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Homometallic cyanide-containing inorganic polymers and related compounds

A technology of composition and complex, applied in the direction of metal cyanide, complex cyanide, non-metallic conductor, etc.

Active Publication Date: 2017-08-29
ALVEO ENERGY INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although recent developments in cyanide-bridged coordination polymer electrodes for aqueous electrolyte batteries indicate the possibility of satisfactory results, many challenging issues must be addressed

Method used

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  • Homometallic cyanide-containing inorganic polymers and related compounds
  • Homometallic cyanide-containing inorganic polymers and related compounds
  • Homometallic cyanide-containing inorganic polymers and related compounds

Examples

Experimental program
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Effect test

Embodiment 1

[0094] Example 1): Under an inert atmosphere of nitrogen (oxygen < 0.1 ppm), add dropwise to a stirred solution of manganese chloride tetrahydrate (16.0 g, 80.0 mmol) in degassed water (40 g) over 290 minutes A solution of potassium cyanide (12.0 g, 184 mmol) in deaerated water (40 g) was added. The resulting mixture was stirred for an additional 15 minutes, then filtered on a 0.45 micron filter. The resulting green powder was washed with degassed water (200ml), rinsed with degassed methanol (100ml) and dried under vacuum to give 9.6g of a green powder.

Embodiment 2

[0095] Example 2): To a stirred solution of manganese acetate tetrahydrate (19.6 g, 80.0 mmol) in degassed water (40 g) was added dropwise over 300 minutes under an inert atmosphere of nitrogen (oxygen < 0.1 ppm) A solution of potassium cyanide (12.0 g, 184 mmol) in degassed water (40 g). The resulting mixture was stirred for an additional 15 minutes, then filtered on a 0.45 micron filter. The resulting green powder was washed with degassed water (300ml), rinsed with degassed methanol (200ml) and dried under vacuum to give 9.35g of a green powder.

Embodiment 3

[0096] Example 3): Under an inert atmosphere of nitrogen (oxygen < 0.1 ppm), to a stirred solution of potassium cyanide (12.0 g, 184 mmol) in deaerated water (40 g) was added dropwise four A solution of manganese acetate hydrate (19.6 g, 80.0 mmol) in degassed water (40 g). The resulting mixture was stirred for an additional 15 minutes, then filtered on a 0.45 micron filter. The resulting green powder was washed with degassed water (200ml), rinsed with degassed methanol (100ml) and dried under vacuum to give 10.4g of a green powder.

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Abstract

The present invention relates to a composition, a compound, a device, and uses thereof according to a formula 1), wherein: A= Na, K, Li; and M= Mg, Al, Ca, Sc, Ti, V, Cr, Fe, Co, Ni, Cu, Zn, Ga, Pd, Ag, Cd, In, Sn, Pb; and wherein 0<j<=4;0<=k<=0.1;0<=p<=3; 0<x<=4; 0<=y<=1; 0<z<1; 0<n<=6; and wherein: x+2(y-k)+jk+(m-6)z=0.

Description

[0001] Cross References to Related Applications [0002] This application claims the benefit of US Patent Application Serial No. 14 / 523,825, currently US Patent No. 9,099,740, filed October 24, 2015, the contents of which are expressly incorporated herein by reference for all purposes. [0003] Statement Regarding Federally Sponsored Research or Development [0004] This invention was made with US Government support under Award No. DE-AR0000300 awarded by the US Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E). The US Government has certain rights in this invention. technical field [0005] In addition to other devices and uses pertaining to the composition or composite, the present invention generally relates to the composition, composites made from the composition, electrodes using the composition or composite, electrochemical structures using the electrode, and Rechargeable batteries comprising the electrochemical structure, more particularly, but ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/58C01C3/11H01B1/06H01M4/137H01M4/136H01M4/62
CPCC01C3/11H01B1/06H01M4/136H01M4/137H01M4/58H01M4/622H01M4/625Y02E60/10C01C3/08H01M2300/0002
Inventor 沙洛克·莫塔雷比科林·迪恩·维塞尔斯阿里·费罗兹
Owner ALVEO ENERGY INC
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