof

InactiveCN102516168AStrong in vitro cytotoxic activityGood antitumor activityOrganic chemistryAntineoplastic agentsArylCancer cell
The invention belongs to the technical field of medicine, particularly discloses a ciprofluoroquinolone C3 / C7 dithizone Schiff base, and meanwhile discloses a preparation method of the ciprofluoroquinolone C3 / C7 dithizone Schiff base and application of the ciprofluoroquinolone C3 / C7 dithizone Schiff base in pharmaceuticals. The chemical structural formula of the ciprofluoroquinolone C3 / C7 dithizone Schiff base is shown in a general formula I, wherein Ar is selected from phenyl, substituted phenyl, heterocyclic aromatic aryl alkyl and substituted heterocyclic aromatic aryl alkyl. Tests show that the ciprofluoroquinolone C3 / C7 dithizone Schiff base provided by the invention has strong in vitro cytotoxic activity to L1210, CHO (Chinese hamster ovary) and HL60 cancer cell strains, has strong antitumor activity, can be used for preparing antitumor drugs with human body acceptable pharmaceutical carrier, and can be further made into human body acceptable pharmaceutical salts for preparing antitumor drugs.
Owner:HENAN UNIVERSITY

Double-layer photochromic glass

The invention relates to the technical field of glassmaking, in particular to double-layer photochromic glass. The double-layer photochromic glass comprises a glass bottom plate and a glass cover plate and is characterized in that a sandwich cavity is arranged between the glass bottom plate and the glass cover plate, a photochromic sandwich layer is arranged in the sandwich cavity, the material used by the photochromic sandwich layer comprises the mixture of one or more of benzopyran, fulgide, photochromic spirooxazine, and diarylethene or metal dithizone salt. A production method of the glassincludes the steps of firstly, preprocessing the glass; secondly, etching the sandwich cavity; thirdly, preparing the photochromic sandwich layer; fourthly, preprocessing the glass bottom plate; fifthly, performing glass laminating. The glass has the advantages that the glass can have different colors in different light states, the color changing process does not need to be controlled by electricenergy or heat, energy conservation and reliability are achieved, and the glass is quite suitable for being used as building door and window glass, high in functionality and good in decoration performance.
Owner:合肥协耀玻璃制品有限公司

Preprocessing method for measuring content of noble metal ions in high-purity reagent

The invention discloses a preprocessing method for measuring content of noble metal ions in a high-purity reagent solution. The method comprises the following steps: processing the high-purity reagent solution utilized as a raw material by utilizing a preprocessing column loaded with polyethylene dithizone laminated resin; eluting the enriched noble metal ions by using an eluting agent, and then performing the constant volume process; and using an atomic absorption spectrograph to measure the content of the noble metal ions in the acquired high-purity reagent preprocessed solution, wherein the acquired measured result is consistent with the measured result acquired by using an X fluorescent analysis meter. Compared with the prior art, the method provided by the invention has the advantages that the operation is easy and simple, the noble metal ions in the high-purity reagent are enriched by performing the pressurization ultra-filtration, the post-processing for the acquired preprocessed solution is unnecessary, and the sample can be directly introduced for using the atomic absorption spectrograph to measure the content of noble metal ions in the high purity reagent.
Owner:SHANGHAI CHEM REAGENT RES INST

Preparing method of polysaccharide-based microsphere with dithizone structure

The invention discloses a preparing method of a polysaccharide-based microsphere with a dithizone structure. According to the method, agarose and glucan are taken as aqueous-phase raw materials, cyclohexane, liquid paraffin and methylbenzene are taken as oil phases, Span80, Span60 and the like are taken as emulsifiers, and reversed phase suspension is utilized for preparing the polysaccharide microsphere; then epoxy chloropropane or epibromohydrin is taken as halogen ligand, and then the halogen is modified on the surface of the microsphere under catalysis of PEG or tetrabutylammonium bromide;then a dithizone acetone solution is added, and the dithizone polysaccharide microsphere is obtained after a reaction. The method is easy to operate and mild in condition, and has a wide applicationprospect in the field of trace heavy metal analysis and the field of heavy metal pollution removal.
Owner:程兰青

Method for detecting contents of lead in foods

The invention relates to the technical field of food safety, and discloses a method for detecting contents of lead in foods. According to the method, nitric acid solution, ammonia solution, diammoniumhydrogen citrate solution, editpotassium cyanide solution, dithizone stock solution, lead standard solution, lead standard working solution and dithizone working solution are prepared to carry out adetection test; a spectrophotometer, a 125 ml separating funnel, a 250 ml flask or a 250 ml conical flask and an electronic balance are prepared to fit the detection work; after a sample is treated through a wet resolution method or a dry ashing method, the sample is measured; and finally, the contents of lead in various foods are obtained through a formula. The method for detecting the contents of leads in foods is capable of accurately calculating and detecting liquid foods through the wet resolution method, and visually inspecting the color changes in the foods after the organic matters inthe liquid foods are completely decomposed and subsequent heating is completed, so as to carry out treatment for the next step more rapidly and more timely during the detection and then prevent the measurement results from deviations.
Owner:中农康正技术服务有限公司

Method for simultaneous enrichment and analysis of heavy metal lead, cadmium and mercury ions

InactiveCN102565111BRapid screening and sensitive testingRapid enrichment and analysis detectionMaterial analysis using wave/particle radiationPreparing sample for investigationMercuric ionFluid phase
The invention relates to the field of detection and analysis of heavy metal ions in water solution, and particularly discloses a method for simultaneous enrichment and analysis of heavy metal lead, cadmium and mercury ions, which adopts diethyl disulfide sodium formate or dithizone as a complexing agent, so as to realize complexation with the lead, cadmium and mercury ions to form metal complex, wherein the metal complex is extracted and enriched through the dispersive liquid phase micro-extraction technology, and qualitative and quantitative analysis is simultaneously performed on the lead, cadmium and mercury ions in the water solution through the X-ray fluorescence spectrum technology. The enrichment multiples of the lead, cadmium and mercury ions in the water solution are high, the enrichment is complete, the operation is simple and quick, and the simultaneous qualitative and quantitative analysis on the lead, cadmium and mercury ions is realized.
Owner:ELECTROMECHANICAL PRODS DETECTING TECH CENT OF SHANGHAI ENTRY EXIT INSPECTION & QUARANTINE BUREAU

Method for visually and rapidly detecting organophosphorus pesticide residues through quantum dot fluorescent probe

The invention relates to a preparation method of a quantum dot fluorescent probe capable of detecting organophosphorus pesticide residues. The method comprises the following steps: 1) preparing a CdTe quantum dot aqueous solution; 2) preparing a CdTe@ZnS composite nano material; and 3) preparation of the quantum dot fluorescent probe capable of detecting organophosphorus pesticide residues. The quantum dot dithizone system is prepared by utilizing a fluorescence resonance transfer principle, and the thiophosphate type organophosphorus pesticide is rapidly detected. The process from quantum dot fluorescence closing to quantum dot fluorescence opening is obvious, visible visual detection can be achieved under ultraviolet light, and therefore qualitative detection is achieved. The fluorescence intensity of the quantum dots and the pesticide concentration are in a certain linear relationship, so that quantitative detection is realized.
Owner:BEIJING UNIV OF AGRI

Method for measuring absorbance of hydroxamic acid type high-molecular chelating agent

The invention discloses a method for measuring the absorbance of a hydroxamic acid type high-molecular chelating agent, comprising the following steps: removing a supernatant and adding an ammonium citrate solution until turning blue; then adding nitric acid dropwisely until the solution turns into green, adding a dithizone solution, and violently shaking; repeating the above steps until the green of the dithizone phase after shaking is the same with the green of dithizone itself; accurately adding a dithizone solution, using water as a reference, measuring the absorbance at a position of 510 mm. According to the invention, the absorbance of the hydroxamic acid type high-molecular chelating agent can be rapidly measured, the precision of the measurement is high, the measurement steps are simple, and the labor cost and time cost are reduced.
Owner:袁俊海

Method for analyzing sulfate ions in preparation process of lithium ion battery

The invention discloses a method for analyzing sulfate ions in the preparation process of a lithium ion battery. The method comprises the following steps: adjusting the pH value of a to-be-detected sample to 7.5-8.5 by using an alkaline substance and then adding deionized water; then adding a bromophenol blue indicator until the solution becomes blue; adjusting the solution to yellow green by using a (8 + 92) nitric acid solution or a 0.2 mol / L ammonia water solution, adding an acetone acetate solution and a dithizone acetone solution until the solution is turned into treasure green, and finally titrating by using a Pb (NO3) 2 standard solution until the solution is turned into brownish red from treasure green, thereby obtaining the end point. When the method is used at an equivalent point, the color of the indicator is changed into brownish red from royal green, the color change is sensitive, trace and ultratrace sulfate radicals can be measured, and the method has the advantages of simplicity, convenience, accuracy and rapidness.
Owner:SHANSHAN ADVANCED MATERIALS QUZHOU CO LTD

Method of Recovering Heavy Metal and Reagent for Recovery of Heavy Metal for Use in the Same

ActiveUS20130078726A1Variation in heavy metal recovery rate among samples is suppressedImprove reliabilitySemi-permeable membranesAnalysis using chemical indicatorsHeavy metal chelationIodoacetic acid
The present invention provides a method of recovering a heavy metal by which the variation in heavy metal recovery rate among samples can be suppressed. A mixture of a sample and a chelating agent capable of chelating with a heavy metal is prepared. A complex between a heavy metal being in the sample and the chelating agent is formed in the presence of a masking agent for a thiol group in the mixture. The heavy metal in the sample is recovered by recovering the complex. By this method, a heavy metal can be recovered with suppressing the variation in the recovery rate among samples. The chelating agent preferably is 1,5-diphenyl-3-thiocarbazone (dithizone). As the masking agent, N-ethylmaleimide, iodoacetamide, iodoacetic acid, or the like can be used.
Owner:ARKRAY INC

Kit for quickly detecting water sample lead on site

The invention discloses a kit for quickly detecting water sample lead on site. The kit comprises a lead detection reagent, a lead test paper, a standard lead color card and a consumable material which are independently packaged, wherein the lead detection reagent includes a hydrochloric acid eluant and a sodium hydroxide neutralizing solution; the lead test paper is arranged as a sulfydryl dithizone test paper; the standard lead color card is arranged as a colorful picture after the developing reaction of 10ul standard lead solution on the sulfydryl dithizone test paper; the consumable material includes sulfydryl adsorption filter paper, a water sampling sucker, an external box, a filtering elution bracket, a shafting liquid absorber, an effluent tank and an elution plate. The kit has the beneficial effects that (1) the operation process is greatly simplified, the detection time is shortened, the detection can be completed within 30min and the quick qualitative determination for the lead on the sampling site can be realized; (2) high-cost device and high-level technicians are not required; (3) the detection sensitivity, stability and reliability all meet the requirement of hygienic evaluation standard; and (4) the test paper, the consumable material and the reagent are respectively independently packaged and are portable.
Owner:BEIJING AFD PHARMA TECH DEVCO

Rapid testing method of zinc salt in milk

The invention relates to a rapid testing method of a zinc salt in milk, which comprises the following steps that: 2ml of a standard milk sample and 2ml of a milk sample to be tested are respectively added into 1ml of dithizone-carbon tetrachloride solution with the concentration of 0.1g / L; the standard milk sample is mixed with the dithizone-carbon tetrachloride solution uniformly to prepare a mixture A, and the color liquid surface dots of the mixture A and the color of lower layered liquid serve as standard color disks; the milk sample to be tested is mixed with the dithizone-carbon tetrachloride solution uniformly to prepare a mixture B, the color of liquid surface dots of the mixture B and the color of the lower layered liquid are observed; the color of the liquid surface dots of the mixture B and the color of the lower layered liquid are visually compared with the color of the standard color disks, if the color of the liquid surface dots is the same with the color of the lower layered liquid, the zinc content of the milk sample to be tested is above 50mg / kg, and if the color of the liquid surface dots is different from the color of the lower layered liquid, the zinc content of the milk sample to be tested is below 50mg / kg. The method has the advantages of low cost, convenient and rapid operation and short testing time, and is a rapid qualitative testing method.
Owner:INNER MONGOLIA MENGNIU DAIRY IND (GRP) CO LTD
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