Higher ester type brake fluid

A technology of brake fluid and ester type, applied in the petroleum industry, lubricating compositions, etc., can solve the problems of low and low temperature kinematic viscosity, difficult to obtain, low grade, etc., and achieve good corrosion resistance and good low temperature kinematic viscosity.

Active Publication Date: 2012-11-07
张家港迪克汽车化学品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As far as the existing technology is concerned, borate brake fluid technology has become a necessary technology for high-performance borate brake fluid products. In recent years, there have been many patents and literatures published by the state about borate technology There are also some reports and studies on the production technology of super DOT4 and DOT5.1 brake fluid, but these technologies still have defects and cannot be really applied to the loading requirements
In 2002, the Chinese patent CN1355279A put boric anhydride, polyethylene glycol methyl ether, diethylene glycol and additives in one time, reacted for 3-4 hours under 2-3 atmospheric pressure, and cooled and filtered to obtain the finished brake fluid. It is reported that due to the use of diethylene glycol, it is also difficult to obtain super DOT4, DOT5.1 and above advanced brake fluids with high dry and wet boiling points and low low temperature kinematic viscosity
[0004] The Chinese patent CN 200310112132.5 of 2003, a kind of borate brake fluid and its preparation method, describes the production and manufacturing method of borate brake fluid, but this technology uses diethylene glycol as the main raw material for preparing borate, The brake fluid can only meet the requirements of DOT3 level indicators, and it is also a relatively low-end formula type
[0005] Chinese patent CN03111223.4 A kind of motor vehicle brake fluid and its production method discloses a method of producing brake fluid using a polymer mixture produced by diethylene glycol and 1,1-dichloroethane under the action of a catalyst as a raw material method, but the DOT4 brake fluid technical indicators described in this patent can only meet the general standard requirements, and there is still a big gap from the technical indicators of super DOT4 brake fluid and DOT5.1 brake fluid required by some automobile manufacturers.

Method used

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  • Higher ester type brake fluid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Add 70 kg of polyglycol methyl ether, 40 kg of trihydroxypolyoxypropylene ether, and 775 kg of triethylene glycol ethyl ether borate in turn in a 1.5T reactor, start stirring, and follow the steps below every 10 minutes Add 10 kilograms of tolyltriazole in sequence; 10 kilograms of N-phenylmorpholine; 15 kilograms of 2,2-two (4-hydroxyphenyl) propane; 5 kilograms of thiodipropionic acid didecyl Glycol ester; 10 kilograms of 4,4'-butylene bis(6-tert-butyl m-cresol); 20 kilograms of 2,2'-(cyclohexylimino) diethanol; finally add alkalinity regulator ( Di-n-butylamine) 45 kilograms, after continuing to stir for 4 hours, it can be filtered and packed through a 1~5um filter.

[0036] The GB12981-2003 standard requires long-term harsh testing, and the actual testing results show that the formula technology has good resistance to long-term metal corrosion:

[0037]

Embodiment 2

[0039] In the 1.5T reactor, add 60 kg of polyglycol methyl ether, 38 kg of trihydroxypolyoxypropylene ether, and 780 kg of triethylene glycol ether borate in turn, start stirring, and follow the steps below every 10 minutes Add 10 kilograms of tolyltriazole in sequence; 15 kilograms of N-phenylmorpholine; 20 kilograms of 2,2-two (4-hydroxyphenyl) propane; 8 kilograms of thiodipropionic acid didecyl Glycol ester; 9 kilograms of 4,4'-butylene bis(6-tert-butyl m-cresol); 19 kilograms of 2,2'-(cyclohexylimino) diethanol; finally add alkalinity regulator ( Di-n-butylamine) 41 kilograms, can pass through 1~5um filter filter packing after continuing to stir for 4 hours.

Embodiment 3

[0041] Add 70 kg of polyglycol methyl ether, 40 kg of trihydroxypolyoxypropylene ether, and 775 kg of triethylene glycol ethyl ether borate in turn in a 1.5T reactor, start stirring, and follow the steps below every 10 minutes Add 7 kilograms of tolyltriazole in sequence; 8 kilograms of N-phenylmorpholine; 15 kilograms of 2,2-bis(4-hydroxyphenyl) propane; 21 kilograms of thiodipropionic acid didecyl Glycol ester; 11 kilograms of 4,4'-butylene bis(6-tert-butyl m-cresol); 21 kilograms of 2,2'-(cyclohexylimino) diethanol; finally add alkalinity regulator ( Di-n-butylamine) 32 kilograms, can pass through 1~5um filter filter packing after continuing to stir for 4 hours.

[0042]The above-mentioned high-grade ester brake fluid can meet the needs of alcohol-ether brake fluid and alcohol-ether-ester brake fluid, especially the high-grade ester additive formula brake fluid technology suitable for ABS braking systems. The present invention can solve the higher dry and wet boiling point...

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Abstract

The invention discloses a higher ester type brake fluid, which comprises the following components in percent by mass: 5-7.0% of polyethylene glycol monomethyl ether, 0.5-4.0% of trihydroxyl polyoxypropylene, 50-78.0% of triethylene glycol boric acid ester, 0.2-1.0% of methyl benzotriazole, 0.3-1.5% of N-phenyl morpholine, 0.5-2.0% of 2,2-di(4-hydroxyl phenyl) propane, 0.04-2.1% of sulfo-dipropionic acid bidodecanol ester, 0.1-1.1% of 4,4'-butylidene bi(6-tert-butyl m-cresol), 0.5-2.1% of 2,2'-(cyclohexyl imino) diethanol and the balance of alkalinity regulator. The invention has the advantages of high drying and wetting boiling point and great low temperature kinematic viscosity, meets the requirement on durable metal corrosion experiment of 600 hours, satisfies and exceeds the requirement of GB12981-2003, is water insensitive and has good corrosion resisting effect in application of alcohol ether prescription.

Description

technical field [0001] The invention relates to a brake fluid technology for an automobile brake system, in particular to a high-grade ester brake fluid. Background technique [0002] Since the 1970s, a new generation of synthetic brake fluid with higher dry and wet boiling points, lower low-temperature kinematic viscosity and low water sensitivity has become a research hotspot in various countries. Subsequently, automobile brake fluids have been widely developed. At present, the mainstream products in the world are DOT4 and DOT5.1 brake fluids with alcohol ether borate as the main raw material. DOT4 borate synthetic brake fluid has been widely used in the world. The use of DOT5.1 type brake fluid is less, the main reason is its higher price, but with the vigorous development of the automobile industry, the higher requirements for the safety performance of automobiles will definitely promote DOT5.1 Brake fluid is widely used, especially in some demanding conditions. [000...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10M169/04C10N40/08C10N30/12
Inventor 陶佃彬曹云龙童秀凤李娟陈明娟闵海琴施丽丽邹密陈洁
Owner 张家港迪克汽车化学品有限公司
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