Compound taking triarylamine as core, and application of compound
A compound, triarylamine technology, applied in organic chemistry, chemical instruments and methods, electrical components, etc., can solve different problems
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Embodiment 1
[0062] The synthesis of embodiment 1 compound 2
[0063]
[0064] Dissolve 0.01 mol of reactant I-1 and 0.012 mol of reactant II-1 in 150 mL of toluene, add 0.015 mol of potassium tert-butoxide, and 0.0001 mol of potassium tert-butoxide, and react at 120°C for 24 hours under a nitrogen atmosphere, then sample and spot the plate. After the reaction is complete, cool and filter, and the filtrate is rotary evaporated to remove the solvent, and the crude product is passed through a silica gel column to obtain compound 2, with an HPLC purity of 99.26% and a yield of 76.95%; elemental analysis structure (C 55 h 35 N) Theoretical: C, 93.06; H, 4.97; N, 1.97; Tested: C, 93.03; H, 4.98; N, 1.99. HRMS (EI): theoretical value: 709.2770, found value: 709.2724.
Embodiment 8
[0065] The synthesis of embodiment 8 compound 115
[0066]
[0067] 0.01mol reactant I-2 and 0.012mol reactant II-6 were dissolved in 150mL toluene / ethanol (V 甲苯 :V 乙醇 =5:1) In the mixed solution, add 0.0002mol Pd(PPh 3 ) 4 and 0.02mol K 2 CO 3 , reacted at 110°C for 24 hours under a nitrogen atmosphere, took a sample and spotted the plate, after the reactants were completely reacted, cooled and filtered, the filtrate was rotary evaporated to remove the solvent, and the crude product was passed through a silica gel column to obtain compound 115; HPLC purity 98.97 %, yield 74.5%; elemental analysis structure (C 68 h 51 N) Theoretical: C, 92.58; H, 5.83; N, 1.59; Found: C, 92.58; H, 5.84; N, 1.58. HRMS (EI): theoretical value: 881.4022, measured value: 881.4098.
[0068] Repeat the preparation process of Example 1 or Example 8 to synthesize the following compounds; wherein reaction condition I represents that the preparation process is the same as in Example 1; reacti...
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