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Additive for selectively adsorbing crotonaldehyde and phenol as well as preparation method and application of additive

A technology of crotonaldehyde and additives, which is applied in the field of functional materials for cigarette tar reduction and detoxification, can solve the problem of low phenol removal rate, and achieve the effect of mild preparation conditions and good reproducibility

Inactive Publication Date: 2018-07-06
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the removal rate of phenol is not high

Method used

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  • Additive for selectively adsorbing crotonaldehyde and phenol as well as preparation method and application of additive
  • Additive for selectively adsorbing crotonaldehyde and phenol as well as preparation method and application of additive
  • Additive for selectively adsorbing crotonaldehyde and phenol as well as preparation method and application of additive

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A preparation method for an additive for selectively adsorbing crotonaldehyde and phenol, comprising the following steps:

[0031] (1) Preparation of CuAPO-5 initial gel: Make pseudo-boehmite into a suspension with water, then dissolve copper nitrate in water, add it to the suspension of pseudo-boehmite, stir and mix until it is in a suspension state ; Afterwards, under stirring, add dropwise the phosphoric acid with a volume concentration of 80%, after adding, continue stirring for 0.9h, add triethylamine dropwise under stirring, continue stirring for 1.9h after adding, to obtain CuAPO -5 initial gel;

[0032] Among them, Al in copper nitrate and pseudoboehmite 2 o 3 、H 3 PO 4 , The mol ratio of the total consumption of triethylamine and water is 0.03:0.97:1:0.74:1.00;

[0033] (2) Crystallization, drying and roasting: Add the initial CuAPO-5 gel prepared in step (1) into a reaction kettle lined with polytetrafluoroethylene, crystallize at 180°C for 36 hours, take...

Embodiment 2

[0038] A preparation method for an additive for selectively adsorbing crotonaldehyde and phenol, comprising the following steps:

[0039] (1) Preparation of CuAPO-5 initial gel: Make pseudo-boehmite into a suspension with water, then dissolve copper nitrate in water, add it to the suspension of pseudo-boehmite, stir and mix until it is in a suspension state ; Afterwards, in a stirring state, dropwise adding phosphoric acid with a volume concentration of 85%, after adding, continue to stir for 1h, add triethylamine dropwise in a stirring state, continue stirring for 2h after adding, to obtain CuAPO-5 initial gel;

[0040] Among them, Al in copper nitrate and pseudoboehmite 2 o 3 、H 3 PO 4 , The mol ratio of the total consumption of triethylamine and water is 0.06:0.94:1:0.75:1.10;

[0041] (2) Crystallization, drying and roasting: Add the initial CuAPO-5 gel prepared in step (1) into a reaction kettle lined with polytetrafluoroethylene, crystallize at 200°C for 24 hours, t...

Embodiment 3

[0045] A preparation method for an additive for selectively adsorbing crotonaldehyde and phenol, comprising the following steps:

[0046] (1) Preparation of CuAPO-5 initial gel: Make pseudo-boehmite into a suspension with water, then dissolve copper nitrate in water, add it to the suspension of pseudo-boehmite, stir and mix until it is in a suspension state ; Afterwards, in a stirring state, dropwise adding phosphoric acid with a volume concentration of 83%, after adding, continue to stir for 1.1h, add triethylamine dropwise in a stirring state, continue stirring for 2.1h after adding, to obtain CuAPO -5 initial gel;

[0047] Among them, Al in copper nitrate and pseudoboehmite 2 o 3 、H 3 PO 4 , The mol ratio of the total consumption of triethylamine and water is 0.09:0.91:1:0.70:1.20;

[0048] (2) Crystallization, drying and roasting: Add the initial CuAPO-5 gel prepared in step (1) into a reaction kettle lined with polytetrafluoroethylene, crystallize at 190°C for 48 hou...

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Abstract

The invention discloses an additive for selectively adsorbing crotonaldehyde and phenol as well as a preparation method and application of the additive. CuAPO-5 is synthesized by adopting a hydrothermal method and taking triethylamine as a template agent, copper nitrate as a copper source, pseudo-boehmite as an aluminum source and phosphoric acid as a phosphorus source. The test result of a cigarette additive test shows that the additive obviously adsorbs tobacco specific harmful gases such as phenol, crotonaldehyde and tar, especially phenol. The additive has the advantages of good adsorptioneffect, strong plasticity, safety, innocuity, low price and the like, and has a good application value.

Description

technical field [0001] The invention relates to an additive for selectively adsorbing crotonaldehyde and phenol, a preparation method and application thereof, and belongs to the field of functional materials for reducing tar and detoxification of cigarettes. Background technique [0002] Cigarette smoke is a mixture of extremely complex components produced by high-temperature combustion, cracking, distillation and other processes during the smoking process of tobacco products. As we all know, smoking is harmful to health. Since the 1950s, tobacco tar reduction and harm reduction have been the focus and hotspot of international tobacco research. In 1954, Cooper et al. first discovered the carcinogenic component, benzo[a]pyrene, from cigarette smoke. Subsequently, there have been more and more studies on harmful components in cigarette smoke. From the list of 43 harmful ingredients published by Hoffmann in 1990 to the list of 46 harmful ingredients released by the Canadian g...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/18B01J20/30A24D3/16
CPCB01J20/18A24D3/16
Inventor 王亚明温青青蒋丽红郑燕娥贾庆明陕绍云郑青叶
Owner KUNMING UNIV OF SCI & TECH
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