Nanometer carrier for targeting treatment of myocardial injury and application thereof
A nano-carrier and targeted therapy technology, applied in the field of biomedicine, can solve problems such as damage to heart function, limit the efficiency of stem cell transplantation treatment, and have no specificity, and achieve the effect of reducing side effects
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Embodiment 1
[0040] This embodiment provides a method for preparing a tanshinone IIA-loaded nanocarrier, which sequentially includes the following steps:
[0041] S1) Dissolve carboxyl-salted polylactic acid-glycolic acid in dichloromethane, then add N-hydroxysuccinimide and 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide salt Acid salt, activated to produce polylactic acid-glycolic acid-N-hydroxysuccinimide; after the activation reaction, followed by precipitation with ice ether, dialysis and vacuum drying; the abbreviation of polylactic acid-glycolic acid-N-hydroxysuccinimide PLG-NHS, PLG-NHS is a polymer of the structure represented by formula (I);
[0042]
[0043] Among them, n≥2;
[0044] S2) Dissolve PLG-NHS into chloroform, add aminopolyethylene glycol carboxyl group and N,N-diisopropylethylamine to activate it to form polylactic acid-glycolic acid-polyethylene glycol; after the activation reaction, Then carry out ice methanol precipitation, ice methanol washing and vacuum drying in seque...
Embodiment 2
[0056] This embodiment provides a method for preparing tanshinone IIA-loaded nanocarriers. The differences from Embodiment 1 are:
[0057] 1) In step S1, the amount ratio of polylactic acid-glycolic acid, N-hydroxysuccinimide and 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride is 0.1:10:1, the total volume of dichloromethane, polylactic acid-glycolic acid, N-hydroxysuccinimide and 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride and The volume ratio of dichloromethane is 5:1, the activation reaction time is 4h, dichloromethane, polylactic acid-glycolic acid, N-hydroxysuccinimide and 1-(3-dimethylaminopropyl)-3- The ratio of the total volume of ethylcarbodiimide hydrochloride to the volume of glacial ether is 1:10, dialysis adopts a dialysis bag with a molecular weight cut-off of 500, the temperature of vacuum drying is 50℃, and the time of vacuum drying is 19h;
[0058] 2) In step S2, the ratio of PLGA-NHS to N,N-diisopropylethylamine is 1:5, the activation ...
Embodiment 3
[0062] This embodiment provides a method for preparing tanshinone IIA-loaded nanocarriers. The differences from Embodiment 1 are:
[0063] 1) In step S1, the amount ratio of polylactic acid-glycolic acid, N-hydroxysuccinimide and 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride is 1:1:1, the total volume of dichloromethane, polylactic acid-glycolic acid, N-hydroxysuccinimide and 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride and The volume ratio of dichloromethane is 20:1, the activation reaction time is 12h, dichloromethane, polylactic acid-glycolic acid, N-hydroxysuccinimide and 1-(3-dimethylaminopropyl)-3- The ratio of the total volume of ethylcarbodiimide hydrochloride to the volume of glacial ether is 1:20, dialysis adopts a dialysis bag with a molecular weight cut-off of 3500, the temperature of vacuum drying is 60℃, and the time of vacuum drying is 12h;
[0064] 2) In step S2, the ratio of PLGA-NHS to N,N-diisopropylethylamine is 1:10, the activation...
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