A kind of oil-filled carbon nanotube binary emulsion coprecipitation rubber and preparation method thereof
A carbon nanotube and emulsion co-precipitation technology is applied in the field of polymer-based nanocomposite materials to achieve the effects of simple process, strong operability and easy industrialization
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[0019] (1) Preparation of modified carbon nanotube suspension: multi-walled carbon nanotubes and water are made into a suspension of 10wt% concentration, and the modifier vinylbenzenetrimethyl chloride of carbon nanotube quality 1wt% is added thereto ammonium chloride, stirred and reacted at 60° C. for 1 hour; then sodium dodecylbenzenesulfonate with 2 wt % carbon nanotube mass was added thereto, and the stirring was continued for 10 minutes to prepare a modified carbon nanotube suspension.
[0020] (2) Preparation of emulsified oil: uniformly mix aromatic oil with water and emulsifier, disperse at 60° C. for 30 minutes in a high-speed shear emulsifier at 3000 r / min, and then prepare emulsified oil.
[0021] (3) Preparation of oil-filled carbon nanotube binary emulsion co-precipitation rubber: add the modified carbon nanotube suspension and anti-aging agent to the solution composed of two kinds of rubber latex according to a certain proportion, and stir at 60°C for 20 minutes ...
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