Cationic modified cellulose fibers

Abstract

The invention relates to cationic modified cellulose fibers, belonging to the technical field of textile dyeing. The modified cellulose fibers are obtained by carrying out modification treatment on cellulose fibers with low molecular quaternary ammonium salt cationic modifiers and a high molecular quaternary ammonium salt cationic modifier as cationic modifiers and have Zeta electrode potential values of 10-30mV when the pH values are 6.5-8.5, wherein the low molecular quaternary ammonium salt cationic modifiers are epoxy quaternary ammonium salt compounds; the high molecular quaternary ammonium salt cationic modifier is branched polyepichlorohydrin dimethylamine. The cationic modified cellulose fibers have the beneficial technical effects that the two kinds of specific modifiers are adopted and the synergistic effects of the modifiers are given play to, so that the modified cellulose fibers achieve salt-free low-alkali dyeing in subsequent dyeing, have the effects of reducing pollution, saving the cost, simplifying the process and reducing the difficulty, have good modification and subsequent dyeing effects, and are suitable for large-scale industrial production.

Description

technical field [0001] The invention relates to a modified cellulose fiber, more specifically, the invention relates to a cationized modified cellulose fiber, which belongs to the technical field of textile dyeing. Background technique [0002] The dye uptake rate of traditional cellulose fiber dyeing process is generally around 40-70%. The dye uptake rate is low and there are many floating colors. In order to achieve the purpose of color fixation, the hydroxyl groups on the cellulose need to be ionized under strong alkaline conditions, so a large amount of soda ash must be added to the dyeing solution in the later stage of dyeing. The treatment of inorganic salts and alkalis has always been a problem that plagues the industry. A large amount of inorganic salts that are neither recyclable nor degradable are discharged into rivers and lakes, seriously polluting water quality. Due to the high permeability of salt, the surrounding soil is salinized and becomes alkaline. It is ...

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Problems solved by technology

[0015] The present invention aims to solve the following problems in the process of dyeing the cellulose fibers after modification in order to reduce the consumption of dyes, inorganic salts and alkali in the prior art: The degree of pollution is high, and the discharged wastewater is difficult to treat, causing pollution; and the existing modified cellulose fiber is used for the process of dyeing without salt and low alkali modification, which cannot be applied to large-scale industrial production

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