Soluble temporary blocking material for well fracturing and preparation method of soluble temporary blocking material for well fracturing

An oil and gas well, soluble technology, applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of increased construction period, poor solubility of cross-linked polymers, formation damage, etc., to achieve increased production, good temporary The effect of blocking the steering and the effect of low ground damage

Inactive Publication Date: 2019-03-19
安庆五宁精细化工有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, polymers with polyacrylamide as the main body are also used as temporary plugging agents, and their plugging strength and temporary plugging rate can also meet the requirements of on-site construction, but after degradation, they have high viscosity, which makes the fracturing fluid Increased viscosity is not conducive to flowback after construction, and will cause greater damage to the formation
[0005] The existing various temporary plugging agents have certain temporary plugging performance but also have their own defects. The release of inorganic salts during the dissolution process of the system composed of inorganic salts will cause permanent blockage of the formation, which is not conducive to later oil and gas production; cross-linking Cross-linked polymers need to be added with a gel breaker after construction to break the gel. In construction operations that require a long temporary plugging time, the construction cycle will be increased, resulting in increased costs. At the same time, the solubility of cross-linked polymers is poor, and some If the gel cannot be completely broken in the fluid, it will also stay in the formation and affect the later mining process; the dissolution of the PAM temporary plugging agent will increase the viscosity of the fracturing fluid, which is not conducive to the flowback of the fracturing fluid

Method used

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  • Soluble temporary blocking material for well fracturing and preparation method of soluble temporary blocking material for well fracturing
  • Soluble temporary blocking material for well fracturing and preparation method of soluble temporary blocking material for well fracturing
  • Soluble temporary blocking material for well fracturing and preparation method of soluble temporary blocking material for well fracturing

Examples

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Effect test

Embodiment 1

[0024] Nitrogen was passed through the reaction system to replace the air, and then fumaric acid (fumaric acid) and pentaerythritol monomers were added into a four-necked round-bottomed flask according to the mass ratio and stirred, wherein 98.5 g of fumaric acid was added into 100 g of distilled water to fully dissolve , add 110 g of pentaerythritol; then add 0.32 g of initiator and gradually heat the system to 100 ° C, after 25 min of heat preservation, add AMPS solution neutralized with sodium hydroxide to the system (dissolve with distilled water, add 25 g of AMPS to 25 g of distilled water, then add 4 g sodium hydroxide). Then the temperature of the system was raised to 140°C and kept for 0.5h. Then, 15 g of phenoxyethanol was added to the reaction system for reaction, and 0.08 g of initiator was added and the temperature was raised to 165° C., and the temperature was lowered after 2 hours of reaction. After the reaction is completed, the obtained product is purified and...

Embodiment 2

[0028] Nitrogen was passed through the reaction system to replace the air, and then itaconic acid and trimethylolpropane monomers were added into a four-necked round-bottomed flask according to the mass ratio and stirred, wherein 105g of itaconic acid was fully dissolved in 100g of distilled water, and trimethylolpropane was added Methylpropane 97g; then add 0.30g initiator and gradually heat up the system to 105°C, keep warm for 30min and add AMPS solution neutralized with sodium hydroxide to the system (dissolve with distilled water, add 21g AMPS to 30g distilled water, then add 4g sodium hydroxide). Then raise the temperature of the system

[0029] The molecular weight is 16500-18500.

[0030] In order to ensure that the obtained temporary plugging material has good hydrophilicity, the embodiment of the present invention adopts a synthetic main chain with a linear structure, and uses itaconic acid and trimethylolpropane containing three hydroxyl groups as the synthetic u...

Embodiment 3

[0032] The soluble temporary plugging material obtained in Example 1 was heated, melted and extruded by a screw extruder, cut and granulated by a granulator, and shaped into particles with a particle size of 5-8 mm to obtain temporary plugging particles. After crushing and sieving, a 20-120 mesh powder is obtained.

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Abstract

The invention discloses a soluble temporary blocking material for well fracturing and a preparation method of the soluble temporary blocking material for well fracturing. The soluble temporary blocking material is a polymer prepared from, by mass, 25-30% of C4-C6 dicarboxylic acids, 7-10% of 2-acrylamide-2-methyl propanesulfonic acid, 20-25% of C4-C7 polyols, 5-8% of monohydric alcohol with a single benzene ring structure, 0.08-0.15% of an initiator, 1.5-2% of sodium hydroxide and 30% of distilled water. The soluble temporary blocking material is capable of dissolving completely without residual solids in environments of fracturing fluids at different temperatures.

Description

technical field [0001] The invention relates to the technical field of oil and gas well fracturing materials, in particular to a soluble temporary plugging material for oil and gas well fracturing and a preparation method thereof. Background technique [0002] my country's low-permeability oilfields are rich in petroleum geological reserves, and their resources account for about 30% of the country's total petroleum resources. Among the proven reserves, low-permeability oil reservoirs account for more than two-thirds of the country's reserves, and the development potential is huge. Although most low-permeability reservoirs have a large increase in production after fracturing, the production is still not high. In recent years, major oilfields have adopted multi-fracture technology or fracture diversion technology in the fracturing operation to intensify efforts to stimulate low-permeability reservoirs and maximize reservoir production. Steering fracturing technology is based ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/508C09K8/68C08G63/688
CPCC09K8/5086C09K8/685C09K8/885C09K8/887C08G63/6888
Inventor 徐太平杨来文杨基林
Owner 安庆五宁精细化工有限责任公司
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