Polarizing plate with phase difference layer and image display device using same
A retardation layer and polarizing plate technology, applied in lighting devices, optics, light sources, etc., can solve the problems of reduced optical characteristics, reduced optical characteristics, insufficient optical characteristics of polarizing plates, etc., and achieves the effects of excellent optical characteristics and excellent handleability.
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Embodiment 1
[0192] 1. Fabrication of Polarizing Film
[0193] As the thermoplastic resin substrate, a long amorphous isophthalic acid-copolymerized polyethylene terephthalate film (thickness: 100 μm) having a water absorption rate of 0.75% and a Tg of about 75° C. was used. Corona treatment is performed on one side of the resin substrate.
[0194] 100 wt. 13 parts by weight of potassium iodide was added to each part, and it was dissolved in water to prepare an aqueous PVA solution (coating solution).
[0195] The above-mentioned PVA aqueous solution was applied on the corona-treated surface of the resin substrate and dried at 60° C. to form a PVA-based resin layer with a thickness of 13 μm to produce a laminate.
[0196] The free end of the obtained laminate was uniaxially stretched 2.4 times in the longitudinal direction (longitudinal direction) between rolls having different circumferential speeds in an oven at 130° C. (in-air auxiliary stretching treatment).
[0197] Next, the lamin...
Embodiment 2-1
[0214] 1. Fabrication of Polarizing Film
[0215] In the same manner as in Example 1, a polarizing film with a thickness of 5 μm was formed on the resin substrate.
[0216] 2. Fabrication of polarizing plate
[0217] Use the triacetate cellulose (TAC) film (hard coat thickness 7 μ m, TAC thickness 25 μ m, modulus of elasticity: 3600MPa) with hard coat as protective layer, except that, operate in the same way as in Example 1, make protective Layer / adhesive layer / polarizing film composition of the polarizing plate.
[0218] 3. Fabrication of the retardation film constituting the retardation layer
[0219] Except that the PMMA of 0.7 mass parts is melt-kneaded, the polyester carbonate resin (pellets) obtained in the same manner as in Example 1 was vacuum-dried at 80° C. for 5 hours, and then, using a single-screw extruder ( Manufactured by Toshiba Machine Co., Ltd., barrel set temperature: 250°C), T-die (width 200mm, set temperature: 250°C), cooling roll (set temperature: 120-...
Embodiment 2-2
[0223] The elongated polyester carbonate resin film with a thickness of 105 μm obtained in the same manner as in Example 2-1 was stretched in the width direction while being adjusted so that a predetermined retardation could be obtained to obtain a retardation film with a thickness of 38 μm. . Re(550) of the obtained retardation film was 140 nm.
[0224] Except using above-mentioned retardation film as retardation layer, operate similarly with embodiment 2-1, obtain the film with retardation layer having the composition of protective layer / bonding layer / polarizing film / adhesive layer / retardation layer polarizer. The total thickness of the obtained polarizing plate with a retardation layer was 81 μm. The obtained polarizing plate with a retardation layer was subjected to the same evaluation as in Example 1. The results are shown in Table 2.
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