Lubricating oil composition for refrigerating machine

a technology for refrigerating machines and lubricating oil, which is applied in the direction of refrigeration machines, refrigeration components, light and heating apparatus, etc., can solve the problems of reducing heat exchange efficiency, adversely affecting the lifetime and efficiency of refrigerators, and shortening the lifetime of refrigerators remarkably, etc., to achieve excellent compatibility with refrigerant, low global warming potential, and excellent stability

Active Publication Date: 2016-11-15
IDEMITSU KOSAN CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0009]Under the circumstances, an object of the present invention is to provide a lubricant composition for a refrigerator having the following characteristics: the composition being used for a refrigerator using a refrigerant having a specific structure such as an unsaturated fluorinated hydrocarbon compound serving as a refrigerant having a low global warming potential and usable particularly in current air-conditioning system for cars; and the composition having excellent stability as well as excellent compatibility with the refrigerant.
[0026]According to the present invention, there can be provided a lubricant composition for a refrigerator having the following characteristics: the composition being used for a refrigerator using a refrigerant having a specific structure such as an unsaturated fluorinated hydrocarbon compound serving as a refrigerant having a low global warming potential and usable particularly in current air-conditioning systems for cars; the composition having excellent stability as well as excellent compatibility with the refrigerant; and the composition suppressing the generation of sludge in a sealed tube test.

Problems solved by technology

The occurrence of the phase separation during the operation of the refrigerator adversely affects the lifetime and efficiency of the refrigerator to a remarkable extent.
For example, when the phase separation of the refrigerant and the lubricant occurs in the compressor portion, a movable part is insufficiently lubricated, with the result that baking or the like occurs to shorten the lifetime of the refrigerator remarkably.
On the other hand, when the phase separation occurs in the evaporator, the lubricant having a high viscosity is present, with the result that the efficiency of heat exchange reduces.
However, such compounds each contain chlorine that is responsible for environmental issues, so investigation has been conducted on a chlorine-free alternative refrigerant such as a hydrofluorocarbon (HFC).
The carbon dioxide requires high pressure, and hence cannot be used in the current air-conditioning system for cars.

Method used

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Examples

Experimental program
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examples

[0119]Subsequently, the present invention is described in more detail by way of Examples. However, the present invention is by no means limited by the Examples.

[0120]It should be noted that properties of the base oil and various characteristics of the refrigerator oil composition were determined according to the following procedure.

(1) Kinematic Viscosity at 100° C.

[0121]The kinematic viscosity at 100° C. was measured according to JIS K2283-1983 by using a glass-made capillary viscometer.

(2) Hydroxyl Number

[0122]The hydroxyl number was measured according to JIS K 0070.

(3) Molecular Weight

[0123]The molecular weight was calculated according to the chemical structures of compounds constituting the base oil.

(4) Flash-Point

[0124]The flash-point was measured according to JIS K 2265 (COC method).

(5) Two-Phase Separation Temperature

[0125]A measuring tube for two-phase separation temperature (internal volume: 10 mL) was filled with an oil (0.6 g) and a refrigerant (2.4 g) and kept in a therm...

examples 1 to 12

, and Comparative Examples 1 to 9

[0131]Refrigerator oil compositions each having a composition as shown in Tables 2 were prepared, and the properties thereof were evaluated by using, as refrigerants, HFC1234yf (2,3,3,3-tetrafluoropropene). The results are shown in Tables 2.

[0132]

TABLE 2Example 123456BlendingBase oilA190——90——compositionA2—90——90—(% by mass)A3——90——90AcidB1101010———scavengerB2———101010B3——————Two-phase separation temperature 202020202020of HFC1234yf[oil content of 20% by mass] (° C.)PerformanceSealedOilGoodGoodGoodGoodGoodGoodevaluationtube testappearanceCatalystGoodGoodGoodGoodGoodGoodappearancePresenceAbsentAbsentAbsentAbsentAbsentAbsentor absenceof sludgeAcid value 0.01> 0.01> 0.01> 0.01> 0.01> 0.01>(mgKOH / g)Example789101112BlendingBase oilA195——98——compositionA2—95——98—(% by mass)A3——95——98AcidB1 5 5 5 2  2  2 scavengerB2——————B3——————Two-phase separation temperature 202020202020of HFC1234yf[oil content of 20% by mass] (° C.)PerformanceSealedOilGoodGoodGoodGoodGo...

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Abstract

Provided is a lubricant composition for a refrigerator having the following characteristics: the composition being used for a refrigerator using a refrigerant having a specific structure such as an unsaturated fluorinated hydrocarbon compound serving as a refrigerant having a low global warming potential and usable particularly in current air-conditioning system for cars; the composition having excellent stability as well as excellent compatibility with the refrigerant; the composition including a base oil containing a polyoxyalkylene glycol derivative as a main component and 1 to 20% by mass of a monoepoxy compound based on the total amount of the composition; and the refrigerator using a refrigerant containing at least one kind of fluorine-containing organic compound selected from compounds represented by the molecular formula (A) CpOqFrRs or including a combination of the fluorine-containing organic compound and a saturated fluorinated hydrocarbon compound.

Description

TECHNICAL FIELD[0001]The present invention relates to a lubricant composition for a refrigerator and more specifically, to a lubricant composition for a refrigerator, which is used for a refrigerator using a specific refrigerant such as an unsaturated fluorinated hydrocarbon compound serving as a refrigerant having a low global warming potential and being available particularly in current air-conditioning systems for cars or the like, and which is formed by using a base oil mainly containing a polyoxyalkylene glycol derivative, has excellent stability, and suppresses the generation of sludge in a sealed tube test.BACKGROUND ART[0002]In general, a compression refrigerator includes at least a compressor, a condenser, an expansion mechanism (such as an expansion valve), and an evaporator, or further includes a drier, and is structured so that a mixed liquid of a refrigerant and lubricant (refrigerator oil) circulates in a closed system. In such a compression refrigerator, the temperatu...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): C09K5/04C10M169/04C10M171/00
CPCC09K5/045C10M169/04C10M171/008C09K2205/112C09K2205/126C10M2207/042C10M2207/24C10M2209/1033C10M2209/1055C10M2209/1075C10N2220/00C10N2220/021C10N2220/022C10N2220/302C10N2230/02C10N2230/08C10N2230/10C10N2240/30C10N2250/18C10N2020/00C10N2020/04C10N2020/02C10N2020/101C10N2030/02C10N2030/08C10N2030/10C10N2040/30C10N2050/14C10M2209/1085
Inventor KANEKO, MASATOIKEDA, HARUTOMOSATO, TOKUE
Owner IDEMITSU KOSAN CO LTD
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