Method for preparing environment friendly catalyst

An environment-friendly and catalytic technology, which is applied in the direction of catalyst activation/preparation, catalyst carrier, chemical instruments and methods, etc., can solve the problems of non-reusable, high catalyst cost, and unsatisfactory service life, and achieve simple production, low cost, and easy The effect of recycling

Inactive Publication Date: 2007-06-27
INNER MONGOLIA NORMAL UNIVERSITY
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  • Summary
  • Abstract
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AI Technical Summary

Problems solved by technology

Most of the catalyst carriers used at home and abroad are synthetic molecular sieves. The cost of the prepared catalyst is high, the service life is not ideal, it cannot be reused, and the price is relatively expensive.

Method used

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  • Method for preparing environment friendly catalyst

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Embodiment Construction

[0007] As shown in Figure 1, take Hang Jin 2 # Add 1000g of clay raw soil ore, add 2500g of hydrochloric acid with a concentration of 10%, boil slightly at 105°C, stir for 1h, wash with water until pH = 6, filter with suction, dry the filter cake at 105°C, roast at 300°C for 2h, cool to room temperature to obtain 1000 g clay-SA 01 . Then 135gZnCl 2 Add 1000ml methanol to get ZnCl 2 methanol solution. Take 1000g Clay-SA 01 As a carrier, with the above ZnCl 2 The methanol solution was mixed and impregnated for 26 hours, and dried in vacuum at 80°C for 4 hours to obtain ZnCl 2 / clay-sa 01 Solid sample, recovered methanol, in N 2 Under gas protection, calcination at 280°C for 4h, N 2 Cool to room temperature in the atmosphere to make 1135g ZnCl 2 / clay-sa 01 catalyst.

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Abstract

The invention unfurls a way to produce a kind of catalyst of friendly environment. The way uses 2#soil--SA01 of feature changing as the carry ZnCl2, through dipping, evaporating to make ZnCl2 / soil--SA01 solid sample, at 70-80 degC, dry the sample in vacuum for 3--4h. In the protection of N2, fire at 250-300 degC for 3--4h cool the N2 to the room temperature, the ZnCl2 / soil--SA01 is made. The catalyst of the invention costs little, can be recovered. It achieves the material proper usage. The production of the catalyst belongs to the green production process.

Description

technical field [0001] The invention relates to a method for preparing an environment-friendly catalyst, in particular to a method for preparing the catalyst by a wet method. Background technique [0002] Friedle-Crafts alkylation generally uses hydrofluoric acid, sulfuric acid, aluminum trichloride, freshly prepared aluminum amalgam, etc. as catalysts. However, these catalysts seriously corrode the equipment and often bring about the "three wastes" problem. The above-mentioned problems can be avoided by using a solid acid instead of a liquid acid, and using a carrier reagent and a molecular sieve catalyst. Most of the catalyst carriers used at home and abroad are synthetic molecular sieves. The prepared catalysts have high cost, unsatisfactory service life, cannot be reused, and are expensive. Contents of the invention [0003] The technical problem to be solved by the present invention is to provide a preparation method of an environment-friendly catalyst. This prepar...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/10B01J32/00B01J37/02
Inventor 照日格图乌云宝迪嘎日迪赵慧
Owner INNER MONGOLIA NORMAL UNIVERSITY
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