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Preparation method of environment-friendly textiles capable of reducing formaldehyde

A technology for textiles and formaldehyde, applied in the field of environmentally friendly textiles preparation, can solve the problems of causing dermatitis, carcinogenicity, and insufficient attention, and achieve the effect of reducing formaldehyde

Inactive Publication Date: 2015-04-29
李长娟
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Formaldehyde is a nasty and irritating chemical that may cause dermatitis and has a potential carcinogenic effect. The occupational safety and health regulations of many countries have made obvious limits on the concentration of formaldehyde in the air. On textiles As early as 1974, the Japanese government made regulations, but it did not attract enough attention in our country for a period of time, perhaps because the awareness of environmental protection has not yet reached a certain height, coupled with developed countries The "green barrier" has not yet been used as a trade weapon. It was not until the 1990s, the rise of environmentally friendly textiles, and the introduction of relevant national laws and regulations, that the awareness of formaldehyde restrictions was raised to the same level as that of banned dyes. Alternatives are possible. The new products of formaldehyde-releasing additives have become the focus of domestic attention

Method used

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Embodiment

[0013] Ways to reduce the amount of formaldehyde released: one is to etherify the methylol that may continuously release formaldehyde; the other is to use formaldehyde scavengers:

[0014] (1) Blocking hydroxymethyl: It is an effective way to reduce the amount of formaldehyde released. According to the timing of blocking, it can be divided into: ① during the production process of the product; ② during cross-linking during use;

[0015] (2) To produce low-formaldehyde products, when lower alcohol is used to etherify methylol, the stability of C-N bond can be improved. At this time, unreacted free formaldehyde can also react with alcohol to form acetal or hemiacetal, thereby reducing formaldehyde Generally, methanol, ethanol, diethylene glycol, etc. are commonly used. The free formaldehyde in the etherified 2D resin and melamine resin products can be reduced to less than 0.3%. Among them, the etherified 2D can reduce the formaldehyde emission of the fabric. to 300ppm, and diethy...

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Abstract

The invention relates to a preparation method of environment-friendly textiles capable of reducing formaldehyde. The method comprises the following aspects: 1 blocking hydroxymethyl, which is an effective method for reducing formaldehyde emission, and can be divided into the following steps according to different blocking time: (1) blocking in a product production process, and (2) blocking when crosslinking in use; 2 producing a low-formaldehyde product, when hydroxymethyl is etherified with low-level alcohols, the stability of a C-N bond can be improved; and (3) adding polyhydric alcohols to a finishing liquid, so as to reduce the formaldehyde emission to not higher than 400ppm. According to the preparation method, formaldehyde can be effectively reduced, and the environment-friendly textiles are produced.

Description

technical field [0001] The invention relates to a method for preparing environmentally friendly textiles with reduced formaldehyde, belonging to the technical field of textile preparation. Background technique [0002] Formaldehyde is a nasty and irritating chemical that may cause dermatitis and has a potential carcinogenic effect. The occupational safety and health regulations of many countries have made obvious limits on the concentration of formaldehyde in the air. On textiles As early as 1974, the Japanese government made regulations, but it did not attract enough attention in our country for a period of time, perhaps because the awareness of environmental protection has not yet reached a certain height, coupled with developed countries The "green barrier" has not yet been used as a trade weapon. It was not until the 1990s, the rise of environmentally friendly textiles, and the introduction of relevant national laws and regulations, that the awareness of formaldehyde res...

Claims

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Application Information

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IPC IPC(8): D06M15/37D06M15/423D06M13/148D06M13/144D06M13/165
Inventor 李长娟
Owner 李长娟
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