Preparation method of novel pencil
A pencil, a new type of technology, applied in non-mechanical pencil, pen holder, printing and other directions, can solve the problems of waste of straw resources, traffic and ecological environment pollution, and achieve the effect of low price and huge raw material resources
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Embodiment 1~3
[0031] Add recycled polyethylene terephthalate scraps and diethanolamine to the reaction kettle, stir, heat to 190-220°C, and react for 2 hours to obtain polyester-amide polyol; cool down to 75-80°C, add toluene Diisocyanate was stirred and reacted for 3 hours to obtain an isocyanate-terminated polyurethane adhesive; the raw materials used in Examples 1-3 and the performance tests of the products are shown in Table 1.
[0032] Table 1
[0033]
Embodiment 4~12
[0035] Drying the rice straw, drying until the water content of the rice straw is less than 15%, pulverizing, sieving, collecting the whole rice straw powder with a particle size of less than 20 meshes, and sealing it for later use;
[0036] Add the dried whole rice straw powder into a high-speed mixer, spray the isocyanate adhesive into it under high pressure, stir and blend at room temperature for 10 minutes to obtain a blend;
[0037] Fill the blend into the pencil molding machine, heat press, feed the pen core, cold press, and paint the exterior.
[0038] Table 2
[0039]
[0040] Example 5
[0041] Note: see Example 1 for the preparation method of isocyanate-terminated polyurethane 1;
Embodiment 2
[0042] The preparation method of isocyanate-terminated polyurethane 2 is shown in Example 2;
[0043] See Example 3 for the preparation method of isocyanate-terminated polyurethane 3.
[0044] Embodiment 4~12 makes pencil, detects its pen holder binding fastness according to the light industry industry standard QB / T2774-2006 of the People's Republic of China, all do not open glue, illustrate that the rice straw pencil produced by this patent, the pen holder binding fastness has reached QB / T2774 -Standards stipulated in 2006.
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