Quantum dot and preparation method thereof and photoelectric device
A technology of quantum dots and quantum dot solutions, which is applied in the field of quantum dot luminescent materials, can solve problems such as the difficulty in regulating the composition and structure of quantum dots, and achieve the effects of avoiding self-nucleation, narrowing the half-peak width of fluorescence, and improving the energy band structure
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[0037] Since it is difficult for the Cd-free quantum dots in the prior art to form quantum dots with tunable composition and structure, in order to improve this situation, in a typical embodiment of the present application, a II-III-V-VI quantum dot is provided. The preparation method includes: step A, preparing a first nanocluster, a second nanocluster and a third nanocluster, wherein the first nanocluster is III-V nanocluster, the second nanocluster is The clusters are III-II-V nanoclusters, and the third nanoclusters are III-II-VI nanoclusters; step B, the first nanocluster is mixed with a non-coordinating solvent to form a first quantum dot solution; step C, mixing and heating the second nanocluster with the first quantum dot solution to form a second quantum dot solution; Step D, mixing and heating the third nanocluster with the second quantum dot solution to form a third quantum dot solution, the third quantum dot solution The third quantum dots in the dot solution are I...
Example Embodiment
[0064] Example 1
[0065] (1) First nanocluster solution: 0.2 mmol In(Ac) 3 (Indium acetate), 0.6 mmol hexadecanoic acid and 6 mL ODE (octadecene) were added to a 50 mL three-necked flask, and the three-necked flask was placed under N 2 It was heated to 180°C in the exhaust state, kept at 180°C for 30 minutes, and then lowered to 40°C. 0.1 mmol of TMS-P (tris(trimethylsilyl)phosphine) and 1 mmol of trioctylamine were added to react for 20 min to form InP nanoclusters, which were cooled to room temperature for later use.
[0066] Second nanocluster solution: 0.2 mmol In(Ac) 3 (Indium acetate), 0.2mmol Zn(Ac) 2 (zinc acetate), 1.0 mmol hexadecanoic acid and 6 mL ODE (octadecene) were added to a 50 mL three-necked flask, and the three-necked flask was heated to 180°C under N2 exhaust state, kept at 180°C for 30min, and then decreased to 60°C. 0.1 mmol of TMS-P (tris(trimethylsilyl)phosphine) and 5 mmol of dioctylamine were added to react for 20 min to form InZnP nanoclusters...
Example Embodiment
[0070] Example 2
[0071] (1) First nanocluster solution: 0.2 mmol In(Ac) 3 (Indium acetate), 0.6 mmol hexadecanoic acid and 6 mL ODE (octadecene) were added to a 50 mL three-necked flask, and the three-necked flask was placed under N 2 It was heated to 180°C in the exhaust state, and after holding at 180°C for 30 minutes, it was lowered to 60°C. 0.04 mmol of TMS-P (tris(trimethylsilyl)phosphine) and 1 mmol of trioctylamine were added to react for 20 min to form InP nanoclusters, which were cooled to room temperature for use.
[0072] Second nanocluster solution: 0.2 mmol In(Ac) 3 (Indium acetate), 0.1mmol Zn(Ac) 2 (zinc acetate), 0.8 mmol hexadecanoic acid and 6 mL ODE (octadecene) were added to a 50 mL three-necked flask, and the three-necked flask was heated to 180° C. under N2 exhaust state, kept at 180° C. for 30 min, and then decreased to 60°C. 0.04 mmol of TMS-P (tris(trimethylsilyl) phosphine) and 5 mmol of dioctylamine were added to react for 20 min to form InZnP...
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