The present invention relates to an organic electroluminescent compound containing adamantane and a heterocyclic structure and its preparation method and application. Its chemical structural formula is shown in general formula I: wherein, X exists or does not exist; Independently selected from chemical bonds, O, S, Si(R4R5), C(R6R7), NR8; Y1‑Y9 independently selected from carbon, nitrogen, oxygen, sulfur atoms, at least one of which is a heteroatom; R1‑R3 each independently selected from methyl, ethyl, propyl, tert-butyl, alkoxy, alkylmercapto, aryloxy, phenyl, biphenyl, or naphthyl; Ar1 and Ar2 are each independently selected from naphthyl, Phenanthryl, phenyl, methylphenyl, terphenyl, biphenyl, dibenzofuran, dibenzothiophene, cyclopentadithiophene, cyclopentadifuran, fluorene and their derivatives. The compound changes the spatial structure and physical and chemical properties of the compound through the use of the adamantane structure and the introduction of heteroatoms. As a luminescence auxiliary layer, the driving voltage of the device can be greatly reduced, and the life and efficiency of the device can be significantly improved.