Method for detecting content of water treatment agent by adopting fluorescent tracer

A fluorescent tracer and treatment agent technology, which is applied in the direction of chemiluminescence/bioluminescence, and analysis by making materials undergo chemical reactions, can solve the problems that affect the widespread application of small and medium-scale circulating cooling water systems, and the difficulty of finding fluorescent tracers. Problems such as high production cost, to achieve the effect of ensuring scale inhibition effect, low use cost and low price

Inactive Publication Date: 2012-08-22
CHANGZHOU UNIV
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  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

Among them, the method of physical blending is relatively simple and low in cost, but it is difficult to find a suitable fluorescent tracer; both polymer modification and fluorescent monomer copolymerization are to improve the water treatment agent itself, but its production cost is high, which affects its performance. Widely popularized and applied in small and medium-sized circulating cooling water systems

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  • Method for detecting content of water treatment agent by adopting fluorescent tracer
  • Method for detecting content of water treatment agent by adopting fluorescent tracer

Examples

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Embodiment 1

[0029] Blend 4,4'-bis-(2-sodium styryl sulfonate) biphenyl fluorescent tracer with water treatment agent containing acrylic acid-hydroxypropyl acrylate-AMPS copolymer and hydrolyzed polymaleic anhydride to prepare The mass concentration of acrylic acid-hydroxypropyl acrylate-AMPS copolymer and hydrolyzed polymaleic acid is 2.5kg / M 3 Fluorescence-labeled reconstituted water treatment standard additive solution. Acrylic acid-hydroxypropyl acrylate-AMPS copolymer accounts for 30-60% in the compound water treatment standard additive solution, and hydrolyzed polymaleic anhydride accounts for 10-30%. The mass ratio of its 4,4'-bis-(2-sodium styryl sulfonate) biphenyl fluorescent tracer to the compounded water treatment agent is 3:500. 30M water retention in one 3 In the cooling water system, add 29.4M 3 Water, adding fluorescent marker compound water treatment standard additive solution (2.5kg / M 3 )0.6M 3 , to run in a loop. At this time, the concentration of the compound wat...

Embodiment 2

[0031] Blend 4,4'-bis-(2-sodium styryl sulfonate) biphenyl fluorescent tracer with water treatment agent containing acrylic acid-hydroxypropyl acrylate-AMPS copolymer and hydrolyzed polymaleic anhydride to prepare The mass concentration of acrylic acid-hydroxypropyl acrylate-AMPS copolymer and hydrolyzed polymaleic acid is 2.5kg / M 3 Fluorescence-labeled reconstituted water treatment standard additive solution. Acrylic acid-hydroxypropyl acrylate-AMPS copolymer accounts for 30-60% in the compound water treatment standard additive solution, and hydrolyzed polymaleic anhydride accounts for 10-30%. The mass ratio of its 4,4'-bis-(2-sodium styryl sulfonate) biphenyl fluorescent tracer to the compounded water treatment agent is 3:500. 60M water retention in one 3 In the cooling water system, add 58.8M 3 Water, adding fluorescent label compound water treatment standard additive solution (2.5kg / M 3 )1.2M 3 , to run in a loop. The initial concentration of the compounded water tr...

Embodiment 3

[0033] Blend 4,4'-bis-(2-sodium styryl sulfonate) biphenyl fluorescent tracer with water treatment agent containing acrylic acid-hydroxypropyl acrylate-AMPS copolymer and hydrolyzed polymaleic anhydride to prepare The mass concentration of acrylic acid-hydroxypropyl acrylate-AMPS copolymer and hydrolyzed polymaleic acid is 2.5kg / M 3 Fluorescence-labeled reconstituted water treatment standard additive solution. Acrylic acid-hydroxypropyl acrylate-AMPS copolymer accounts for 30-60% in the compound water treatment standard additive solution, and hydrolyzed polymaleic anhydride accounts for 10-30%. The mass ratio of its 4,4'-bis-(2-sodium styryl sulfonate) biphenyl fluorescent tracer to the compounded water treatment agent is 3:500. 80M water retention in one 3 In the cooling water system, add 78.4M 3 Water, adding fluorescent label compound water treatment standard additive solution (2.5kg / M 3 )1.6M 3 , to run in a loop. The initial concentration of the compounded water tr...

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Abstract

The invention discloses a method for detecting the content of compound water treatment agent in industrial circulating cooling water by adopting fluorescent tracer. Disodium 4,4'-bis(2-sulfostyryl) biphenyl fluorescent tracer and the water treatment agent containing acrylic acid-hydroxypropyl acrylate-AMPS copolymer and hydrolytic polymaleic anhydride are blended, so that fluorescence-labeled compound water treatment standard additive is prepared, the mass concentration of the acrylic acid-hydroxypropyl acrylate-AMPS copolymer and the hydrolytic polymaleic anhydride of the fluorescence-labeled compound water treatment standard additive is 2.5kg / M3, 40g / M3 to 50g / M3 of fluorescence-labeled compound water treatment standard additive is added into industrial circulating cooling water and industrially circulated, and if the measured fluorescence value is less than 5470 plus or minus 100, then the fluorescence-labeled compound water treatment standard additive needs to be added. The content of the compound water treatment agent can be quantitatively monitored according to the fluorescence intensity of the circulating cooling water, so that the compound water treatment agent can be conveniently added in real time in order to guarantee the scale inhibition effect of a circulating cooling water system.

Description

technical field [0001] The invention relates to a method for detecting the content of a compound water treatment agent in industrial circulating cooling water by using a tracer substance, and belongs to the field of industrial water treatment detection. Background technique [0002] In industrial water treatment systems, water treatment agents have been widely used, and the concentration control of water treatment agents has always been one of the difficult problems in water treatment management. Usually, the concentration of the water treatment agent can be monitored by manual sampling to detect the total phosphorus value, but this method is time-consuming, the control lags, and it is easy to cause the waste of the water treatment agent and the scaling and corrosion of the system. In recent years, with the promotion and use of environmentally friendly phosphorus-free water treatment agents, the concentration of water treatment agents cannot be monitored and controlled by co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/76
Inventor 杨扬陆钰蒙张国君
Owner CHANGZHOU UNIV
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