A kind of oil-filled carbon nanotube binary emulsion coprecipitation rubber and preparation method thereof

A carbon nanotube and emulsion co-precipitation technology is applied in the field of polymer-based nanocomposite materials to achieve the effects of simple process, strong operability and easy industrialization

Inactive Publication Date: 2016-03-09
QINGDAO UNIV
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Problems solved by technology

The above methods all mix the rubber latex produced by a single variety of emulsion polymerization with carbon nanotubes, and do not involve the preparation of binary emulsion co-precipitation rubber

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  • A kind of oil-filled carbon nanotube binary emulsion coprecipitation rubber and preparation method thereof

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[0019] (1) Preparation of modified carbon nanotube suspension: multi-walled carbon nanotubes and water are made into a suspension of 10wt% concentration, and the modifier vinylbenzenetrimethyl chloride of carbon nanotube quality 1wt% is added thereto ammonium chloride, stirred and reacted at 60° C. for 1 hour; then sodium dodecylbenzenesulfonate with 2 wt % carbon nanotube mass was added thereto, and the stirring was continued for 10 minutes to prepare a modified carbon nanotube suspension.

[0020] (2) Preparation of emulsified oil: uniformly mix aromatic oil with water and emulsifier, disperse at 60° C. for 30 minutes in a high-speed shear emulsifier at 3000 r / min, and then prepare emulsified oil.

[0021] (3) Preparation of oil-filled carbon nanotube binary emulsion co-precipitation rubber: add the modified carbon nanotube suspension and anti-aging agent to the solution composed of two kinds of rubber latex according to a certain proportion, and stir at 60°C for 20 minutes ...

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Abstract

The invention discloses an oil-filled carbon nanotube binary emulsion co-precipitation rubber and a preparation method thereof. The main components are: 100 parts by weight of rubber, 1-80 parts by weight of oil, 1-80 parts by weight of carbon nanotubes, anti-aging 0.1-5 parts by weight of agent; the preparation method is: adding modified carbon nanotubes, emulsified oil, and anti-aging agent into the emulsion composed of two kinds of rubber latex, keeping the temperature at 30-60°C and stirring for 1-30 minutes; Adding flocculant to the mixture, the oil-filled carbon nanotube binary emulsion co-precipitated rubber was prepared by flocculation, dehydration and drying. The method can overcome the shortcomings of non-uniform filler dispersion and high energy consumption in the preparation of binary rubber nanocomposites by the traditional mechanical blending method, and has simple process, low cost and easy popularization. In the composite material prepared by the method, the carbon nanotubes are uniformly dispersed in the rubber matrix and play an effective reinforcing role. The emulsion co-precipitation rubber prepared by this method has greatly improved mechanical properties, wear resistance, antistatic and the like.

Description

technical field [0001] The invention relates to the technical field of polymer-based nanocomposite materials, in particular to an oil-filled carbon nanotube binary emulsion co-precipitation rubber and a preparation method thereof. Background technique [0002] The research on polymer / carbon nanotube nanocomposites is a hot spot in recent years. Due to the special tubular structure of carbon nanotubes, it has excellent mechanical properties, electrical conductivity, thermal conductivity, toughness, etc. In recent years, there have been many researches on rubber / Research on carbon nanotube nanocomposites, due to these excellent properties of carbon nanotubes, a small amount of carbon nanotubes can be combined with rubber to prepare rubber / carbon nanotube nanocomposites with high strength and good conductivity. [0003] Combining rubber to make binary composite materials can make use of the advantages and properties of a single rubber to complement each other, so as to obtain ...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): C08L9/06C08L9/02C08L7/00C08L11/00C08K5/01C08K5/103C08K9/06C08K7/24
Inventor宋国君谷正王立李培耀
OwnerQINGDAO UNIV