Zr-Nb-based alloy with good additive manufacturing forming performance and application of Zr-Nb-based alloy

A technology of additive manufacturing and formability, which is applied in the field of Zr-Nb based alloys, can solve the problems that the mechanical properties of additive manufacturing components cannot be fully utilized, and achieve the effects of good comprehensive mechanical properties, low magnetic susceptibility, and good mechanical properties

Inactive Publication Date: 2018-04-10
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
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Problems solved by technology

At present, most of the alloys used in additive manufacturing are traditional casting alloys or forging alloys, but the composition design of these alloys is based on the process characteristics, microstructure, alloying characteristics and strengthening and toughening mechanism of the alloy in the casting or forging process. The manufacturing process characteristics determine that its microstructure and alloying characteristics must be quite different from traditional castings or forgings, so that the design of these alloys usually cannot give full play to the mechanical properties of additive manufacturing components, and it is necessary to redefine the special alloys for additive manufacturing. Design, and the main feature of additive manufacturing is that the alloy undergoes the whole process from melting to solidification in a short time, so the core material selection is based on high melt stability and compatibility between the melt and the solid structure, while the structure From the source point of view, the various properties of the material are related to the chemical process

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  • Zr-Nb-based alloy with good additive manufacturing forming performance and application of Zr-Nb-based alloy
  • Zr-Nb-based alloy with good additive manufacturing forming performance and application of Zr-Nb-based alloy
  • Zr-Nb-based alloy with good additive manufacturing forming performance and application of Zr-Nb-based alloy

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Embodiment Construction

[0013] The following examples will further illustrate the invention.

[0014] Based on Zr-Nb alloy, the atomic integer substitution of alloy elements was carried out according to the double-cluster alloy design model.

[0015] The specific embodiments of the present invention are described below in conjunction with specific experimental steps.

[0016] 1. Preparation of alloys: According to the design model of double-cluster alloys [Zr-Zr 14 +Zr-Zr 8 Nb 6 ]NbZr=Nb 7 Zr 25 , the binary alloy composition is Nb 21.8 Zr 78.2 (at.%), the element is converted from atomic percentage to mass percentage of 22.1Nb-77.9Zr (wt.%) for composition ratio; the prepared alloy raw material is smelted multiple times under the protection of Ar gas atmosphere in a vacuum arc furnace , the alloy composition is uniform, and the master alloy ingot is obtained. The ingredients are in figure 1 near the eutectic point.

[0017] 2. Observation of as-cast microstructure: metallographic preparat...

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Abstract

The invention discloses a Zr-Nb-based alloy with good additive manufacturing forming performance and application of the Zr-Nb-based alloy, and belongs to the technical field of metal additive manufacturing. Components of the Zr-Nb-based alloy are from a dual cluster alloy component design model. The expression formula of the alloy element atomic percent (at./%) is Zr75+/-2(Zr, Mo, Sn)3.1+/-0.5(Zr,Ti, Hf, Nb, Ta)21.9+/-1.5, wherein (Zr, Ti, Hf, Nb, Ta) elements are single, or the mixed total quantity is 21.9+/-1.5 at./%, (Zr, Mo, Sn) elements are single, or the mixed total quantity is 3.1+/-0.5 at./%, and the total quantity of the other elements is controlled within 1 at.%. The main alloying element of the alloy is the Nb element; the low-elasticity-modulus Nb element has low magnetic susceptibility; meanwhile, grains of the alloy can be refined; the oxidization resistance of alloy melt and melt stability are improved; liquid-solid phase areas are reduced; flowability is enhanced; andthe alloy has good melt and solid structure compatibility and can be used for additive manufacturing forming.

Description

technical field [0001] The invention relates to a Zr-Nb base alloy with good additive manufacturing forming performance and application thereof, which is expected to be used in the technical field of metal additive manufacturing. Background technique [0002] Zr-Nb-based alloys are the main materials for medical devices and implants because of their high strength, good toughness and biocompatibility, low magnetic susceptibility and Young's modulus. However, traditional processing methods are used to process the implants. Due to the differences in the shape and size of the implants of different patients, it is necessary to mold according to the specific requirements of different patients, which will consume a lot of time and cost. Additive manufacturing is an emerging manufacturing process that is based on digital models and uses high-energy beam particle flow as a heat source to accumulate materials point by point or layer by layer to form three-dimensional solid parts. Bec...

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C16/00B33Y70/00
CPCC22C16/00B33Y70/00
Inventor 刘田雨董闯闵小华王存山
Owner DALIAN UNIV OF TECH
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