A high ptc-strength conductive composite material with isolation-double percolation structure, and preparation method and application thereof
A conductive composite material, double percolation technology, applied in the field of conductive composite materials with high PTC strength, can solve the problems of low PTC strength, poor stability, and high filling amount of conductive fillers, and achieve reduced percolation value, high stability, and improved The effect of conductivity
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Embodiment 1
[0048] A conductive composite material with high PTC strength of isolation-double percolation structure, the conductive composite material is made from raw materials comprising the following components: 5g of linear low density polyethylene, 45g of polyvinylidene fluoride, 1g of conductive carbon black and antioxidant 10100.05g;
[0049] That is, the mass ratio of linear low density polyethylene and polyvinylidene fluoride is 1:9; the mass of conductive carbon black is 2% of the total mass of linear low density polyethylene and polyvinylidene fluoride; the mass of antioxidant 1010 is linear low 1% of density polyethylene mass.
[0050] Its preparation method comprises the following steps:
[0051] Dry linear low-density polyethylene and polyvinylidene fluoride in vacuum; add linear low-density polyethylene to an internal mixer at 150°C and melt for 2 minutes; then add conductive carbon black and antioxidant 1010 according to the above ratio, and melt Blend for 4 minutes to o...
Embodiment 2
[0054] A conductive composite material with high PTC strength of isolation-double percolation structure, the conductive composite material is made from raw materials comprising the following components: linear low density polyethylene 5g, polyvinylidene fluoride 45g, conductive carbon black 1.3 g and antioxidant 10100.05g;
[0055] That is, the mass ratio of linear low density polyethylene and polyvinylidene fluoride is 1:9; the mass of conductive carbon black is 2.6% of the total mass of linear low density polyethylene and polyvinylidene fluoride; the mass of antioxidant 1010 is linear low 1% of density polyethylene mass.
[0056] The preparation method is the same as in Example 1.
Embodiment 3
[0058] A kind of conductive composite material with high PTC strength of isolation-double percolation structure, this conductive composite material is made by the raw material that comprises following component: linear low density polyethylene 5g, polyvinylidene fluoride 45g, conductive carbon black 1.4 g and antioxidant 10100.05g;
[0059] That is, the mass ratio of linear low density polyethylene and polyvinylidene fluoride is 1:9; the mass of conductive carbon black is 2.8% of the total mass of linear low density polyethylene and polyvinylidene fluoride; the mass of antioxidant 1010 is linear low 1% of density polyethylene mass.
[0060] The preparation method is the same as in Example 1.
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