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A kind of oil-releasing silica gel and its preparation method and application

A technology of silica gel and rubber materials, which is applied in the field of oil-discharging silica gel and its preparation. It can solve the problems of difficult control of oil-discharging parts, large compression permanent deformation, and drug contamination, etc., and achieve good lubricating effect, reduced addition amount, and stable oil production. control effect

Active Publication Date: 2021-03-30
HANGZHOU NORMAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the peroxide vulcanization system used in the above method has its own defects. For example, the peroxide vulcanized silicone rubber will leave acid residues, the cleaning process is complicated, and the compression set is large. It is not suitable for sealing devices and medical and health industries, and it is also very difficult. It is difficult to apply to medical rubber stoppers, and the oil outlet is difficult to control, and it is easy to cause a large amount of silicone oil to dissolve in the drug, causing drug contamination

Method used

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  • A kind of oil-releasing silica gel and its preparation method and application
  • A kind of oil-releasing silica gel and its preparation method and application
  • A kind of oil-releasing silica gel and its preparation method and application

Examples

Experimental program
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Effect test

Embodiment 1

[0043] Take 100 parts of methyl-terminated polymethyl vinyl raw rubber with a molecular weight of 500,000 and a vinyl content of 0.05 wt%, 8 parts of a hydrogen-containing crosslinking agent with a hydrogen content of 0.8 wt% and a viscosity of 25 mPa·s, and 2 parts Hydroxyl silicone oil with a hydroxyl content of 6.0wt% and a viscosity of 20mPa·s, and 45 parts of precipitated white carbon black were added to a kneader and kneaded into a block, heated to 150°C, and kneaded at -0.05Mpa for 30min to obtain a common compound Rubber compound.

[0044] Take 100 parts of methyl-terminated polymethyl vinyl raw rubber with a molecular weight of 500,000 and a vinyl content of 0.05 wt%, 8 parts of a hydrogen-containing crosslinking agent with a hydrogen content of 0.8 wt% and a viscosity of 25 mPa·s, and 2 parts Hydroxyl silicone oil with a hydroxyl content of 6.0wt% and a viscosity of 20mPa·s, 2 parts of silicone wax, 1 part of polyisobutylene, 0.2 parts of perfluorohexylethylene, and ...

Embodiment 2

[0049] Take 100 parts of terminal vinyl polymethylvinyl with a molecular weight of 650,000 and a vinyl content of 0.06 wt%, 10 parts of a hydrogen-containing crosslinking agent with a hydrogen content of 0.5 wt% and a viscosity of 20mPa·s, and 2 parts of a hydroxyl content 8wt% high-vinyl silicone oil with a viscosity of 25mPa·s, 40 parts of fumed white carbon black is added to a kneader and kneaded into a block, the temperature is raised to 160°C, and the kneading is continued for 15min at -0.06MPa to obtain a common kneading Gum.

[0050] Take 100 parts of vinyl-terminated polymethylvinyl raw rubber with a molecular weight of 650,000 and a vinyl content of 0.05%, 10 parts of a hydrogen-containing crosslinking agent with a hydrogen content of 0.5 wt% and a viscosity of 20 mPa·s, and 2 parts of hydroxyl Add hydroxy silicone oil with a content of 8.0wt% and a viscosity of 30mPa·s, 1 part of liquid paraffin, 2 parts of polyisobutylene, 0.5 parts of perfluorobutylethylene, and 40...

Embodiment 3

[0053] Take 100 parts of methyl-terminated polymethyl vinyl raw rubber with a molecular weight of 720,000 and a vinyl content of 0.08 wt%, 15 parts of a hydrogen-containing crosslinking agent with a hydrogen content of 0.1 wt% and a viscosity of 40 mPa·s, and 5 parts Hydroxyl silicone oil with a hydroxyl content of 10.0wt% and a viscosity of 30mPa·s, and 25 parts of precipitated white carbon black were added to a kneader and kneaded into a block, heated to 160°C, and kneaded at -0.06MPa for 15 minutes to obtain a common compound Rubber compound.

[0054] Take 100 parts of methyl-terminated polymethyl vinyl raw rubber with a molecular weight of 720,000 and a vinyl content of 0.08 wt%, 15 parts of a hydrogen-containing crosslinking agent with a hydrogen content of 0.1 wt% and a viscosity of 40 mPa·s, and 2 parts Hydroxyl silicone oil with a hydroxyl content of 10.0wt% and a viscosity of 30mPa·s, 1 part of polyisobutylene, 1 part of polyisobutylene, 0.5 part of perfluorohexylethy...

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Abstract

The invention discloses oil-release silica gel which comprises the following raw materials in parts by mass: 100 parts of medical crude silica gel, 2-5 parts of a structure control agent, 5-15 parts of a hydrogen-containing cross-linking agent, 20-45 parts of a reinforcing filler, 0.1-1 part of an aid and 1-10 parts of a lubricant. The invention furthermore provides a preparation method of the oil-release silica gel. The preparation method comprises the following steps: mixing the raw materials according to a ratio, kneading the mixture into a solid block, increasing the temperature to 140-160DEG C, and continuously kneading the mixture for 15-60 minutes at pressure of minus 0.04MPa to 0.08MPa, so as to obtain the oil-release silica gel. The invention furthermore provides application of the oil-release silica gel. The oil-release silica gel can be cross-linked with common silica gel to manufacture a self oil-release lubricating piston. The piston is good in compatibility and adhesiveness, stable in oil release and good in lubricating effect, in addition has excellent properties such as ultraviolet resistance, chemical medicine resistance, small permanent compression deformation and biological sluggishness, and meets standards of the medical industry, and a step of silicification in the injection piston production process can be canceled.

Description

technical field [0001] The invention relates to the technical field of medical silicone rubber, in particular to an oil-releasing silicone rubber and its preparation method and application. Background technique [0002] Syringes are a common medical appliance. After repeated use, the syringes have serious piston wear, which makes the sealing effect with the syringe barrel poor and prone to air leakage. How to reduce the friction force between the syringe piston and the cylinder wall so that it has good lubricating performance has become an important issue. [0003] The existing method is mainly to coat a layer of lubricating liquid between the syringe barrel and the piston, and let the lubricating liquid fill the gap after the piston becomes smaller, so as to achieve the effect of lubrication and sealing. However, this method has a limited number of lubrication times, and it is easy to dissolve in a large amount in the drug, causing pollution to it and affecting the effect ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L83/07C08L83/04C08L83/05C08L91/06C08L23/20C08K3/36
CPCC08L83/04C08L2203/02C08L2205/025C08L2205/03C08L2205/035C08L91/06C08L23/22C08K3/36
Inventor 张国栋夏乔琦汤龙程郭坤雨赵丽王华兰龚丽秀
Owner HANGZHOU NORMAL UNIVERSITY