Double-mirror hot-melt adhesive film, preparation method, application
A technology of hot-melt adhesive film and adhesive film, applied in the field of nano-materials, can solve the problems of increasing material costs, difficult recycling of composite release films and protective films, and white pollution of the environment
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[0039] further, see figure 2 , the invention provides a method for preparing microcapsules, comprising: dissolving catalyst and aniline in an organic solvent to form solution A; dissolving concentrated sulfuric acid in an aqueous emulsifier solution to form solution B; moving organic solution A into solution B In the process, a clear organic-water interface layer is formed; heating causes the organic-water interface layer to react until the water phase turns yellow completely and produces granular solids; the reaction is stopped, and the lower layer mixture is centrifuged; the separated solid product is passed through Washing with water and absolute ethanol; vacuum drying to obtain microcapsules.
[0040] further, see figure 1 , the invention provides a method for preparing a hot-melt adhesive film, comprising: blending and melting microcapsules and base film raw materials, peroxides, crosslinking monomers, and silane coupling agents through a mold to form an adhesive film m...
Embodiment 1
[0050] (1) Preparation of microcapsules
[0051] Dissolve 5 parts of catalyst and 10 parts of aniline in a solvent to form an oil phase; slowly add the oil phase to the upper layer of an aqueous solution containing 30 parts of concentrated sulfuric acid and 0.5 parts of an emulsifier to form a clear organic-water phase interface, and control the reaction temperature at Around 80°C. After the solution at the interface turns yellow and gradually diffuses into the water phase, the water phase turns yellow completely, and granular solids are produced. After the reaction was stopped, the mixture in the lower layer was centrifuged, and the collected solid product was washed with water and absolute ethanol, and dried in vacuum at 70°C to obtain microcapsules containing the catalyst.
[0052] (2) Preparation of hot melt adhesive film
[0053] Blend and add 6 parts of microcapsules, 86.2 parts of base film raw materials, 0.5 parts of peroxide, 5 parts of crosslinking monomer, and 0.4...
Embodiment 2
[0055] (1) Preparation of microcapsules
[0056] Dissolve 20 parts of catalyst and 20 parts of aniline in a solvent to form an oil phase; slowly add the oil phase to the upper layer of an aqueous solution containing 50 parts of concentrated sulfuric acid and 1 part of emulsifier to form a clear organic-water phase interface, and control the reaction temperature at Around 80°C. After the solution at the interface turns yellow and gradually diffuses into the water phase, the water phase turns yellow completely, and granular solids are produced. After the reaction was stopped, the mixture in the lower layer was centrifuged, and the collected solid product was washed with water and absolute ethanol, and dried in vacuum at 70°C to obtain microcapsules containing the catalyst.
[0057] (2) Preparation of hot melt adhesive film
[0058] Blend and add 6 parts of microcapsules, 86.2 parts of base film raw materials, 0.5 parts of peroxide, 5 parts of crosslinking monomer, and 0.4 part...
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