Hermetic compressor and refrigeration system
a compressor and refrigeration system technology, applied in the direction of positive displacement liquid engines, pumping, lighting and heating apparatus, etc., can solve the problems of increasing aggression to organic materials, clogging of capillaries, and sludge accompanying extraction, so as to suppress the aggression of refrigeration oil to organic materials, reduce the extraction of organic materials, and reduce the effect of aggression of refrigeration oil
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first embodiment
[0046]FIG. 3 is a diagram showing the relation between the carbon number of a hydrocarbon radical and the swelling ratio of an organic material in the present invention. In FIG. 3, C1, C4, C8 and C9 denotes a hydrocarbon radical whose carbon number is 1, 4, 8 and 9, respectively, and content ratio is the ratio of C1, C4, C8 and C9 among all hydrocarbon radicals. FIG. 3 shows the result of evaluation of a shield tube test between HFC-134a and refrigeration oil 103.
[0047]In FIG. 3, in the case where the alicyclic multivalent carboxylic acid ester compound in which the carbon number of R1 is 4 or less is 15% by weight or less, penetration to an organic material is small and the swelling ratio is low. That is, the result is excellent. It was understood that, however, when the compound exceeds 20% by weight, penetration to an organic material increases, and the swelling ratio increases.
[0048]Increase in the swelling ratio denotes that refrigeration oil 103 penetrates an organic material,...
embodiment 1
[0069]Table 1 shows the result of evaluation made in a shield tube test between HFC-134a and refrigeration oil 203. Here, refrigeration oil 203 is a same refrigeration oil of
TABLE 1Mixing ratio(% by weight)0103050HueL 0.5L 0.5L 0.5L 0.5Total acid number0.010.010.010.01
[0070]It is understood from Table 1 that, when the mixture ratio of the ester oil obtained by the reaction between aliphatic alcohol and fatty acid is 0% to 50% by weight, the characteristics of refrigeration oil 203 are stable. It means that, at the time of replacing hermetic compressor 201 for service or the like, hermetic compressor 201 can be simply replaced without washing the inside of the refrigeration system.
[0071]Further, a life test was conducted in a refrigeration system constructed by hermetic compressor 201, condenser 206, expansion mechanism 207, and evaporator 208. In the test, refrigeration oil 203 in which 50% by weight of the ester oil obtained by the reaction between aliphatic alcohol and fatty acid ...
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